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Preparation of Functional Textiles by Multilayer Structure - Cotton Fabrics Treated with Chitosan and Alginate Skin -

다층 코팅 처리에 의한 기능성 섬유의 제조 - 키토산과 알지네이트로 피복된 면 -

  • Received : 2011.05.06
  • Accepted : 2011.09.02
  • Published : 2011.09.27

Abstract

With a new method of applying chitosan and alginate onto cellulose, multi-coated cotton fabrics with chitosan and alginate were prepared and characterized. To coat cotton with chitosan, raw cotton was dipped in chitosan solution, mangled of 1kgf/$cm^2$, neutralized in 2 wt% NaOH soluton, washed, and dried at $60^{\circ}C$ oven. The chitosan-coated fiber was dipped in sodium alginate solution, 1kgf/$cm^2$ mangled, neutralized in 2 wt% $CaCl_2$ solution, washed, and dried at $60^{\circ}C$ oven, resulting in CCAC(coated cotton with chitosan and calcium alginate skin) fiber characteristics. Excellent absorbancy of distilled water and saline solution was observed by the absorption test on cotton fabric treated with CCAC(0.5 wt% calcium alginate) and 0.5 wt% calcium alginate respectively. The SEM photograph confirmed the uniform coating on the cotton fabric surface.

Keywords

References

  1. C. W. Lee, H. J. Lee, and K. Kim, A Study on Deacetylation of Chitin for Preparation of Chitosan, J. Korea Ins. Chem. Eng., 36, 496-501(1998).
  2. R. J. Samuels, Solid State Characterization of the Structure of Chitosan Films, J. Polym. Sci. Poly. Phys. Ed., 19, 1081-1105(1981). https://doi.org/10.1002/pol.1981.180190706
  3. M. J. Kim, T. W. Son, B. G. Kim, D. S. Kim and H. S. Lim, Preparation of Conjugated Cotton with Chitosan Skin, J. Korean Fiber Soc., 41(4), 255-264(2004).
  4. K. Ogura, M. Itoh, T. Kanamoto, and K. Tanaka, Dynamic Mechamical-Behavior of Chitin and Chitosan, Polym. Bull., 2, 301-304(1980). https://doi.org/10.1007/BF00266704
  5. J. Kawada, Y. Abe, T. Yui, K. Okuyama, and K. Ogawa, Crystalline Transformation of Chitosan from Hydrated to Anhydrous Polymorphvia Chitosan Monocarboxylic Acid Salts, J. Carbohydr. Chem., 18, 559-563(1999). https://doi.org/10.1080/07328309908544019
  6. K. E. Park, S. A. Park, G. H. Kim and W. D. Kim, Preparation and Characterization of Sodium Alginate/PEO and Sodium Alginate/PVA Nanofiber, Polymer(Korea), 32(3), 206-212(2008).
  7. S. M. Han, C. W. Nam, and S. W. Ko, Preparation of Alginate Fibers with Antimicrobial Activity, J. Kor. Fib. Soc., 37(7), 365-373(2000).
  8. Y. Qin, H. Hu, and A. Luo, The Conversion of Calcium Alginate Fibers into Alginic Acid Fibers and Sodium Alginate Fibers, J. Appl. Polym. Sci., 101(6), 4216-4221(2006). https://doi.org/10.1002/app.24524
  9. Y. Qin, Gel Swelling Properties of Alginate Fibers, J. Appl. Polym. Sci., 91(3), 1641-1645(2004). https://doi.org/10.1002/app.13317
  10. J. Z. Knaul, S. M. Hudson, and K. A. M. Creber, Crosslinking of Chitosan Fibers with Dialdehyde: Proposal of a New Reaction Mechanism, J. Polym. Sci. Part B : Polym. Phys., 37, 1079-1094(1999). https://doi.org/10.1002/(SICI)1099-0488(19990601)37:11<1079::AID-POLB4>3.0.CO;2-O
  11. X. D. Liu, N. Nishi, S. Tokura, and N. Sakairi, Chitosan Coated Cotton Fiber: Preparation and Physical Properties, Carbohydrate Polymers, 44, 233-238(2001). https://doi.org/10.1016/S0144-8617(00)00206-X
  12. J. W. Cho, T. W. Son, K. S. Lee, B. Y. Kang and H. S. Lim, Improvement of Cotton Fabrics Treated by Chitosan/Silicone Softener Mixing Solution, J. Korean Fiber Soc., 41(4), 270-277(2004).
  13. J. J. Kim, D. W. Jeon, and S. Y. An, A Study on the Change of Hand of Chitosantreated Fabrics, J. Korean Fiber Soc., 34(9), 614-621(1997).
  14. Y. S. Son, K. S. Yang, S. H. Park, H. Y. Kweon, S. I. Kim and C. S. Cho, Polyelectrolyte Complex Composed of Chitosan and Sodium Alginate for Structure Application, J. Chitin Chitosan, 6(1), 7-11(2001).
  15. H. S. Bae, Changes in Mechanical Properties of Sanitary Nonwoven Fabrics by Chitosan/Nanosilver Mixed Solution Treatment, Textile Coloration and Finishing, 22(2), 163-172(2010). https://doi.org/10.5764/TCF.2010.22.2.163
  16. T. Nakajima, H. Itoh, and K. Sugai, Studies on Water Sorption for polymers(5) Sorption of Water-Vapor by Chitosan, Kobunshi Ronbunshu, 37, 705-710(1980). https://doi.org/10.1295/koron.37.705
  17. J. W. Rhim and J. H. Kim, Increase in Moisture Barrier Properties of Alginate-based Films by Composting with Fatty Acids and $CaCl_2$ Treatment, Korean J. Food Sci. Technol., 36(3), 432-439(2004).
  18. S. M. Park, I. J. Kwon, J. Y. Kim, C. N. Kim, J. H. Yeum, and N. S. Yoon, A Study on the Super-hydrophobicity of Poly(ethylene terephthalate) Fabric by $TiO_2$ Nano-particles Coating, Textile Coloration and Finishing, 21(1), 30-37(2009). https://doi.org/10.5764/TCF.2009.21.1.030
  19. J. Brandrup and E. H. Immergut, "Polymer Handbook 3rd. Edition", Wiley, N. Y., p.122, 1989.
  20. J. F. Kennedy, G. O. Phillips, and P. A. Willians, "Cellulose: Structural and Funtional Aspects", Halsted Press, N. Y., pp.35-44, 1989.
  21. G. C. East and Y. Qin, Wet Spinning of Chitosan and the Acetylation of Chitosan Fibers, J. Appl. Polym. Sci., 50, 1773-1779(1993). https://doi.org/10.1002/app.1993.070501013
  22. C. K. Kim, Characteristics of Chitosan-PVA-Alginate Hybrid Scaffold, J. Chitin Chitosan, 15(3), 147-155(2010).
  23. J. J. Kim, D. W. Jeon, and Y. K. Kwon, A Study on the Change of Hand of Chitosan-Treated Fabrics(III)-Effects of Chitosan Treatment Conditions, J. Korean Fiber Soc., 34(10), 689-700(1997).
  24. J. W. Rhim and J. H. Kim, Preparation of Bio-degradable Films Using Various Marine Algae Powder, J. Food Soc. Technol., 36(1), 69-74(2004).
  25. Y. M. Jeon, T. W. Son, M. G. Jeong, M. J. Kim and H. S. Lim, Mechanical Properties of High Add-on Chitosan Treated Cellulose Fabrics, J. Korean Fiber Soc., 40(2), 177-188(2003).

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