• Ceramist
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• v.23 no.2
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• pp.211-230
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• 2020

Perovskite-type oxides with the nominal composition of ABO₃ can exsolve the B-site transition metal upon the controlled reduction. In this exsolution process, the transition metal emerges from the oxide lattice and migrates to the surface at which it forms catalytically active nanoparticles. The exsolved nanoparticles can recover back to the bulk lattice under oxidation treatment. This unique regeneration character by the redox treatment provides uniformly dispersed noble metal nanoparticles. Therefore, the conventional problem of traditional impregnated metal/support, i.e., sintering during reaction, can be effectively avoided by using the exsolution phenomenon. In this regard, the catalysts using the exsolution strategy have been well studied for a wide range of applications in energy conversion and storage devices such as solid oxide fuel cells and electrolysis cells (SOFCs and SOECs) because of its high thermal and chemical stability. On the other hand, although this exsolution strategy can also be applied to gas phase reaction catalysts, it has seldomly been reviewed. Here, we thus review recent applications of the exsolution catalysts to the gas phase reactions from the aspects of experimental measurements, where various functions of the exsolved particles were utilized. We also review non-perovskite type metal oxides that might have exolution phenomenon to provide more possibilities to develop higher efficient catalysts.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.7 no.2
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• pp.79-86
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• 2009

Concrete materials in nuclear facilities may become contaminated or activated by various radionuclides through different mechanism. Decommissioning and dismantling of these facilities produce considerable quantities such as concrete structure, rubble. In this paper, the characteristics distribution of the radionuclide have been investigated for the effects of the heating and grinding test for aggregate size such as gravel, sand and paste from decommissioning of the TRIGA MARK II research reactor and uranium conversion plant. The experimental results showed that most of the radionuclide could be removed from the gravel, sand aggregate and concentrated into a paste. Especially, we found that the heating temperature played an important role in separating the radionuclide from the concrete waste. Contamination of concrete is mainly concentrated in the porous paste and not in the dense aggregate such as the gravel and sand. The volume reduction rate could be achieved about 80% of activated concrete waste and about 75% of dismantled concrete waste generated from UCP.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.11a
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• pp.145-146
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• 2007

Dye-Sensitized Solar Cell Solar cells(DSSC) were appeared for overcoming global environmental problems and lack of fossil fuel problems. And it is one of study field that is getting into the spotlight lately because manufacturing method is more simple and inexpensive than existing silicon solar cells. Oxide semiconductor is used for adsorption of dye and electron transfer in DSSC study, and $TiO_2$ is used most usually. Overall light conversion efficiency is changed by several elements such as $TiO_2$ particle size and structure, pore size and shape. In this study, we report the solar cell performance of titania$(TiO_2)$ film electrodes with various particle sizes. $TiO_2$ particle size was 16 nm, 25 nm, and mixture of 16nm and 25 nm, and manufactured using Doctor blade method. When applied each $TiO_2$ film to DSSC, the best efficiency was found at 16nm of $TiO_2$ particle. 16nm of $TiO_2$ particle has the highest efficiency compared to the others, because particles with smaller diameters would adsorb more dye due to larger surface area. And in case of the mixture of 16nm and 25 nm, the surface area was smaller than expected. It is estimated that double layer is adsorbed a large amount of chemisorbed dye and improved light scattering leading due to efficiency concentration light than mono layer.

• Nuclear Engineering and Technology
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• v.39 no.1
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• pp.9-20
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• 2007

Design study on the Gas Turbine High Temperature Reactor 300-Cogeneration (GTHTR300C) aiming at producing both electricity by a gas turbine and hydrogen by a thermochemical water splitting method (IS process method) has been conducted. It is expected to be one of the most attractive systems to provide hydrogen for fuel cell vehicles after 2030. The GTHTR300C employs a block type Very High Temperature Reactor (VHTR) with thermal power of 600MW and outlet coolant temperature of $950^{\circ}C$. The intermediate heat exchanger (IHX) and the gas turbine are arranged in series in the primary circuit. The IHX transfers the heat of 170MW to the secondary system used for hydrogen production. The balance of the reactor thermal power is used for electricity generation. The GTHTR300C is designed based on the existing technologies of the High Temperature Engineering Test Reactor (HTTR) and helium turbine power conversion and on the technologies whose development have been well under way for IS hydrogen production process so as to minimize cost and risk of deployment. This paper describes the original design features focusing on the plant layout and plant cycle of the GTHTR300C together with present development status of the GTHTR300, IHX, etc. Also, the advantage of the GTHTR300C is presented.

• Applied Chemistry for Engineering
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• v.27 no.2
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• pp.190-194
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• 2016

Tricyclopentadiene (TCPD) is one of the important precursors for making tetrahydrotricyclopentadiene, which is well known as a next-generation fuel with high energy density. In this study, TCPD was obtained by polymerization reaction of dicyclopentadiene (DCPD) using an ionic liquid (IL) supported mesoporous silica catalysts. ILs were supported to two kinds of mesoporous silica catalysts with different pore sizes such as MCM-41 and SBA-15. Four different ILs were supported to mesoporous silicas using anionic precursors such as CuCl or $FeCl_3$ and cationic precursors such as triethylamine hydrochloride or 1-butyl-3-methylimidazolium chloride. We proved that IL supported mesoporous silicas showed better catalytic performance than those of using non-supported prestine IL in the aspect of TCPD yield and DCPD conversion. Among four kinds of IL supported mesoporous silica catalysts, CuCl-based IL supported MCM-41 system showed the highest TCPD yield.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.5
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• pp.627-633
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• 2019

This study aimed to predict the resistance and propulsion performance of a ship using computational fluid dynamics (CFD) and a database as well as establish an assessment method for the energy efficiency design index (EEDI) using the results. First, the total resistance of the studied ship is obtained using CFD. A flow analysis is conducted with the free surface and trim and sinkage using a commercial CFD code (STAR-CCM+). The effective power of the ship is assessed based on the CFD results. The quasi-propulsive efficiency is calculated from an empirical prediction equation using experimental data and similar material. Finally, a general calculation program for the EEDI is established based on the hydrodynamic results, ship information for principal particulars, conversion factor of $CO_2$ for fuels, and fuel consumption.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.508-513
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• 2011

Hemp is known as one of the most productive and useful plants, which grows quickly in a moderate climate with only moderate water and fertilizer. Traditionally in Korea, hemp bast is used to natural fibres, and remaining such as stem and root is treated as waste. Those of hemp by-products can be transformed to bio fuel such as bio-oil and activated carbon. To understand pyrolysis characteristics, thermogravimetric analysis were carried out in TGA, in which hemp by-products were mostly decomposed at the temperature range of $270{\sim}370^{\circ}C$. The corresponding kinetic parameters including activation energy and pre-exponential factor were determined by differential method over the degree of conversions. The values of activation energies for pyrolysis were increased as the conversion increased from 10 to 90%.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.7
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• pp.1067-1073
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• 2021

Regulations to reduce greenhouse gas emissions from ships are gradually being strengthened. EEXI (Energy Efficiency Existing Index) has been introduced in existing ships, and various studies are aimed at achieving the greenhouse gas emission reduction target are currently underway. In this study, we proposed a method to reduce greenhouse gas emissions through reducing fuel oil consumption by applying a solar power generation system to a pure and truck carrier among existing ships engaged in international voyages. The proposed photovoltaic power generation system consists of a photovoltaic module, an energy storage system, and a power conversion device. To confirm applicability, the system was modeled through a power electronics program, and a simulation was performed. In addition, economic analysis was conducted to check the feasibility of application to real ships, and it was confirmed that significant results were derived in the economical aspect after about 11 years had elapsed.

• Journal of the Korean Institute of Gas
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• v.26 no.2
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• pp.21-26
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• 2022

Since the four-wheel drive transmits the driving force to all four wheels, the traction with the road surface increases, thereby increasing the driving force. However, it has the disadvantage of lowering fuel efficiency. Therefore, four-wheel drive is commonly used as a method of converting to optional four-wheel drive when necessary while driving in two-wheel drive. This selective four-wheel drive converts the driving force by mechanically changing the electric signal sent by the driver in the transfer case. In this study, in order to mechanically change the electrical signal, a reducer is applied to the motor to increase the torque to perform the function. Therefore, in this study, a reduction mechanism applicable to the motor inside the transfer case applied to convert the drive is derived, and the reduction ratio applying the planetary gear type is optimized accordingly. And based on the derived reduction ratio, two sets of planetary gears using a ring gear in common were applied to develop a planetary gear tooth type in which the input shaft and output shaft are decelerated in the same phase. Optimization design was carried out.

• Journal of the Microelectronics and Packaging Society
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• v.30 no.4
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• pp.17-31
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• 2023

Amidst escalating global warming fueled by indiscriminate fossil fuel consumption, concerted efforts are underway worldwide to mitigate atmospheric carbon dioxide (CO₂) levels. Electrochemical CO₂ reduction technology is recognized as a promising and environmentally friendly approach to convert CO₂ into valuable hydrocarbon compounds, deemed essential for achieving carbon neutrality. Copper, among the various materials used as CO₂ reduction electrodes, is known as the sole metal capable of generating C₂₊ compounds. However, low conversion efficiency and selectivity have hindered its widespread commercialization. This review highlights diverse research endeavors to address these challenges. It explores various studies focused on utilizing copper-based electrodes for CO₂ reduction, offering insights into potential solutions for advancing this crucial technology.