• 제목/요약/키워드: frequency shifts

검색결과 177건 처리시간 0.028초

밀집된 상자성체 $CuF_{2}$의 초교환 상호작용 (Superexchange in the Dense Paramagnet $CuF_{2}$)

  • Jun Hyeong Kim;Chang Hoon Lee;Cheol Eui Lee
    • 한국자기학회지
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    • 제5권3호
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    • pp.171-174
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    • 1995
  • 성자성 $CuF_{2}$$^{19}F$에 대한 펄스 핵자기공명을 수행하였다. 분말시료에 대하여 상온과 질소온도에서 측정된 선모양은 서로 다른 자리의 $^{19}F$에 대응하는 잘 분리된 두개의 공명선으로 구성되었다. 두 공명선의 서로 다른 주파수 이동량을 구리원자로부터 불소 원자로 부분적으로 이동된 전자에 의한 기여로 해석할 수 있었다. 두 공명선은 모두 매우 짧은 스핀-격자 완화시간($T_{1}$)을 나타내었으며 더 큰 주파수 이동을 나타내는 $^{19}F$ 공명선이 더 짧은 스핀-격자 완화시간을 보였다. 이를 두 $^{19}F$ 자리 주위의 서로 다른 전자 환경이 반영되어 나타난 것으로 해석하였다.

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Dielectric and Transport Properties of Acetonitrile at Varying Temperatures: a Molecular Dynamics Study

  • Orhan, Mehmet
    • Bulletin of the Korean Chemical Society
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    • 제35권5호
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    • pp.1469-1478
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    • 2014
  • Use of acetonitrile in electrolytes promotes better operation of supercapacitors. Recent efforts show that electrolytes containing acetonitrile can also function in a wide range of operating temperatures. Therefore, this paper addresses the dielectric relaxation processes, structure and dynamic properties of the bulk acetonitrile at various temperatures. Systems of acetonitrile were modeled using canonical ensemble and simulated by employing Molecular Dynamics method. Results show that interactions among the molecules were correlated within a cut-off radius while parallel and anti-parallel arrangements are observed beyond this radius at relatively high and low temperatures respectively. Furthermore, effects of C-C-N and C-H bending modes were greatly appreciated on the power spectral density of time rate change of dipole-dipole correlations whereas frequency shifts were observed on all modes at the lowest temperature under consideration. Linear variations with temperature were depicted for reorientation times and self-diffusion coefficients. Shear viscosity was also computed with a good accuracy within a certain range of the temperature as well.

Local dynamic characteristics of PZT impedance interface on tendon anchorage under prestress force variation

  • Huynh, Thanh-Canh;Lee, Kwang-Suk;Kim, Jeong-Tae
    • Smart Structures and Systems
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    • 제15권2호
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    • pp.375-393
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    • 2015
  • In this study, local dynamic characteristics of mountable PZT interfaces are numerically analyzed to verify their feasibility on impedance monitoring of the prestress-loss in tendon anchorage subsystems. Firstly, a prestressed tendon-anchorage system with mountable PZT interfaces is described. Two types of mountable interfaces which are different in geometric and boundary conditions are designed for impedance monitoring in the tendon-anchorage subsystems. Secondly, laboratory experiments are performed to evaluate the impedance monitoring via the two mountable PZT interfaces placed on the tendon-anchorage under the variation of prestress forces. Impedance features such as frequency-shifts and root-mean-square-deviations are quantified for the two PZT interfaces. Finally, local dynamic characteristics of the two PZT interfaces are numerically analyzed to verify their performances on impedance monitoring at the tendon-anchorage system. For the two PZT interfaces, the relationships between structural parameters and local vibration responses are examined by modal sensitivity analyses.

Hydrogen Bonding in Aromatic Alcohol-Water Clusters: A Brief Review

  • Ahn, Doo-Sik;Jeon, In-Sun;Jang, Sang-Hee;Park, Sung-Woo;Lee, Sung-Yul;Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • 제24권6호
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    • pp.695-702
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    • 2003
  • Recent experimental and theoretical advances on the aromatic alcohol-water clusters are reviewed, focusing on the structure of the hydrogen bonding between the alcoholic OH group and the binding water molecules. The interplay of experimental observations and theoretical calculations for the elucidation of the structure is demonstrated for phenol-water, benzyl alcohol-water, substituted phenol-water, naphthol-water and tropolone -water clusters. Discussion is made on assigning the role (either proton-donating or -accepting) of the hydroxyl group by measuring the shifts of infrared frequency of the OH stretching mode in the cluster from that of bare aromatic alcohol for the experimental determination of the cluster structure.

Time Series Simulation of Explosive Charges In Shallow Water Using Ray Approach

  • Hahn, Jooyoung;Lee, Seongwook;Na, Jungyul
    • The Journal of the Acoustical Society of Korea
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    • 제22권3E호
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    • pp.133-140
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    • 2003
  • A time series simulation is presented by a ray approach for the simulating the received waveform of a broadband acoustical signals interacting with the ocean boundaries. The environment is assumed to be horizontally stratified, and the seafloor is described in terms of homogeneous fluid half-space. The ray approach includes the effects of reflection from the air-water, water-sediment interface and phase shifts due to boundaries interaction. To generate time series, we assume that the acoustic energy propagates from source to receiver along eigenrays and represent the action of the bottom on the incident wave by a linear filter and characterized in the frequency domain by the transfer function. As example application, the time series for an explosive source in a shallow water environment is calculated and analyzed in terms of acoustical process. good agreement with measured time series is demonstrated.

2차원 BJT의 전기적 특성 및 왜곡 해석 시뮬레이션 (Simulation for the analysis of distortion and electrical characteristics of a two-dimensional BJT)

  • 이종화;신윤권
    • 전자공학회논문지D
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    • 제35D권4호
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    • pp.84-92
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    • 1998
  • A program was developed to analyze the electrical characteristics and harmonic distrotion in a two-dimensional silicon BJT. The finite difference equations of the small signal and its second and thired harmonics for basic semiconductor equations are formulated treating the nonlinearity and time dependence with Volterra series and Taylor series. The soluations for three sets of simultaneous equations were obtained sequantially by a decoupled iteration method and each set was solved by a modified Stone's algorithm. Distortion magins and ac parameters such as input impedance and current gains are calculated with frequency and load resistance as parameters. The distortion margin vs. load resistancecurves show cancellation minima when the pahse of output voltage shifts. It is shown that the distortionof small signal characteristics can be reduced by reducing the base width, increasing the emitter stripe length and reducing the collector epitaxial layer doping concentration in the silicon BJT structure. The simulation program called TRADAP can be used for the design and optimization of transistors and circuits as well as for the calculation of small signal and distortion solutions.

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휴대전화 단말기용 전파흡수체의 개발에 관한 연구 (A Study on Development of EM Wave Absorbers for Mobile Phones)

  • 정재현;김동일
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 후기학술대회논문집
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    • pp.67-68
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    • 2005
  • This thesis is concerned with basic research for development of EM wave absorbers in sheet type for mobile phones. By controlling the sendust ratio, the $Al(OH)_3$ coating, the thickness, the kind of binders, EM wave absorbers were prepared and examined. Centeral frequency shifts toward lower with increasing thickness of the absorber, and absorption ability controlled to adjust Sendust amount. The absorption band of the EM wave absorber coated with $Al(OH)_3$ becomes larger than that of non-coated one. Sendust composite microwave absorbers mixed with CPE were prepared at $70^{\circ}C$ in temperature. The fabricated EM wave absorbers show a reflection coefficient 5.56 dB at 1.8 GHz in thickness of 0.85 mm.

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캐비티-유도된 원자측정 장치 (A Cavity-Assisted Atom Detector (CAAD))

  • Chough, Young-Tak;Hyuncheol Nha;Kyungwon An
    • 한국광학회:학술대회논문집
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    • 한국광학회 2000년도 제11회 정기총회 및 00년 동계학술발표회 논문집
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    • pp.124-125
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    • 2000
  • We introduce a scheme with a maximized efficiency of detecting atoms passing through an optical standing-wave mode cavity. Consider a standing-wave optical cavity illuminated by a weak probe beam through one of its mirrors where the transmission through the other mirror is monitored by a photodetector. If an atom is put in the cavity, the atom-cavity coupling shifts the resonance frequency of the system via the so-called normal mode splitting, and thereby the transmission power will drop. In fact, this type of atom detection scheme has been used in recent single atom trap experiments In practice, however, the field in a standing-wave mode will have a geometrical structure having nodes and antinodes that when the atom traverses the cavity through one of the nodes, there will be no such effect of atom-field interaction. (omitted)

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위상천이 영사식 모아레법을 이용한 고속 3차원 형상복원 (East 3-Dimensional Shape Reconstruction Using Phase-Shifting Grating Projection Moire Method)

  • 최이배;구본기;정연구
    • 한국감성과학회:학술대회논문집
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    • 한국감성과학회 1998년도 추계학술발표 논문집
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    • pp.111-115
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    • 1998
  • A phase-shifting projection moire method particularly intended for high-speed three-dimensional shape reconstruction of diffuse objects is presented. Emphasis is on realization of phase-shifting fringe analysis in projection moire topography using a set of line grating pairs designed to provide different phase shifts in sequence. Further a time-integral fringe capturing scheme is devised to remove undesirable high frequency original grating patterns in real-time without time-consuming software image processing. Finally the performances of the proposed method are discussed with measurement results.

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헬름홀쯔 공명기에서 외부로의 누출 (External Leakage on Helmholtz Resonators)

  • 이일재
    • 한국소음진동공학회논문집
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    • 제23권8호
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    • pp.752-758
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    • 2013
  • The effect of external leakage on the acoustic performance of Helmholtz resonators is experimentally and numerically investigated. The transmission loss of the Helmholtz resonator with a circular perforated hole is measured by using an impedance tube setup. The experimental results are then compared with one-dimensional analytical and three-dimensional numerical results. As the size of the hole increases, the peak of the transmission loss shifts to higher frequency, especially for the holes on the cavity. While the transmission loss is almost independent of the location of the hole on the cavity, the impact of the hole location on the neck on the transmission loss is not negligible. The results show that one-dimensional analytical method can predict the overall trends, whereas three-dimensional numerical method is necessary for more accurate predictions.