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http://dx.doi.org/10.5012/bkcs.2003.24.6.695

Hydrogen Bonding in Aromatic Alcohol-Water Clusters: A Brief Review  

Ahn, Doo-Sik (School of Environmental Science and Applied Chemistry, Kyunghee University)
Jeon, In-Sun (School of Environmental Science and Applied Chemistry, Kyunghee University)
Jang, Sang-Hee (School of Environmental Science and Applied Chemistry, Kyunghee University)
Park, Sung-Woo (School of Environmental Science and Applied Chemistry, Kyunghee University)
Lee, Sung-Yul (School of Environmental Science and Applied Chemistry, Kyunghee University)
Cheong, Won-Jo (Department of Chemistry, Inha University)
Publication Information
Bulletin of the Korean Chemical Society / v.24, no.6, 2003 , pp. 695-702 More about this Journal
Abstract
Recent experimental and theoretical advances on the aromatic alcohol-water clusters are reviewed, focusing on the structure of the hydrogen bonding between the alcoholic OH group and the binding water molecules. The interplay of experimental observations and theoretical calculations for the elucidation of the structure is demonstrated for phenol-water, benzyl alcohol-water, substituted phenol-water, naphthol-water and tropolone -water clusters. Discussion is made on assigning the role (either proton-donating or -accepting) of the hydroxyl group by measuring the shifts of infrared frequency of the OH stretching mode in the cluster from that of bare aromatic alcohol for the experimental determination of the cluster structure.
Keywords
Hydrogen bonding; Aromatic alcohol; Water; Cluster;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By Web Of Science : 16  (Related Records In Web of Science)
Times Cited By SCOPUS : 16
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