• Title/Summary/Keyword: frequency shifts

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Superexchange in the Dense Paramagnet $CuF_{2}$ (밀집된 상자성체 $CuF_{2}$의 초교환 상호작용)

  • Jun Hyeong Kim;Chang Hoon Lee;Cheol Eui Lee
    • Journal of the Korean Magnetics Society
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    • v.5 no.3
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    • pp.171-174
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    • 1995
  • We have studied the paramagnetic $CuF_{2}$ using the techniques of pulsed nuclear magnetic resonance(NMR). The powder sample revealed two well-separated lines from the distinct $^{19}F$ sites at room temperature and at 77 K. The distinct frequency shifts of the two lines appear to arise from electron transfers. Furthermore, the two sites have very short spin-lattice relaxation times ($T_{1}$). The frequency-shifted site has the shorter $T_{1}$ than the unshifted one, reflecting the difference of the electron environments of the two sites.

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Dielectric and Transport Properties of Acetonitrile at Varying Temperatures: a Molecular Dynamics Study

  • Orhan, Mehmet
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1469-1478
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    • 2014
  • Use of acetonitrile in electrolytes promotes better operation of supercapacitors. Recent efforts show that electrolytes containing acetonitrile can also function in a wide range of operating temperatures. Therefore, this paper addresses the dielectric relaxation processes, structure and dynamic properties of the bulk acetonitrile at various temperatures. Systems of acetonitrile were modeled using canonical ensemble and simulated by employing Molecular Dynamics method. Results show that interactions among the molecules were correlated within a cut-off radius while parallel and anti-parallel arrangements are observed beyond this radius at relatively high and low temperatures respectively. Furthermore, effects of C-C-N and C-H bending modes were greatly appreciated on the power spectral density of time rate change of dipole-dipole correlations whereas frequency shifts were observed on all modes at the lowest temperature under consideration. Linear variations with temperature were depicted for reorientation times and self-diffusion coefficients. Shear viscosity was also computed with a good accuracy within a certain range of the temperature as well.

Local dynamic characteristics of PZT impedance interface on tendon anchorage under prestress force variation

  • Huynh, Thanh-Canh;Lee, Kwang-Suk;Kim, Jeong-Tae
    • Smart Structures and Systems
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    • v.15 no.2
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    • pp.375-393
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    • 2015
  • In this study, local dynamic characteristics of mountable PZT interfaces are numerically analyzed to verify their feasibility on impedance monitoring of the prestress-loss in tendon anchorage subsystems. Firstly, a prestressed tendon-anchorage system with mountable PZT interfaces is described. Two types of mountable interfaces which are different in geometric and boundary conditions are designed for impedance monitoring in the tendon-anchorage subsystems. Secondly, laboratory experiments are performed to evaluate the impedance monitoring via the two mountable PZT interfaces placed on the tendon-anchorage under the variation of prestress forces. Impedance features such as frequency-shifts and root-mean-square-deviations are quantified for the two PZT interfaces. Finally, local dynamic characteristics of the two PZT interfaces are numerically analyzed to verify their performances on impedance monitoring at the tendon-anchorage system. For the two PZT interfaces, the relationships between structural parameters and local vibration responses are examined by modal sensitivity analyses.

Hydrogen Bonding in Aromatic Alcohol-Water Clusters: A Brief Review

  • Ahn, Doo-Sik;Jeon, In-Sun;Jang, Sang-Hee;Park, Sung-Woo;Lee, Sung-Yul;Cheong, Won-Jo
    • Bulletin of the Korean Chemical Society
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    • v.24 no.6
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    • pp.695-702
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    • 2003
  • Recent experimental and theoretical advances on the aromatic alcohol-water clusters are reviewed, focusing on the structure of the hydrogen bonding between the alcoholic OH group and the binding water molecules. The interplay of experimental observations and theoretical calculations for the elucidation of the structure is demonstrated for phenol-water, benzyl alcohol-water, substituted phenol-water, naphthol-water and tropolone -water clusters. Discussion is made on assigning the role (either proton-donating or -accepting) of the hydroxyl group by measuring the shifts of infrared frequency of the OH stretching mode in the cluster from that of bare aromatic alcohol for the experimental determination of the cluster structure.

Time Series Simulation of Explosive Charges In Shallow Water Using Ray Approach

  • Hahn, Jooyoung;Lee, Seongwook;Na, Jungyul
    • The Journal of the Acoustical Society of Korea
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    • v.22 no.3E
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    • pp.133-140
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    • 2003
  • A time series simulation is presented by a ray approach for the simulating the received waveform of a broadband acoustical signals interacting with the ocean boundaries. The environment is assumed to be horizontally stratified, and the seafloor is described in terms of homogeneous fluid half-space. The ray approach includes the effects of reflection from the air-water, water-sediment interface and phase shifts due to boundaries interaction. To generate time series, we assume that the acoustic energy propagates from source to receiver along eigenrays and represent the action of the bottom on the incident wave by a linear filter and characterized in the frequency domain by the transfer function. As example application, the time series for an explosive source in a shallow water environment is calculated and analyzed in terms of acoustical process. good agreement with measured time series is demonstrated.

Simulation for the analysis of distortion and electrical characteristics of a two-dimensional BJT (2차원 BJT의 전기적 특성 및 왜곡 해석 시뮬레이션)

  • 이종화;신윤권
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.35D no.4
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    • pp.84-92
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    • 1998
  • A program was developed to analyze the electrical characteristics and harmonic distrotion in a two-dimensional silicon BJT. The finite difference equations of the small signal and its second and thired harmonics for basic semiconductor equations are formulated treating the nonlinearity and time dependence with Volterra series and Taylor series. The soluations for three sets of simultaneous equations were obtained sequantially by a decoupled iteration method and each set was solved by a modified Stone's algorithm. Distortion magins and ac parameters such as input impedance and current gains are calculated with frequency and load resistance as parameters. The distortion margin vs. load resistancecurves show cancellation minima when the pahse of output voltage shifts. It is shown that the distortionof small signal characteristics can be reduced by reducing the base width, increasing the emitter stripe length and reducing the collector epitaxial layer doping concentration in the silicon BJT structure. The simulation program called TRADAP can be used for the design and optimization of transistors and circuits as well as for the calculation of small signal and distortion solutions.

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A Study on Development of EM Wave Absorbers for Mobile Phones (휴대전화 단말기용 전파흡수체의 개발에 관한 연구)

  • Jung, Jae-Hyun;Kim, Dong-Il
    • Proceedings of the Korean Society of Marine Engineers Conference
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    • 2005.11a
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    • pp.67-68
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    • 2005
  • This thesis is concerned with basic research for development of EM wave absorbers in sheet type for mobile phones. By controlling the sendust ratio, the $Al(OH)_3$ coating, the thickness, the kind of binders, EM wave absorbers were prepared and examined. Centeral frequency shifts toward lower with increasing thickness of the absorber, and absorption ability controlled to adjust Sendust amount. The absorption band of the EM wave absorber coated with $Al(OH)_3$ becomes larger than that of non-coated one. Sendust composite microwave absorbers mixed with CPE were prepared at $70^{\circ}C$ in temperature. The fabricated EM wave absorbers show a reflection coefficient 5.56 dB at 1.8 GHz in thickness of 0.85 mm.

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A Cavity-Assisted Atom Detector (CAAD) (캐비티-유도된 원자측정 장치)

  • Chough, Young-Tak;Hyuncheol Nha;Kyungwon An
    • Proceedings of the Optical Society of Korea Conference
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    • 2000.02a
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    • pp.124-125
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    • 2000
  • We introduce a scheme with a maximized efficiency of detecting atoms passing through an optical standing-wave mode cavity. Consider a standing-wave optical cavity illuminated by a weak probe beam through one of its mirrors where the transmission through the other mirror is monitored by a photodetector. If an atom is put in the cavity, the atom-cavity coupling shifts the resonance frequency of the system via the so-called normal mode splitting, and thereby the transmission power will drop. In fact, this type of atom detection scheme has been used in recent single atom trap experiments In practice, however, the field in a standing-wave mode will have a geometrical structure having nodes and antinodes that when the atom traverses the cavity through one of the nodes, there will be no such effect of atom-field interaction. (omitted)

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East 3-Dimensional Shape Reconstruction Using Phase-Shifting Grating Projection Moire Method (위상천이 영사식 모아레법을 이용한 고속 3차원 형상복원)

  • 최이배;구본기;정연구
    • Proceedings of the Korean Society for Emotion and Sensibility Conference
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    • 1998.11a
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    • pp.111-115
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    • 1998
  • A phase-shifting projection moire method particularly intended for high-speed three-dimensional shape reconstruction of diffuse objects is presented. Emphasis is on realization of phase-shifting fringe analysis in projection moire topography using a set of line grating pairs designed to provide different phase shifts in sequence. Further a time-integral fringe capturing scheme is devised to remove undesirable high frequency original grating patterns in real-time without time-consuming software image processing. Finally the performances of the proposed method are discussed with measurement results.

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External Leakage on Helmholtz Resonators (헬름홀쯔 공명기에서 외부로의 누출)

  • Lee, Iljae
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.23 no.8
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    • pp.752-758
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    • 2013
  • The effect of external leakage on the acoustic performance of Helmholtz resonators is experimentally and numerically investigated. The transmission loss of the Helmholtz resonator with a circular perforated hole is measured by using an impedance tube setup. The experimental results are then compared with one-dimensional analytical and three-dimensional numerical results. As the size of the hole increases, the peak of the transmission loss shifts to higher frequency, especially for the holes on the cavity. While the transmission loss is almost independent of the location of the hole on the cavity, the impact of the hole location on the neck on the transmission loss is not negligible. The results show that one-dimensional analytical method can predict the overall trends, whereas three-dimensional numerical method is necessary for more accurate predictions.