• Title/Summary/Keyword: fluoride application

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Fabrication of Poly(Vinylidene Fluoride) Nanocomposite Fibers Containing Zinc Oxide Nanoparticles and Silver Nanowires and their Application in Textile Sensors for Motion Detection and Monitoring (산화아연(Zinc oxide) 나노입자와 은나노 와이어(Silver nanowire)를 함유한 Poly(vinylidene fluoride) 복합나노섬유 제조 및 동작 센서로의 적용 가능성 탐색)

  • Hyukjoo Yang;Seungsin Lee
    • Journal of the Korean Society of Clothing and Textiles
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    • v.47 no.3
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    • pp.577-592
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    • 2023
  • In this study, nanofiber-based textile sensors were developed for motion detection and monitoring. Poly(vinylidene fluoride) (PVDF) nanofibers containing zinc oxide (ZnO) nanoparticles and silver nanowires (AgNW) were fabricated using electrospinning. PVDF was chosen as a piezoelectric polymer, zinc oxide as a piezoelectric ceramic, and AgNW as a metal to improve electric conductivity. The PVDF/ZnO/AgNW nanocomposite fibers were used to develop a textile sensor, which was then incorporated into an elbow band to develop a wearable smart band. Changes in the output voltage and peak-to-peak voltage (Vp-p) generated by the joint's flexion and extension were investigated using a dummy elbow. The β-phase crystallinity of pure PVDF nanofibers was 58% when analyzed using Fourier transform infrared spectroscopy; however, the β-phase crystallinity increased to 70% in PVDF nanofibers containing ZnO and to 78% in PVDF nanocomposite fibers containing both ZnO and AgNW. The textile sensor's output voltage values varied with joint-bending angle; upon increasing the joint angle from 45° to 90° to 150°, the Vp-p value increased from 0.321 Vp-p to 0.542 Vp-p to 0.660 Vp-p respectively. This suggests that the textile sensor can be used to detect and monitor body movements.

PAMPANT DENTAL CARIES의 예방

  • Koo, Chang-Soo
    • The Journal of the Korean dental association
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    • v.12 no.10
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    • pp.767-770
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    • 1974
  • A 12 years old patient having rampant dental caries on permanent dentition has been treated under operative procedures. In addition to this operative treatment the nutritional survey and the caries activity was checked, and performed the oral hygiene instruction to the patient. As the consequences of above procedures the following results were obtained: 1. The familial history and eating habits checkings were helpful for better dental health guide and caries control. 2. The restriction of mono & disaccharide intake and topical application of 8% stannous fluoride at least two times revealed excellent control effect for recurrent dental caries.

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The Surface Characteristics of Enamel according to Fluoride Application Methods and Frequency (불소 도포 방법과 적용 횟수에 따른 법랑질의 표면 특성)

  • Jang, Sun-Ok;Choi, Eun-Mi;Oh, Sang-Hwan;Kang, Min-Kyung;Kim, Kwang-Man
    • Journal of dental hygiene science
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    • v.11 no.2
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    • pp.69-76
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    • 2011
  • The aim of this study was to compare the effects on the resistance to demineralization by the frequency and method of fluoride application in vitro. ninety-one human enamel specimens were embedded in acrylic resin with the labial surfaces exposes. The specimens were divided into 7 groups; (1) non-treated; (2) 1.23% APF gel 1 time; (3) 2% NaF sol 1 time; (4) 2% NaF sol iontophoresis 1 time; (5) 1.23% APF gel 4 time; (6) 2% NaF sol 4 time; (7) 2% NaF sol iontophoresis 4 time. All the groups were immersed in the remineralizing solution (RS) before baseline and divided into 7 test groups of 13 specimens each. All the specimens were exposed to a pH-cycling model which consisted of demineralization (6 hours) and remineralization (18 hours) for 5 days. The Vickers surface micro-hardness number of all the specimens was measured using microhardness tester and the specimen surfaces were observed by scanning electron microscope (SEM). The results were analyzed using one-way ANOVA followed a Tukey's multiple comparison at a significance level of 0.05. The group 7 showed higher level of microhardness after Fluoride application. The group 1 showed lowest level of microhardness but group 7 showed higher level of microhardness after pH-cycling model, there were significant differences between groups. After the modified pH-cycling, the 2% NaF solution with the iontophoresis group showed the best resistance to demineralization(p<0.05). These results were also confirmed by SEM. The fluoride iontophoresis method was the most effective of the regimens in increasing the acid resistance of the enamel.

Novel Tm(III) Membrane Sensor Based on 2,2'-Dianiline Disulfide and Its Application for the Fluoride Monitoring of Mouth Wash Preparations

  • Ganjali, Mohammad Reza;Norouzi, Parviz;Tamaddon, Atefeh;Husain, Syed Waqif
    • Bulletin of the Korean Chemical Society
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    • v.27 no.9
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    • pp.1418-1422
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    • 2006
  • In this work the construction of a novel poly(vinyl chloride) membrane sensor based on 2,2'-dianiline disulfide (DADS) as a neutral carrier, o-nitrophenyloctyl ether (NPOE) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic site with unique selectivity towards Tm(III) ions is reported. The electrode has a linear dynamic range between $1.0\;{\times}\;10^{-6}$ and $1.0\;{\times}\;10^{-2}$ M, with a nice Nernstian slope of 19.5 ${\pm}$ 0.3 mV per decade and a detection limit of $4.0\;{\times}\;10^{-7}$ M at the pH range of 4.8-8.5. It has a very fast response time (<15 s) in the whole concentration range, and can be used for at least 4 weeks without any considerable divergence in the electrode potentials. The proposed sensor revealed comparatively good selectivity with respect to most common metal ions, and especially lanthanide ions. It was used as an indicator electrode in the potentiometric titration of Tm(III) ions with EDTA and in direct determination of concentration of Tm(III) ions in binary mixtures. It was also applied in determination of fluoride ions in mouth wash preparations.

Removal of Natural Organic Matter (NOM) by Carbon Nanotubes Modified PVDF Membrane (탄소나노튜브(CNT)-PVDF 막을 이용한 자연용존유기물 제거)

  • Cho, Hyun-Hee;Cha, Min-Whan;Park, Jae-Woo
    • Journal of Korean Society on Water Environment
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    • v.28 no.1
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    • pp.148-156
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    • 2012
  • In this research, the application of carbon nanotubes (CNTs) modified PVDF (polyvinylidene fluoride) membrane was tested as a simply and beginning attempt to overcome membrane fouling because CNTs importantly affect the transport of natural organic matter (NOM). Suwannee River fulvic acid (SRFA) as the representative of NOM was selected and its sorption results with single-walled CNT (SWCNT), multi-walled CNT (MWCNT), and oxidized MWCNT (O-MWCNT) were obtained through the batch experiment. SRFA sorption isotherms had a strong nonlinearity and its sorption capacity followed the order O-MWCNT < MWCNT < SWCNT. The adsorbed mass of SRFA on each CNT decreased as a function of pH due to their charge repulsion. For the CNT-PVDF membrane filtration experiments, the suspended CNT solution (10 mg/40 mL) was incorporated into $0.45{\mu}m$-PVDF membrane and 5 mg/L of SRFA solution was monitored using UV detector connected with high pressure pump after passing through CNT-PVDF membrane. The SRFA removal efficiency by MWCNT-PVDF membrane was the strongest among other modified membranes. This suggests that the CNT modified microfiltration (MF) membrane might effectively and selectively apply to treat the contaminated water including organic compounds in the presence of NOM.

Effects of Fluoride Additions on Sintering and Microwave Dielectric Properties of CaWO$_4$ (Fluoride 첨가에 따른 CaWO$_4$의 소결 및 고주파 유전특성)

  • 이경호;김용철;방재철
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07a
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    • pp.127-130
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    • 2002
  • In this study, development of a new LTCC material using a non-glassy system was attempted with respect to reducing the fabrication process steps and cost down. Lowering the sintering temperature can be achieved by liquid phase sintering. For LTCC application, the starting material must have quality factor as high as possible in microwave frequency range. And also, the material should have a low dielectric constant for enhancing the signal propagation speed. Regarding these factors, dielectric constants of various materials were estimated by the Clausius-Mosotti equation. Among them, CaWO$_4$ was tamed out the suitable LTCC material. CaWO$_4$ can be sintered up to 98% of full density at 1200$^{\circ}C$ for 3 hours. It's measured dielectric constant, quality factor, and temperature coefficient of resonant frequency were 10.15, 62880GHz, and -27.8ppm/$^{\circ}C$, respectively. In order to modify the dielectric properties and densification temperature, 0.5∼1.5 wt% LiF were added to CaWO$_4$. LiF addition reduced the sintering temperature/time down to 800$^{\circ}C$/10∼30min due to the reactive liquid phase sintering. Dielectric constant lowered from 10.15 to 9.38 and Q x fo increased up to 92000GHz with increasing LiF content.

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A Case of Chemical Burn Caused by Trifluoroacetic Anhydride that Mimicked a Hydrofluoric Acid Burn (불화수소산에 의한 것으로 오인된 Trifluoroacetic anhydride에 의한 화학화상)

  • Park, Jung-Soo;Kim, Hoon;Lee, Suk-Woo
    • Journal of The Korean Society of Clinical Toxicology
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    • v.8 no.1
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    • pp.43-45
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    • 2010
  • A 22-year-old woman was referred to our emergency department for the treatment of a chemical injury on her arm. She had accidentally spilled 99% trifluoroacetic anhydride (TFAA) over her left forearm during an organic chemistry experiment. She visited a primary care unit, and then she was referred to our hospital for inactivation of the released fluoride ions. Her skin lesions were different from those caused by hydrofluoric acid (HF) injury. The injured area showed painful whitish maculae and patchy areas with accentuated rim. No vesiculation and bulla formation was detected. We intradermally injected a 5% solution of calcium through a 24-gauge needle into the burned skin. After the injection, she complained of more severe pain. Although TFAA contains fluorine, it does not release free fluoride ions on contact with the skin, unlike HF. In fact, application of calcium gluconate for TFAA burns is not recommended. Rather, it should be avoided since it increases pain and local abscess formation.

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Initial estimates of the economical attractiveness of a nuclear closed Brayton combined cycle operating with firebrick resistance-heated energy storage

  • Chavagnat, Florian;Curtis, Daniel
    • Nuclear Engineering and Technology
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    • v.50 no.3
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    • pp.488-493
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    • 2018
  • The Firebrick Resistance-Heated Energy Storage (FIRES) concept developed by the Massachusetts Institute of Technology aims to enhance profitability of the nuclear power industry in the next decades. Studies carried out at Massachusetts Institute of Technology already provide estimates of the potential revenue from FIRES system when it is applied to industrial heat supply, the likely first application. Here, we investigate the possibility of operating a power plant (PP) with a fluoride-salt-cooled high-temperature reactor and a closed Brayton cycle. This variant offers features such as enhanced nuclear safety as well as flexibility in design of the PP but also radically changes the way of operating the PP. This exploratory study provides estimates of the revenue generated by FIRES in addition to the nominal revenue of the stand-alone fluoride-salt-cooled high-temperature reactor, which are useful for defining an initial design. The electricity price data is based on the day-ahead markets of Germany/Austria and the United States (Iowa). The proposed method derives from the equation of revenue introduced in this study and involves simple computations using MatLab to compute the estimates. Results show variable economic potential depending on the host grid but stress a high profitability in both regions.

Synthesis, interfacial property, and application of new hybrid anion surfactant containing fluorocarbon and hydrocarbon chains

  • Kang, Eun-kyung;Sohn, Eun-Ho;Jung, Ga Young;Jung, Seon Hwa;Ha, Jong-Wook;Lee, Soo-Bok;Park, In Jun;Lee, Byung Min
    • Journal of Industrial and Engineering Chemistry
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    • v.67
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    • pp.72-79
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    • 2018
  • Hybrid F2HX surfactants bearing a sulfate moiety and both hydrocarbon and fluorocarbon chains were prepared by the reaction of alkyl glycidyl ethers with fluoro-alcohol, and subsequent sulfation. The fluorocarbon number in F2HX was fixed at the shortest number possible (i.e., 2), while the hydrocarbon number (X) in the second chain was varied between 2, 4, 6, and 8. Their surface-active properties and emulsion stabilities were systematically estimated as a function of the X. Among them, F2H8 exhibited the optimal surfactant performance, which was comparable to previously reported surfactants and it was successfully applied in the emulsion polymerization of vinylidene fluoride.

A study on the preventive dental service experience and dental fear (예방치과서비스 경험 유무와 치과 공포도에 관한 연구)

  • Kim, Soo-Kyung;Park, Ha-Ran;Lee, Da-Eun;Lee, Su-Jeong;Jung, Eun-Seo
    • Journal of Korean society of Dental Hygiene
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    • v.18 no.3
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    • pp.335-346
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    • 2018
  • Objectives: This study was conducted to examine the degree of dental fear according to the experiences of the preventive dental care services. Methods: A self-administered survey was conducted in the subjects of male and female teenagers who lived in Seoul and Gyeonggi-do areas, and 231 copies of collected data for a month from July 26, 2017 were analyzed to find the following results. Results: In terms of the experiences of the preventive dental care services, they were classified in the order of preventive scaling (67.5%), education of toothbrushing (60.6%), fluoride application (49.8%) and sealant (44.2%). For the degree of dental fear according to their general characteristics, treatment avoidance factor ($2.56{\pm}1.19$) in the married was higher than that in the unmarried. All of treatment avoidance, physiological response and fearful stimulus induction factor, and the entire degree of fear were higher when there were experiences of the preventive dental care services than those without such experiences. The factors affecting the degree of dental fear included dental health conditions, experiences of toothbrushing education, sealant and fluoride application. In case those without the experiences considered their dental health condition was not healthy, the degree of dental fear was increased. Conclusions: This study verified that the degree of dental fear was increased in case no experiences of the preventive dental care services. Therefore, it is necessary to seek out the measures for promotion of the preventive dental care services, to reduce the degree of dental fear and enhance the dental health.