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http://dx.doi.org/10.1016/j.jiec.2018.06.016

Synthesis, interfacial property, and application of new hybrid anion surfactant containing fluorocarbon and hydrocarbon chains  

Kang, Eun-kyung (Advanced Materials and Chemical Engineering, University of Science and Technology)
Sohn, Eun-Ho (Advanced Materials and Chemical Engineering, University of Science and Technology)
Jung, Ga Young (Advanced Materials and Chemical Engineering, University of Science and Technology)
Jung, Seon Hwa (Center for Interface Chemistry and Engineering, Korea Research Institute of Chemical Technology)
Ha, Jong-Wook (Center for Interface Chemistry and Engineering, Korea Research Institute of Chemical Technology)
Lee, Soo-Bok (Center for Interface Chemistry and Engineering, Korea Research Institute of Chemical Technology)
Park, In Jun (Advanced Materials and Chemical Engineering, University of Science and Technology)
Lee, Byung Min (Advanced Materials and Chemical Engineering, University of Science and Technology)
Publication Information
Journal of Industrial and Engineering Chemistry / v.67, no., 2018 , pp. 72-79 More about this Journal
Abstract
Hybrid F2HX surfactants bearing a sulfate moiety and both hydrocarbon and fluorocarbon chains were prepared by the reaction of alkyl glycidyl ethers with fluoro-alcohol, and subsequent sulfation. The fluorocarbon number in F2HX was fixed at the shortest number possible (i.e., 2), while the hydrocarbon number (X) in the second chain was varied between 2, 4, 6, and 8. Their surface-active properties and emulsion stabilities were systematically estimated as a function of the X. Among them, F2H8 exhibited the optimal surfactant performance, which was comparable to previously reported surfactants and it was successfully applied in the emulsion polymerization of vinylidene fluoride.
Keywords
Hybrid anion surfactant; Fluorocarbon chain; Surface-active property; Emulsion polymerization; Vinylidene fluoride;
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