Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
권호 표지
DOI QR코드

DOI QR Code

Novel Tm(III) Membrane Sensor Based on 2,2'-Dianiline Disulfide and Its Application for the Fluoride Monitoring of Mouth Wash Preparations

  • Ganjali, Mohammad Reza (Center of Excellence in Electrochemistry, Department of Chemistry, University of Tehran) ;
  • Norouzi, Parviz (Center of Excellence in Electrochemistry, Department of Chemistry, University of Tehran) ;
  • Tamaddon, Atefeh (Department of Chemistry, Science and Research Unit, Islamic Azad University) ;
  • Husain, Syed Waqif (Faculty of Chemistry, University of Tarbiat Moallem)
  • Published : 2006.09.20
Download PDF
⟨ Previous Next ⟩

Abstract

In this work the construction of a novel poly(vinyl chloride) membrane sensor based on 2,2'-dianiline disulfide (DADS) as a neutral carrier, o-nitrophenyloctyl ether (NPOE) as a plasticizer and sodium tetraphenyl borate (NaTPB) as an anionic site with unique selectivity towards Tm(III) ions is reported. The electrode has a linear dynamic range between $1.0\;{\times}\;10^{-6}$ and $1.0\;{\times}\;10^{-2}$ M, with a nice Nernstian slope of 19.5 ${\pm}$ 0.3 mV per decade and a detection limit of $4.0\;{\times}\;10^{-7}$ M at the pH range of 4.8-8.5. It has a very fast response time (<15 s) in the whole concentration range, and can be used for at least 4 weeks without any considerable divergence in the electrode potentials. The proposed sensor revealed comparatively good selectivity with respect to most common metal ions, and especially lanthanide ions. It was used as an indicator electrode in the potentiometric titration of Tm(III) ions with EDTA and in direct determination of concentration of Tm(III) ions in binary mixtures. It was also applied in determination of fluoride ions in mouth wash preparations.

Keywords

References

  1. El-Sherif, A. F.; King, T. A. Lasers Medical Science 2003, 18, 139 https://doi.org/10.1007/s10103-003-0267-5
  2. Kakui, M.; Shitomi, T.; Hirose, C.; Hatayama, H.; Shigematsu, M. Optics Communications 2003, 221, 87 https://doi.org/10.1016/S0030-4018(03)01467-6
  3. Zang, F. X.; Hong, Z. R.; Li, W. L.; Li, M. T.; Sun, X. Y. Applied Physics Letters 2004, 84, 2679 https://doi.org/10.1063/1.1695098
  4. Lee, S. K.; Chung, T. D.; Kim, H. Electroanalysis 1997, 9, 527 https://doi.org/10.1002/elan.1140090704
  5. Takehara, K.; Aihara, M.; Ueda, N. Electroanalysis 1994, 6, 1083 https://doi.org/10.1002/elan.1140061128
  6. Bakker, E.; Buhlmann, P.; Pretsch, E. Chem. Rev. 1997, 97, 3083 https://doi.org/10.1021/cr940394a
  7. Ganjali, M. R.; Daftari, A.; Qomi, M.; Norouzi, P. Sens. Actuators B 2004, 98, 92 https://doi.org/10.1016/j.snb.2003.09.028
  8. Ganjali, M. R.; Daftari, A.; Rezapour, M. Talanta 2003, 59, 613 https://doi.org/10.1016/S0039-9140(02)00573-8
  9. Shamsipur, M.; Yousefi, M.; Hosseini, M.; Ganjali, M. R. Anal. Chem. 2002, 74, 5538 https://doi.org/10.1021/ac0110451
  10. Hassanien, M. M.; Abou-El-Sherbini, K. S.; Mostafa, G. A. E. Talanta 2003, 59, 392
  11. Itot, T.; Goto, C.; Noguchi, K. Anal. Chim. Acta 2001, 443, 41 https://doi.org/10.1016/S0003-2670(01)01192-8
  12. Susheel, K.; Mittal, S. K.; Kumar, A.; Sharma, H. K. Talanta 2004, 62, 801 https://doi.org/10.1016/j.talanta.2003.10.001
  13. Ganjali, M. R.; Kiani, R.; Shamsipur, M.; Poursaberi, T.; Salavati-Niasari, M.; Talebpour, Z.; Emami, M. Electroanalysis 2004, 16, 1002 https://doi.org/10.1002/elan.200302899
  14. Gupta, V.; Suresh, C.; Chandra, C. Anal. Chim. Acta 2003, 486, 199 https://doi.org/10.1016/S0003-2670(03)00506-3
  15. Shamsipur, M.; Yousefi, M.; Ganjali, M. R. Anal. Chem. 2000, 72, 2391 https://doi.org/10.1021/ac991155w
  16. Karami, H.; Mousavi, M. H.; Shamsipour, M.; Yavari, I.; Alizadeh, A. A. Anal. Lett. 2003, 36, 1065 https://doi.org/10.1081/AL-120020143
  17. Shamsipur, M.; Yousefi, M.; Hosseini, M.; Ganjali, M. R. Anal. Lett. 2001, 34, 2249 https://doi.org/10.1081/AL-100107292
  18. Akhond, M.; Najafi, M. F.; Tashkhourian, M. F. Anal. Chim. Acta 2005, 531, 179 https://doi.org/10.1016/j.aca.2004.09.089
  19. Gaber, A. A. A. Anal. Lett. 2003, 36, 2585 https://doi.org/10.1081/AL-120024634
  20. Ganjali, M. R.; Pourjavid, M. R.; Rezapour, M.; Haghgoo, V. Sens. Actuators B 2003, 89, 21 https://doi.org/10.1016/S0925-4005(02)00422-7
  21. Shamsipur, M.; Hosseini, M.; Alizadeh, K.; Eskandari, M. M.; Sharghi, H.; Mousavi, M. F.; Ganjali, M. R. Anal. Chim. Acta 2003, 486, 93 https://doi.org/10.1016/S0003-2670(03)00401-X
  22. Ganjali, M. R.; Rezapour, M.; Pourjavid, M. R.; Haghgoo, S. Anal. Sci. 2004, 20, 1007 https://doi.org/10.2116/analsci.20.1007
  23. Shamsipur, M.; Hosseini, M.; Alizadeh, K.; Talebpour, Z.; Mousavi, M. F.; Ganjali, M. R.; Arca, M.; Lippolis, V. Anal. Chem. 2003, 75, 5680 https://doi.org/10.1021/ac0205659
  24. Ganjali, M. R.; Rahimi, M.; Maddah, B.; Moghimi, A.; Borhany, S. Anal. Sci. 2004, 20, 1427 https://doi.org/10.2116/analsci.20.1427
  25. Ganjali, M. R.; Tahami, M.; Shamsipur, M.; Poursaberi, T.; Haghgoo, S.; Hosseini, M. Electroanalysis 2003, 15, 1038 https://doi.org/10.1002/elan.200390125
  26. Ganjali, M. R.; Ravanshad, J.; Hosseini, M.; Salavati-Niasari, M.; Pourjavid, M. R.; Baezzat, M. R. Electroanalysis 2004, 16, 1771 https://doi.org/10.1002/elan.200303024
  27. Ganjali, M. R.; Naji, L.; Poursaberi, T.; Shamsipur, M.; Haghgoo, S. Anal. Chim. Acta 2003, 475, 59 https://doi.org/10.1016/S0003-2670(02)01226-6
  28. Shamsipur, M.; Hosseini, M.; Alizadeh, K.; Mousavi, M. F.; Lippolis, Y. Anal. Chem. 2005, 77, 276 https://doi.org/10.1021/ac049349l
  29. Ganjali, M. R.; Rasoolipour, S.; Rezapour, M.; Norouzi, P.; Tajarodi, A.; Hanifehpour, Y. Electroanalysis 2005, 17, 1534 https://doi.org/10.1002/elan.200403251
  30. Ganjali, M. R.; Rezapour, M.; Norouzi, P.; Salavati-Niasari, M. Electroanalysis 2005, 17, 2032 https://doi.org/10.1002/elan.200503324
  31. Zare, H. R.; Ardakani, M. M.; Nasirizadeh, N.; Safari, J. Bull. Korean Chem. Soc. 2005, 26, 51 https://doi.org/10.5012/bkcs.2005.26.1.051
  32. Ganjali, M. R.; Matloobi, P.; Ghorbani, M.; Norouzi, P.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2005, 26, 38 https://doi.org/10.5012/bkcs.2005.26.1.038
  33. Ganjali, M. R.; Zamani, H. A.; Norouzi, P.; Adib, M.; Rezapour, M.; Aceedy, M. Bull. Korean Chem. Soc. 2005, 26, 57934
  34. Ganjali, M. R.; Ghorbani, M.; Daftari, A.; Norouzi, P.; Pirelahi, H.; Dargahani, H. D. Bull. Korean Chem. Soc. 2004, 25, 172 https://doi.org/10.5012/bkcs.2004.25.2.172
  35. Ganjali, M. R.; Babaei, L. H.; Taghvaei-Ganjali, S.; Modjallal, A.; Shamsipur, M.; Hosseini, M.; Javanbakht, M. Bull. Korean Chem. Soc. 2004, 25, 177 https://doi.org/10.5012/bkcs.2004.25.2.177
  36. Ganjali, M. R.; Pourjavid, M. R.; Mouradzadegun, K.; Hosseini, M.; Mizani, F. Bull. Korean Chem. Soc. 2003, 24, 1585 https://doi.org/10.5012/bkcs.2003.24.11.1585
  37. Ganjali, M. R.; Daftari, A.; Mizani, F.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2003, 24, 23 https://doi.org/10.5012/bkcs.2003.24.1.023
  38. Ganjali, M. R.; Emami, M.; Salavati-Niasari, M. Bull. Korean Chem. Soc. 2002, 23, 1394 https://doi.org/10.5012/bkcs.2002.23.10.1394
  39. Gehrig, P. M.; Morf, W. E.; Welti, M.; Spichiger, U.; Simon, W. Helv. Chim. Acta 1990, 73, 203 https://doi.org/10.1002/hlca.19900730124
  40. Rosatzin, T.; Bakker, E.; Suzuki, K.; Simon, W. Anal. Chim. Acta 1993, 280, 197 https://doi.org/10.1016/0003-2670(93)85122-Z
  41. IUPAC Analytical Chemistry Devision, Commission on Analytical Nomenclature. Recommendations for Nomenclature for Ion Selective Electrodes. Pure Appl. Chem. 1976, 48, 127 https://doi.org/10.1351/pac197648010127
  42. Bakker, E. Electroanalysis 1997, 9, 7 https://doi.org/10.1002/elan.1140090202

Cited by

  1. ′‐bis(2‐Pyridinecarboxamide)‐1,3‐benzene as a Sensing Material vol.41, pp.1, 2008, https://doi.org/10.1080/00032710701746824
  2. Lanthanide Recognition: Determination of Thulium(III) Ions in Presence of Other Rare Earth Elements by a Thulium(III) Sensor Based on 4-Methyl-1,2-Bis(2-Pyridinecarboxamido)benzene as a Sensing Material vol.41, pp.13, 2008, https://doi.org/10.1080/00032710802350484
  3. Developments in the Field of Conducting and Non-conducting Polymer Based Potentiometric Membrane Sensors for Ions Over the Past Decade vol.8, pp.4, 2008, https://doi.org/10.3390/s8042331
  4. Determining fluoride ions in ammonium desulfurization slurry using an ion selective electrode method vol.121, pp.1755-1315, 2018, https://doi.org/10.1088/1755-1315/121/2/022033
  5. Construction of Tm3+-PVC membrane sensor based on 1-(2-thiazolylazo)-2-naphthol as sensing material vol.30, pp.3, 2006, https://doi.org/10.1016/j.msec.2010.01.007