• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.2
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• pp.142-151
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• 2007

Non-halogen flame retardant have been focus of extensive research because of environmental problem. Hexakisphenokycyclotriphosphazene was synthesized in order to use as the flame retardant of ABS resin. And using bisphenol A, bisphenol S, and resorcinol, the polymers which contained cyclophosphazene structure were synthesized in order to also use as the flame retardants of ABS resin. All of the synthesized polymers themselves got the excellent flame retardancy. And as the molecular weight of the compound were increased, the thermal stability was increased. But when the synthesized compounds were used as the flame retardants for ABS resin, the lower molecular weight compound in these compounds showed the better flame retardancy and the better physical properties of ABS resin. In case of using resorcinol, it showed the best flame retardancy.

• Fire Science and Engineering
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• v.31 no.4
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• pp.12-19
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• 2017

The present paper is a study on the performance characteristics of organic-inorganic hybrid flame retardants. MDF plywood has been used, that are being used for the interior decoration of building structures, to make the samples for experiment according to the existing or non-existing treatment of organic-inorganic hybrid flame resistants. Later, the experiment on the measurement of flame retardant performance using a $45^{\circ}$ flammability tester and the experiment on the measurement of combustion characteristic using a cone calorimeter have been proceeded to confirm the performance characteristic of organic-inorganic hybrid flame retardants. From the result of experiments, it has been confirmed that both organic-inorganic hybrid flame retardants have merits of inorganic and organic substances, and that heat resistance, durability and adhesiveness have been largely improved. The performance on the flame retardant has also appeared with excellent effect such as the reduced generation of combustion gas and the decreased generation of smoke.

• Journal of the Korea Institute of Building Construction
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• v.21 no.2
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• pp.113-119
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• 2021

Polymers are widely applied to construction materials due to their lightweight and excellent mechanical properties. However, owing to the combustible properties, polymers are one of the biggest reason of spreading large fires in fire accidents that occur frequently in the construction industry. Therefore, as a solution to this problem, many research has been conducted to impart flame retardancy by incorporating flame retardants to polymer matrix. Among these flame retardants, organic phosphorus-containing flame retardants have been attracting much attention because they have excellent compatibility with polymer matrix and low toxicity compared with halogen or inorganic-containing flame retardants. Accordingly, this study aims to design and synthesize an alkoxyamine-based organic phosphorus flame retardant to improve flame retardancy of polylactide which is an eco-friendly polymer used for construction materials.

• Journal of the Korean Applied Science and Technology
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• v.24 no.2
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• pp.182-189
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• 2007

Used polyurethane was chemically degraded by treatments with flame retardants such as tris(3-chloropropyl) phosphate (TCPP), triethyl phosphate (TEP), and trimethyl phosphate (TMP). The structure of degraded products (DEP) was analyzed by FT-IR and P-NMR and it turned out to be phosphorus containing oligourethanes. Rigid polyurethane foam was produced by using the degraded products (DEP) as flame retardants. The flammability of recycled rigid polyurethane was investigated. The recycled polyurethane shows a reduced flammability over virgin polyurethane. In order to evaluate flame retardant properties of the recycled polyurethane foams with various amounts of DEP, the combustion parameters of the foam was measured by a cone calorimeter. Scanning electron micrograph of recycled PU shows the same uniform cell morphology as virgin PU.

• Journal of the Korean Institute of Gas
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• v.17 no.5
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• pp.75-80
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• 2013

In this study, the effect of phosphorus flame retardants on the flame retardancy of the rigid polyurethane foam(PUF) was studied. Tetramethylene bis(orthophos-phorylurea)[TBPU] and Tris(2-chloroethyl) phosphate[TCEP], Tris(2-chloropropyl)phosphate [TCPP], Triethyl phosphate[TEP] were used as flame retardant. It was found that TBPU added PUF exhibits low mean heat release rate(HRR), peak HRR, effective heat of combusion(EHC), mass loss rate (MLR), CO yield and $CO_2$ compared other flame retardants.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.11a
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• pp.29-30
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• 2023

Wood is a construction material that has the advantages of carbon dioxide storage ability, noise reflection, and eco-friendliness. In order to use wood for a long time, you must use wood-specific paint, which is called oil stain. Oil stain improves water resistance and moisture resistance, but has the disadvantage of being weak against fire. This is because the oil contained in the oil stain causes a chemical reaction, and this chemical reaction causes the oil stain to spontaneously ignite, igniting nearby combustible materials and causing frequent fires. To improve this, in this study, different flame retardants were mixed and added to oil stain to produce functional oil stain. In addition, we would like to apply it to wood to check glow time and carbonization area. As a result of the experiment, it shows the best performance when mixed at 30(15 + 15)(%) and added to oil stain. The remaining burn time is satisfied from 10% for all samples, and the carbonized area is satisfied when it is 30%.

• Applied Chemistry for Engineering
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• v.24 no.2
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• pp.208-213
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• 2013

In this study, the effect of phosphorus flame retardants on the flame retardancy of the flexible polyurethane foam (PUF) was investigated. Tetramethylene bis(orthophosphorylurea) [TBPU] and phosphinyl alkylphosphate ester [CR-530], resorcinol bis diphenylphosphate [RDP], triethyl phosphate [TEP] were used as flame retardants. The results of thermogravimetric analysis (TGA) indicate that TBPU added PUF produces more charred residues than the other flame retardant added PUF. It was found that TBPU added PUF exhibits low mean heat release rate (HRR), peak HRR, effective heat of combusion (EHC), mass loss rate (MLR), CO yield and $CO_2$ compared to those other flame retardants.

• Proceedings of the KSR Conference
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• 2008.06a
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• pp.1789-1793
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• 2008

The Oxygen Index was measured for another flame retardant APP, or phosphorus, and other flame retarding assistants ZS, ZHS, AOM, and ZB, which are used as low smoke emitting materials, in order to see the increase in the flame retardation effect in comparison to the volume of additions. The results show that their flame retardation synergy effect was very small compared to the main flame retardants. The mixed use of main flame retardants, low smoking emitting materials, and phosphorus is a very important area of examination for creating synergy effect of flame retardation and lowering smoking and toxicity. For this, the results of flame retardation effect in comparison to the volume of addition of each low smoke emitting material are shown below.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.13 no.3
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• pp.955-960
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• 2012

In this study, pure Polyurethane and commonly used flame retardants $Al(OH)_3$ and $Mg(OH)_2$, the add-in sample and Cloisite Na+, Cloisite 15A added sample of flammability and mechanical properties are compared. Sodium silicate and a mixture of polyurethane that the lightweight filler Vermiculite, Perlite addition of flame retardant and mechanical properties of the sample was confirmed. As a result, the flame retardant additive in the Vermiculite and Perlite in a flame-retardant grade sample except sample were identified. Tensile strength is degrade accord to the filler amount. But, Sodium silicate in the case of the sample add-in, other than confirmed that the sample strength increases.

• Journal of the Korean Applied Science and Technology
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• v.7 no.2
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• pp.63-69
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• 1990

(2,3-Dibromopropyl) phenyl lauroyl phosphate[DPPL] was synthesized by adding lauric acid to (2,3-dibromopropyl)chloro phenyl phosphate [DPP]. which prepared from phenyl phosphoric acid dichloride with 2,3-dibromo propyl alcohol. Flame retardants of DPPF and DPPLF were prepared respectively. DPPF was a water soluble flame retardant, and DPPLF was o/w type emulsion flame retardant. After flame retardant treating two kinds of flame retardants to the various synthetic fabrics respectively. the flame retardancy and tear strength were measured. As the results of the measurement. DPPF had only name retardancy, but DPPLF had both of flame retardancy and softness.