• Title/Summary/Keyword: fire retardant materials

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A STUDY ON THE FLAMMABILITY OF NON-FLAME-RETARDANT AND FLAME-RETARDANT MATERIALS BY USING CONE CALORIMETER

  • Yanai, Eiji;Suzuki, Takeshi;Yamada, Tokiyoshi
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.85-92
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    • 1997
  • Flammability of non-flame-retardant and flame-retardant materials was studied by using cone calorimeter Also, relations between the results obtained by using cone calorimeter and those obtained by the flammability test of japanese fire Service Law were examined. The results are as follows: 1) The ignition time of the molten specimens is relatively long, whereas the ignition time of the non-molten specimens is short. None of remarkable difference of the ignition time has been found between non-flame-retardant and flame-retardant materials specimens. 2) The peak heat release rates of flame-retardant materials are smaller than those of non-flame- retardant materials. 3) The carbon monoxide and smoke evolved from flame-retardant materials generate much more than those evolved from non-flame-retardant materials. 4) Even if flame-retardant materials are passed by the flammability test of Japanese Fire Service Law, they burn easily under external radiative heating condition.

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Tests of Fire and Flame Retardant Performance for Membrane Materials (막재료의 난연 및 방염성능 실험에 대한 연구)

  • Kim, Gee-Cheol;Choi, Kwang-Ho
    • Journal of Korean Association for Spatial Structures
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    • v.16 no.2
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    • pp.55-60
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    • 2016
  • The Membrane structure has a number of problems in the application of a fireproof code based on general buildings codes. Thus, the fireproof code of membrane structure is necessary to activate the construction of the membrane structure. Because it requires a systematic classification of fire retardant and flame proof performance of membrane material. Fire retardant and flame proof tests are conducted on membrane materials mostly used in current construction to propose the fire and flame retardant performance criteria of membrane materials. Fire and flame retardant tests results, PTFE membrane material with the glass fiber fabric have a limit-combustible performance. PVDF membrane material with the polyester fabric does not ensure the fire retardant performance, but this membrane material has the flame retardant performance of a thick fabric. Also, ETFE does not ensure the fire retardant performance, but this membrane material has the flame retardant of a thin fabric.

Study on Property Modification with Fire Retardant Content in the Manufacture of Compounds for Cable Sheath (전선피복용 컴파운드의 제조에서 난연제의 첨가량에 따른 물성 변화 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.3
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    • pp.47-51
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    • 2019
  • The three different polymer compounds were manufactured with the three different fire retardant (silane coated magnesium dihydroxide) contents, 180, 200, 220 phr, for making cable sheath for ship industry. In the research, ethylene-vinylacetate, polyethylene as matrix polymers and ethylene-vinylacetate grafted maleic anhydride as coupling agent were selected for compounding with fire retardant, closslinking agent, plasticizer, and other additives. In the evaluation. ΔT, Mooney viscosity, and tensile strength increased with the content of fire retardant. But it was found that too much fire retardant damaged aging resistance and cold resistance of the polymer compound.

Combustion and Mechanical Properties of Fire Retardant Treated Waste Paper-Waste Acrylic Raw Fiber Composite Board

  • Eom, Young Geun;Yang, Han-Seung;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.31 no.3
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    • pp.1-10
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    • 2003
  • Shredded waste newspapers, waste acrylic raw fibers, and urea-formaldehyde (UF) adhesives, at 10% by weight on raw material, were used to produce recycled waste paper-waste acrylic raw fiber composite boards in laboratory scale experiments. The physical and mechanical properties of fire retardant treated recycled waste paper-waste acrylic raw fiber composite boards were examined to investigate the possibility of using the composites as internal finishing materials with specific gravities of 0.8 and 1.0, containing 5, 10, 20, and 30(wt.%) of waste acrylic raw fiber and 10, 15, 20, and 25(wt.%) of fire retardant (inorganic chemical, FR-7®) using the fabricating method used by commercial fiberboard manufacturers. The bending modulus of rupture increased as board density increased, decreased as waste acrylic raw fiber content increased, and also decreased as the fire retardant content increased. Mechanical properties were a little inferior to medium density fiberboard (MDF) or hardboard (HB), but significantly superior to gypsum board (GB) and insulation board (IB). The incombustibility of the fire retardant treated composite board increased on increasing the fire retardant content. The study shows that there is a possibility that composites made of recycled waste paper and waste acrylic raw fiber can be use as fire retardant internal finishing materials.

Study on Property Change with a Fire Retardant Content in the Manufacture of Polymer Composites for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.2
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    • pp.118-122
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    • 2019
  • Four different polymer compounds were manufactured to make cable sheaths for the shipping industry. Two kinds of ethylene vinyl acetate (EVA) as the main matrix polymers and EVA-grafted maleic anhydride (EVA-g-MAH) as the coupling agent were selected for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with different contents of the fire retardant, silanecoated magnesium dihydroxide (S-MDH). In the rheology evaluation, the $t_{60}$ and ${\Delta}T$ values increased with increasing S-MDH contents. On the other hand, the tensile strength decreased with increasing S-MDH content due to a relative decrease in binder polymers. With increasing S-MDH content, fire resistance increased, but cold resistance showed no obvious enhancement due to the polar effect of vinyl acetate in EVA.

Comparison on the fire performance of additional insulation materials for improving the fire retardancy in engine-room of FRP vessel (FRP 선박 기관실 난연성 향상을 위한 추가 방열재의 화재성능비교)

  • Choi, Jung-Min;Um, Han-Chan;Jin, Young-Hwa
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.9
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    • pp.1150-1155
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    • 2014
  • To prevent the flame spread in FRP vessel in fire, the engine-room of the vessel should be constructed additionally with laminated fire-retardant resin over 3 times or equivalent insulation materials to former according to the relevant standard for FRP vessel structure. It is surveyed that insulation materials called 'Gel coat' are widely used in FRP fishing vessel, however, test method and its criteria for Gel coat are not clearly establish and have not been evaluated yet, while test method and criteria for fire-retardant resin and fire-retardant polyurethane composite are described in test standard for type-approval. In this study, 3 fire-retardant resins, 4 gel coats, 1 flame-retardant paint and 1 polyurethane composite were selected based on the survey and were evaluated according to both IMO FTP Code part 5 and flame-retardant test. When comparing based on CFE values from flame-spread test, average value for 4 gel coats were lower than that of 3 fire-retardant resins. As for flame-retardant test, there were no significant differences between fire-retardant resin and gel coat, based on charred area.

A Study on the fire characteristic of pipe insulation film materials (배관 보온필름의 화재특성에 관한 연구)

  • Lee, Young-Sam;Lee, Jang-Won;Rie, Dong-Ho
    • Journal of the Korea Safety Management & Science
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    • v.14 no.2
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    • pp.65-70
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    • 2012
  • This study was performed to test the combustive properties of the pipe insulation materials which are mainly used in the industries and buildings. Fire characteristic test of pipe insulation film according to the KS F ISO 5660-1 was performed. The experimental materials commonly used in the pipe insulation were used four kinds of films. Two kinds of 4 types of products that have the flame retardant performance and the other two types of them have no flame retardant performance. They were selected for fire characteristic test. The result of finding 25kW/$m^2$ radiation from the ignition was that flame retardant products were 140sec and the other one were 69sec in average of heat release rate(HRR). The result of flame retardant products in the 50kW/$m^2$ was 34sec and the other one were 15sec in average of HRR. However, the HRR of flame retardant products was much higher than the other one. Flame propagation test was conducted according to the KOFEIS 1001. The result of flame retardant products was that flame retardant products had a hold without fire spread after firing them. But the other one were completely fired after firing them. Therefore, I want to recommend that flame retardant products need to be used by the regulation to prevent or decrease a fire spread.

An Experimental Study on the Development of Fire-retardant Treated Wood for Construction (건축용 난연 목재 개발에 대한 실험 연구)

  • Seo, Hyun Jeong;Kim, Nam Kyun;Jo, Jeong Min;Lee, Min Chul
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.149-156
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    • 2017
  • This study investigates fire-retardant performances and combustion/thermal characteristics of fire-retardant treated wood by comparing them with those of fire-retardant untreated wood from the expreimental resutls of cone calorimeter and thermo-gravimetric(TG) analyzer. Hazardousness of combustion product gases for fire-retardant treated wood and untreasted wood were also observed from the results of internal finish material incombustibility test according to the Korea standard code of KS F 2271. In this study, we also tried to improve the fire retardant performance of wood by applying fire-retardant chemical composites, and to secure the fire safety performance in buildings. Red pine (Pinus densiflora) was selected as a test specimen because it is mostly used as a building material in Korea. Fire retardant chemical composites (FRCs) were prepared by mixing boron, phosphorous, and nitrogen species and treated by press-impregnation method. Water-based FRCs were composed of 3% boric acid($H_3BO_3$), 3% borax decahydrate($Na_2B_4O_7$), 8% ammonium carbonate($(NH_4)_2CO_3$), diammonium phosphate ($(NH_4)_2HPO_4$) varied from 10-30% and potassium carbonate($K_2CO_3$) varied from 10-30%. From the test results of cone calorimeter, TG analysis and gas hazard assessments, newly proposed were the optimal composition and production methods of FRCs which can sufficiently meet fire-retardant level 3 based on Korea law of construction. Thus, the FRCs, developed in this study, are anticipated to contribute to the improvement of fire safety and widespread of usage in wood as building materials.

Effects of Antimony Trioxide-containing Coating on Fire Retardancy of Wood-based Materials (Antimony Trioxide가 첨가(添加)된 내화도료(耐火塗料)의 도막(塗膜)이 목질(木質) 판상재료(板狀材料)의 내화성(耐火性)에 미치는 영향(影響))

  • Yun, Young-Ki;Lee, Phil-Woo
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.2
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    • pp.31-42
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    • 1992
  • In this study, the relative effectiveness of antimony trioxide-containing coat on fire retardancy of plywood, particleboard and medium density fiberboard was investigated and compared through ISO ignition test and inclined panel test with non-coated ones. The results obtained were summarized as fallows: Any treated materials was not ignited in inclined panel test with 5 minutes, but only particleboard among treated ones burned in ISO ignition test with fairly delayed time. The weight loss rate of plywood decreased with the increased addition level of fire-retardant and the least values were obtained in particleboard and MDF at addition level of 7% and 5% respectively. Carbonized area of wood based materials decreased with the increased addition level of fire retardant. The temperatures of back in plywood, particleboard treated with fire-retard ant coat containing 7% $Sb_2O_3$ showed the lowest but MDF did not show any effectiveness with the increased addition level. The first flash time of plywood treated with fire retardant coat containing 9% $Sb_2O_3$, MDF and particleboard treated with fire retardant coat containing 7% $Sb_2O_3$ were 257sec., 286.4sec., 165.4sec. respectively.

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Study on Manufacture and Properties of Polymer Compounds for Cable Sheath (전선피복용 고분자 컴파운드의 제조 및 물성 연구)

  • Li, Xiangxu;Lee, Sang Bong;Cho, Ur Ryong
    • Journal of the Semiconductor & Display Technology
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    • v.18 no.1
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    • pp.42-47
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    • 2019
  • The four different polymer compounds were manufactured to make cable sheath for ship industry. Two kinds of ethylene-vinyl acetate (EVA) were selected as main matrix polymers for compounding with fire retardant, crosslinking agent, filler, plasticizer, and other additives. The properties of the four compounded materials were investigated with the contents of fire retardant, silane coated aluminum hydroxide (S-ATH). Rheology, Mooney viscosity, and tensile strength increased with S-ATH contents by reinforcing effect. With increasing fire retardant amount, fire resistance increased, but cold resistance didn't show an obvious enhancement due to polar effect of vinyl acetate in EVA.