• Title/Summary/Keyword: fire point

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Measurement and Prediction of Fire and Explosion Characteristics of n-Butylacetate (초산부틸의 화재 및 폭발 특성치 측정 및 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Society of Safety
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    • v.32 no.5
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    • pp.25-31
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    • 2017
  • The flash point, explosion limits, autoignition temperature(AIT) are important combustible properties which need special concern in the chemical safety process that handle hazardous substances. For the evaluation of the flammable properties of n-butylacetate, this study was investigated the explosion limits of n-butylacetate in the reference data. The flash points, fire points and AIT by the ignition delay time of n-butylacetate were experimented. The lower flash points of n-butylacetate by using the Setaflash and Pensky-Martens closed-cup testers were $24^{\circ}C$ and $26^{\circ}C$, respectively. The flash points of n-butylacetate using the Tag and Cleveland open cup testers are measured $31^{\circ}C$ and $40^{\circ}C$, respectively. And the fire points of n-butylacetate by the Tag and Cleveland open cup testers were measured $32^{\circ}C$ and $41^{\circ}C$. The AIT of n-butylacetate measured by the ASTM 659E tester was measured as $411^{\circ}C$. The lower explosion limit of lower flash point $24^{\circ}C$, which was measured by the Setaflash tester, was calculated to be 1.40 vol%. Also, the upper explosion limit of upper flash point $67^{\circ}C$ the Setaflash tester was calculated to be 12.5 vol%.

The Measurement and Estimation of Lower Flash Point for 2-Propanol+Acid Systems Using Cleveland Open Cup Apparatus (클리브랜드 개방식 장치를 이용한 2-propanol+acid류 계의 하부 인화점 측정 및 예측)

  • Ha, Dong-Myeong;Lee, Sung-Jin
    • Fire Science and Engineering
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    • v.21 no.4
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    • pp.32-37
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    • 2007
  • An accurate knowledge of the flash point is important in developing appropriate preventive and control measures in industrial fire protection. The lower flash points for the 2-propanol+acetic acid and 2-propanol+-n-propionic acid systems were measured by Cleveland open cup apparatus. The experimental data were compared with the values calculated by the Raoult's law, the Wilson equation and the NRTL(non random two liquids) equation. The calculated values based on the Wilson and NRTL equations were found to be better than those based on the Raoult's law. And the predictive curve of the flash point prediction model, based on NRTL equation described the experimentally-derived data were more effective than the case of the Wilson equation.

Prediction of Upper Explosion Limits (UEL) of Acids and Ketones by Using Setaflash Tester (Setaflash 장치를 이용한 산류와 케톤류의 폭발상한계 예측)

  • Ha, Dong-Myeong
    • Fire Science and Engineering
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    • v.25 no.2
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    • pp.114-119
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    • 2011
  • Explosion limit and flash point are the major combustion properties used to determine the fire and explosion hazards of the flammable substances. In this study, in order to predict upper explosion limits (UEL) for acids and ketones, the upper flash point of these were measured under the VLE (vaporliquid equilibrium) state by using Setaflash closed cup tester (ASTM D3278). The UELs calculated by Antoine equation by using the experimental upper flash point are usually lower than the several reported UELs. From the given results, using the proposed experimental and predicted method, it is possible to research the upper explosion limits of the other flammable substances.

A Study on Technical Trend of Fire Safety on Railway Vehicles for Launch CEN/TS 45545 (CEN/TS 45545 출범에 따른 철도차량 화재안전 기술 동향에 대한 연구)

  • Sung, Si-Young;Woo, Yee-Wan;Park, Jea-Hong
    • Proceedings of the KSR Conference
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    • 2010.06a
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    • pp.1768-1773
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    • 2010
  • CEN/TS 45545 is Europe consolidation standard for fire safety on railway behicles. This is based on the International Union of Railways(UIC) and different European countries. It is intended to protect passengers and staff in railway in the event of a fire on board. It will be prepared in 2012. Based on this consolidate standard, they are going to make single market, for raising technical competitiveness, technical innovation and globalization of that standard. For this reason, European academies, manufacturers, and sub-manufacturers confer and stady animated about CEN/TS 45545. In Korea, get out the safety assessment for ues incombustible interior material, the needs of quantitative analysis on fire protection, demand on recognition of fire protection scenario, and define about fire load analysis are becomin more and more important. Therefore, this paper will estimate and compare Flammability, Smoke Density, Toxicity Index( this is the key point for appraised fire safety performance of material) between CEN/TS45545 and fire standards on railway vehicle. Then suggest criteria for fire safety on railway vehicles.

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Thermal Characteristics of Fire-Protection Foams Exposed to Radiant Heating (복사열에 노출된 소방용 폼 약제의 열적 특성 연구)

  • Kim, H.S.;Hwang, I.J.;Kim, Youn-J.
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.1570-1575
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    • 2004
  • In order to evaluate the performance of fire-fighting agents used to protect structures from heat and fire damages, the thermal characteristics of fire-protection foams are experimentally investigated. The current research focuses on the destruction of a fire-fighting foam subjected to heat radiation. A simple repeatable test for fire-protection foams subjected to fire radiation is developed. This test involves foam generation equipment, a fire source for heat generation, repeatable test procedures, and data acquisition techniques. Results of the experimental procedure indicated that each thermocouple within the foam responded in a similar manner and gradually to a temperature of $15^{\circ}C{\sim}20^{\circ}C$. At this point, each trace generally rises to a temperature of approximately $90^{\circ}C$. The temperature gradient in the foam as time passes increases with increased foam expansion ratio. In addition, it is determined that the temperature gradient along the foam for depth decreases with increased foam expansion ratio.

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A Study on the Fire Resistance Design of Buildings Considering the Fire Load Energy Density (화재하중밀도를 고려한 건축물의 내화설계법에 관한 연구)

  • 이평강;이용재;최인창;김회서
    • Fire Science and Engineering
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    • v.17 no.2
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    • pp.10-16
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    • 2003
  • The main purpose of this study is to raise the point at issue and to propose reform direction about the current performance criteria of fire resistance through the examination of the fire resistance required for each use of compartment by using performance-based fire safety design method. To examine the performance criteria of fire resistance, this study compared the equivalent time of fire exposure which was calculated by using time-equivalent formulae with the required fire resistance time determined by existing prescriptive code, and surveyed factors such as the fire load energy density, ventilation factor, fire compartment materials and fire compartment geometry in order to calculate the equivalent time of fire exposure.

Predicting of Ignition Time and Critical Distance for Ignition of Douglas fir by Radiant Heat of Incandescent Lamp (백열전구 복사열에 의한 미송판의 발화 임계거리 및 발화시간 예측)

  • Lee, Heung-Su;Kim, Doo-Hyun
    • Journal of the Korean Society of Safety
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    • v.31 no.2
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    • pp.18-25
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    • 2016
  • The incandescent lamp is an electric light fixture with a tungsten filament heated to a high temperature, by passing an electric current through it, until it glows with visible light. The hot filament is protected from oxidation with a glass bulb that is filled with inert gas. The incandescent lamp has fire risk when combustible materials are close to its glass bulb. Because its lamp has the property which converts 90~95 percents of the electric power to heat energy. 2015 national fire statistics show that fires caused by lighting fixtures were 652 cases, and incandescent lamps(44 cases) and halogen lamps(53 cases) accounted for 15 percents in those of high heating light fixtures. Since incandescent lamp fires account for about 45 percents in the high heating light fixture, we could not overlook the fire risks by the incandescent lamp. Although many studies related with those have been conducted, incandescent lamp fires are continuously occurred. This study was carried out to study the fire risk of ignition of wood due to radiant heat of incandescent lamp. Radiant heat flux of the incandescent lamp was predicted by applying point source model, and critical distance for ignition of wood was calculated by applying integral model. The results from this study could applied to fire prevention activities related to light bulb, and it could be used in fire cause investigations related to radiant heat of incandescent lamp.

The Analysis of Distribution and Characteristics of Forest Fires Damage over 30 ha in Korea (우리나라 30 ha 이상 산불피해의 분포 및 특성 분석)

  • Lee, Hyung-Seok;Lee, Si-Young
    • Fire Science and Engineering
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    • v.25 no.5
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    • pp.39-46
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    • 2011
  • In order to consider the prevention countermeasure to the occurrence of forest fires, analysing characteristic of the past forest fire data is needed. This research analyzed distribution and characteristics of forest fires damage over 30 ha based on statistics data of forest fires in Korea between 1975 and 2010. As a result, the number of forest fires damage over 30 ha as 23 was most occurred in 1978. Forest fires show an upward tendency from 1970 to 2000. Forest fires of 30 ha~50 ha damaged area was most occurred. Forest fire in Gangwon province was occurred as the number of total 66 (37.0 %). Gangwon province was superior in point density analysis. The number of forest fire occurrence over 30 ha was most high to 114 (63.0 %) in April and to 44 (24.3 %) in Sunday. The occurrence number of forest fire and damage caused by forest fire is increasing more and more since 1975, appropriate authorities can use effectively in devising policy for forest fire prevention from this result.

The development of the escape light control system (유도등 제어시스템의 개발)

  • Kim, Dong-Ook;Mun, Hyun-Wook;Lee, Ki-Yeon;Kim, Dong-Woo;Gil, Hyung-Jun;Kim, Hyang-Kon;Chung, Young-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.6
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    • pp.52-58
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    • 2009
  • When a fire breaks out, it is frequent that large sized miserable death is happened by seriousness of poisonous gas and peculiarity of space because the building construction is recently more complex and diverse. So early countermeasure in preparation for evacuation escape linked directly with a loss of lives is pressing. Because escape light that mark fixing one-way of existing way is not efficiently extricated refugees from dangers when a fire breaks out, construction of system that can extricate refugees from dangers and suppress early a fire by grasping correctly fire point is required urgently. When a fire breaks out, all escape lights connected with fire sensor and reception group which have ill aiming in these point will lead people to safe emergency entrance of opposite direction of place that a fire is broken out after being calculated the direction and speed of flame and smoke. There is the purpose of my research in development of artificial intelligent directional escape light that can mark direction to most suitable pull-out and assist in early extinguishing a fire.

A Study on the Fire Risk for Self-regulating Heating Cable (정온전선의 화재 위험성에 관한 연구)

  • Jung Hyun Lee;Si Hyun Kim;Ye Jin Park;Sin Dong Kang;Jae-Ho Kim
    • Journal of the Korean Society of Safety
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    • v.39 no.3
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    • pp.7-13
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    • 2024
  • This study examines the physical characteristics of self-regulating heating cables caused by increased temperature and fire risk due to local degradation. A thermo hygrostat system, a convection dryer, a digital multimeter (Agilent 34465 A), NI DAQ, and the LabVIEW program were used to assess the physical properties in response to temperature fluctuations. As the temperature increases, the resistance of the self-regulating heating cable increases; however, when the critical point is exceeded, the resistance sharply decreases. A problem arises when the resistance value cannot return to its original state even though the temperature is lowered to the initial state. Moreover, when the ambient temperature rises while power is applied, the resistance value initially increases, and the flowing current decreases, maintaining a constant state. However, when the critical temperature is exceeded, the flowing current increases because of a rapid decrease in the resistance value, progressing to ignition. When the resistance value decreases because of the deterioration of one local area, the total resistance value becomes less than the initial resistance value. Therefore, the flowing current increases and an ignition problem occurs at one location where deterioration occurs. Despite the sustained flames and arcs resulting from the changes in the overall physical properties of the self-regulating heating cable and resistance variations due to local decline, the fire continued as the flowing current was lower than the operating current of the circuit breaker, failing to cut the power. In the case of self-regulating heating cables and heating wires, which are the leading causes of fires in winter, efforts are needed to ensure the need for periodic maintenance and the use of KS-certified products.