• Journal of the Korean Ceramic Society
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• v.36 no.11
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• pp.1261-1265
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• 1999

Effect of SiC particle size of the densification of Al2O3-SiC composite during pressureless sintering was investigated. Two types of SiC powders having average particle size of 0.15${\mu}{\textrm}{m}$ and 3${\mu}{\textrm}{m}$ were used. Densification rate of the specimen containing 0.15${\mu}{\textrm}{m}$ SiC particles was slower than that of the specimen containg 3${\mu}{\textrm}{m}$ SiC particles. Although the relative density of the specimen containing 0.15${\mu}{\textrm}{m}$ SiC particles was below 90% of theoretical density after sintering at 155$0^{\circ}C$ the complete closure of open pores occurred. Therefore full densification could be obtained by subsequent HIP. On the other hand in the specimen containing 3${\mu}{\textrm}{m}$ SiC particles the complete closed pore was observed at 95% of theoretical density. Such a fast pore closure in the specimen containing 0.15${\mu}{\textrm}{m}$ SiC particles is likely to occur as a result of dense reaction layer formation on the specimen surface which is attributed to the high reactivity of small size particles with sintering atmosphere.

• Journal of Ceramic Processing Research
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• v.19 no.5
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• pp.383-387
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• 2018

Highly transparent $Y_2O_3$ ceramics were produced using spark plasma sintering (SPS) at $1600^{\circ}C$ and 30 MPa for 5 min. When the SPS process was applied with various amounts of $La_2O_3$ as dopant. The specimen doped with 3 mol% $La_2O_3$ showed the highest density, and rapid particle growth and pore growth occurred, exhibiting that the relative density and average grain size are 99.2% and $17.2{\mu}m$, respectively. The specimen showed excellent transmittance of 79.44% in the visible light region (600 nm), resulting that $La_2O_3$ would be a useful dopant for improving the transmittance and mechanical properties of transparent $Y_2O_3$ ceramics produced with SPS.

• Applied Chemistry for Engineering
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• v.35 no.2
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• pp.96-99
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• 2024

A sintering paste for bonding copper plates was synthesized using Cu formate nanofibers on Cu microparticles, mixed with formic acid. Copper oxide nanofibers of 10 ㎛ grown at 400 ℃ on Cu microparticles on the surface were transformed into copper formate nanofibers through the mixing of formic acid. Compared to Cu bulk particles or nanoparticles, Cu formate on Cu microparticles decomposed into metallic Cu at a lower temperature of 210 ℃, facilitating the sintering of copper paste. The growth of nanofiber on Cu microparticles allowed for an increase in the reaction rate of formation to copper formate, aggregating surface area, and decomposition rate of copper formate, resulting in fast sintering.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.134-134
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• 2016

The effect of different thermal treatments on the sub-50 nm copper nanoparticles is examined in the aspects of chemical, electrical and surface morphology. The copper nanoparticles are chemically synthesized and fabricated for paste-type solution. Simple bar coating method is practiced as a deposition process to form copper thin film on a typical slide glass. Deposited copper thin films are annealed by two different routes: general tube furnace with 99.99 % Ar atmosphere and selective laser sintering process. The thermal behavior of the different thermal-treated copper thin films is compared by SEM, XRD, FT-IR and XPS analysis. In this study, the laser sintering process ensures low annealing temperature, fast working speed and ambient-accessible route. Moreover, the laser-sintered copper thin film shows good electrical property and enhanced chemical stability than conventional thermal annealing process. Consequently, the proposed laser sintering process can be compatible with plastic substrate for flexible applications.

• Journal of Powder Materials
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• v.9 no.4
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• pp.235-244
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• 2002

The effects of residual impurities on solid state sintering of the powder injection molded (PIMed) W-15wt%Cu nanocomposite powder were investigated. The W-Cu nanocomposite powder was produced by the mech-ano-chemical process consisting of high energy ball-milling and hydrogen reduction of W blue powder-cuO mixture. Solid state sintering of the powder compacts was conducted at $1050^{\circ}C$ for 2~10 h in hydrogen atmosphere. The den-sification of PIM specimen was slightly larger than that of PM(conventional PM specimen), being due to fast coalescence of aggregate in the PIM. The only difference between PIM and PM specimens was the amount of residual impurities. The carbon as a strong reduction agent effectively reduced residual W oxide in the PIM specimen. The $H_2O$ formed by $H_2$ reduction of oxide disintegrated W-Cu aggregates during removal process, on the contrary to this, micropore volume rapidly decreased due to coalescence of the disintegrated W-Cu aggregates during evolution of CO.It can be concluded that the higher densification was due to the earlier occurred Cu phase spreading that was induced by effective removal of residual oxides by carbon.

• Nuclear Engineering and Technology
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• v.56 no.7
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• pp.2767-2774
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• 2024

In this study, investment casting shell waste successfully utilized to produce cordierite/mullite/zircon composites. Green pellets, consisting of investment casting shell waste, alumina, and magnesia, were prepared and sintered at temperatures between 1250 and 1350 ℃. The influence of the sintering temperature on the crystalline phase composition, densification behavior, flexural strength, microstructure, and radiation shielding properties of the cordierite/mullite/zircon composites is investigated. Phase analysis showed that characteristic cordierite peaks appear at 1250 ℃, but the complete conversation of silica from investment casting shell waste into cordierite requires a sintering temperature of at least 1300 ℃. Notably, the cordierite/mullite/zircon composite sintered at 1350 ℃ exhibited a sixfold increase in flexural strength compared to the ceramic composite directly fabricated from investment casting shell waste at the same sintering temperature. Furthermore, the effect of Y₂O₃ addition on composites' radiation shielding properties is investigated. The results show that the Y₂O₃ addition improves densification behavior, enhancing the shielding capabilities of the composites against fast neutron and gamma radiation. Our findings suggest that the developed ceramic composites show significant potential for gamma-ray and neutron shielding applications.

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.2175-2178
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• 2005

Selective Laser Sintering(SLS) method is one of Rapid Prototyping(RP) technologies. It has been used to fabricate desirable part to sinter powder and stack the fabricated layer. Since the sintering process occurs using infrared laser having high thermal energy, shrinkage and curling of the fabricated part occurs according to thermal distribution. Therefore, the fast scanning path generation is necessary to eliminate the factors of quality deterioration. In case of fabricating larger size parts, the unique scanning device and scanning path generation should be considered. In this paper, the development of SLS machines being capable of large size fabrication(800${\times}$1000${\times}$800 mm, W${\times}$D${\times}$H) will be addressed. The dual laser system and the unique scanning device have been designed and built, which employ CO2 lasers and dynamic 3-axis scanners. The developed system allows scanning a larger planar surface with the desired laser spot size. Also, to generate the fast scanning paths, adaptive path generation is needed with respect to the shape of each layer, and not simply x, y scanning, but the scanning of arbitrary direction should be enabled. To evaluate the suggested method, the complex part will be used for the experiment fabrication.

• Journal of Institute of Convergence Technology
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• v.9 no.1
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• pp.7-12
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• 2019

The aim of this study is to improve the durability performance of catalysts for a catalytic combustor and to obtain operating conditions for stable combustion of the catalytic combustor. It was attempted to improve the durability of the catalysts by adding a promoter in order to reduce the cost of replacing Pt catalyst while maintaining stability. The main catalyst used in the study was Pt and the promoters were Ni and La. Pure Pt3/γ-Al₂O₃ catalyst without promoter was promoted to fast sintering states under harsh conditions and catalytic combustion was turned off, whereas the catalysts added La, Ni as promoter were showed relatively slow sintering states. It can be concluded that the promoter La, Ni effectively contributes to the improvement of the durability of the Pt catalyst, and it is possible to get longer durability and more stable duration than the conventional catalytic combustor.

• Journal of Powder Materials
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• v.12 no.1
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• pp.70-78
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• 2005

Mechanical alloying using high-energy ball mill and subsequent spark plasma sintering (SPS) process was applied to understand mechanical alloying processing of Al-Fe alloy system. The thermal stability of mechanically alloyed Al-Fe alloy was intended to be enhanced by SPS process. Various analytical techniques including particle size analysis, density measurement, micro-Vickers hardness test, SEM, TEM, and X-ray diffractometry were adopted to find optimum processing conditions for mechanical alloying and subsequent SPS and to estimate thermal stability of the prepared alloy. It was found from the treatment of mechanically alloyed Al-8wt.%Fe powder mixture that needle-shaped $Al_3Fe$ precipitates was formed in the Al-Fe matrix, and the alloy compact showed enhanced densification and reached its full density with little loss of its fine microstructure. After heat treatment at $500^{\circC}$, it was also shown that the thermal stability of Al-8wt.%Fe alloy fabricated in the present study was enhanced, which was due to its fine microstructure developed by fast densification of SPS.

• Korean Journal of Metals and Materials
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• v.47 no.10
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• pp.660-666
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• 2009

The consolidation of mechanical alloyed $Ti_5Si_3$ powder by electro-discharge-sintering has been investigated. A single pulse of 2.5 to 8.0 kJ/0.34 g was applied to each powder mixture using 300 and $450{\mu}F$ capacitors. A bulk-like solid with $Ti_5Si_3$ phase has been successfully fabricated by the discharge with an input energy of more than 2.5 kJ in less than $160{\mu}sec$. Micro-Vickers hardness was found to be higher than 1350, which is significantly higher than that of a conventional high temperature sintered sample. The formation of $Ti_5Si_3$ and consolidation occurred through a fast solid state diffusion reaction.