• Title/Summary/Keyword: excellent thermal stability

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Improved Thermal Stability of Ag Nanowire Heaters with ZnO Layer (ZnO를 이용한 은 나노와이어 히터의 열 안정성 향상)

  • Choi, Wonjung;Jo, Sungjin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.8
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    • pp.530-534
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    • 2017
  • Transparent film heaters employing silver nanowires (Ag NWs) have attracted increasing attention because of their widespread applications. However, the low thermal resistance of Ag NWs limits the maximum operating temperature of the Ag NW film heater. In this study, Ag NW film heaters with high mechanical and thermal stability were successfully developed. The thermal power-out characteristics of the Ag NW heaters were investigated as a function of the Ag NW density. The results revealed that the prepared flexible Ag NW heater possessed high thermal stability over $190^{\circ}C$ owing to ZnO encapsulation. This indicates that the Ag NW film with excellent thermal stability have remarkably high potential for use as electrodes in film heaters operating at high temperatures.

Phase Stability Studies of Unirradiated Al-U-10wt.%Mo Fuel at Elevated Temperature

  • Kim, Ki-Hwan;Jang, Se-Jung;Hyun suk Ahn;Park, Jong-Man;Kim, Chang-Kyu;Sohn, Dong-Seong
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.273-278
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    • 1998
  • The phase stability of atomized U-10wt. %Mo powder and the thermal compatibility of dispersed fuel meats at 40$0^{\circ}C$ and 50$0^{\circ}C$ have been characterized. Atomized U-10Mo powder has a good \ulcorner-U phase stability, and excellent thermal compatibility with aluminum matrix in a dispersion fuel. It is thought that the good phase stability is related to th large supersaturation of Mo atoms in the atomized particles. The reasons for the excellent thermal compatibility have been considered to be as follows. Before thermal decomposition of ${\gamma}$-U in particle, supersaturated Mo atoms at ${\gamma}$-U grain boundaries inhibit the diffusion of Al atoms. After thermal decomposition of ${\gamma}$-U into ${\gamma}$-U and U$_2$Mo, the intermetallic compound of U$_2$Mo seems to retard the penetration of Al atoms. The penetration mechanisms of aluminum atoms in the atomized particles are assumed be classified as (a) diffusion through the reacted layer between fuel particles and Al matrix leaving a kernel-like unreacted island and (b) diffusion along grain boundaries showing several unreacted islands and more reacted regions.

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A Study on Dimensional Stability and Thermal Performance of Superheated Steam Treated and Thermal Compressed Wood

  • Chung, Hyunwoo;Han, Yeonjung;Park, Jun-Ho;Chang, Yoon-Seong;Park, Yonggun;Yang, Sang-Yun;Yeo, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.44 no.2
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    • pp.184-190
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    • 2016
  • Recently, wood is attracting attention as green building interior decoration material. When wood is used as building interior decoration material, excellent dimensional stability and thermal performance is required. In this study, superheated steam treatment process and thermal compression process were applied to flat sawn Pinus koraiensis wood panel in order to improve dimensional stability and thermal performance. According to results of this study, superheated steam treatment process and thermal compression process improve thermal performance and dimensional stability of wood, especially in tangential direction. The spring back in radial direction reduces the effect of thermal compression on dimensional stability of wood in radial direction.

Surface modified ceramic fiber separators for thermal batteries

  • Cheong, Hae-Won;Ha, Sang-Hyeon;Choi, Yu-Song
    • Journal of Ceramic Processing Research
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    • v.13 no.spc2
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    • pp.308-311
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    • 2012
  • A wide range of possible hazards existing in thermal batteries are mainly caused by thermal runaway, which results in overheating or explosion in extreme case. Battery separators ensure the separation between two electrodes and the retention of ion-conductive electrolytes. Thermal runaways in thermal batteries can be significantly reduced by the adoption of these separators. The high operating temperature and the violent reactivity in thermal batteries, however, have limited the introduction of conventional separators. As a substitute for separators, MgO powders have been mostly used as a binder to hold molten salt electrolyte. During recent decades the fabrication technology of ceramic fiber, which has excellent mechanical strength and chemical stability, has undergone significant improvement. In this study we adopted wet-laid nonwoven paper making method instead of the electrospinning method which is costly and troublesome to produce in volume. Polymeric precursor can readily be coated on the surface of wet-laid ceramic paper, and be formed into ceramic film after heat treatment. The mechanical strength and the thermo-chemical stability as well as the wetting behaviors of ceramic separators with various molten salts were investigated to be applicable to thermal batteries. Due to their excellent chemical, mechanical, and electrical properties, wet-laid nonwoven separators made from ceramic fibers have revealed positive possibility as new separators for thermal batteries which operate at high temperature with no conspicuous sign of a short circuit and corrosion.

Study of thermal stability on PVC using mixed metal soap and stabilizer (복합금속비누와 안정화조제를 이용한 PVC의 열안정화에 대한 연구)

  • Jeon, In-Ki;Ahn, Sung-Hwan;Chung, Kwang-Bo
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.4
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    • pp.552-558
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    • 2010
  • Zinc soap and Zn/Ba mixed metal soap were synthesized and PVC plastisol with mixed metal soap and various costabilizers were also synthesized with good structures and characterized by IR and $^1H$-NMR. The IR spectrums and $^1H$-NMR spectrums of the synthesized soaps were in very good accordance with the structures proposed by earlier workers. In using phosphite as a costabilizer, TIDP phosphite was shown to be the excellent thermal stabilization effect at the low temperature and TNPP phosphite was shown to be the excellent thermal stabilization effect at the high temperature. In case of antioxidant, it was revealed that antioxidant was not effective in the low temperature thermal stabilization effect while highly effective in the high temperature thermal stability. $NaClO_4$ solution with sorbitol solvent had the best thermal stabilization effect among $NaClO_4$ solution series at low and high temperature.

The Thermal Stability and Elevated Temperature Mechanical Properties of Spray-Deposited $SiC_P$/Al-11.7Fe-1.3V-1.7Si Composite

  • Hao, L.;He, Y.Q.;Wang, Na;Chen, Z.H.;Chen, Z.G.;Yan, H.G.;Xu, Z.K.
    • Advanced Composite Materials
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    • v.18 no.4
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    • pp.351-364
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    • 2009
  • The thermal stability and elevated temperature mechanical properties of $SiC_P$/Al-11.7Fe-1.3V-1.7Si (Al-11.7Fe-1.3V-1.7Si reinforced with SiC particulates) composites sheets prepared by spray deposition (SD) $\rightarrow$ hot pressing $\rightarrow$ rolling process were investigated. The experimental results showed that the composite possessed high ${\sigma}_b$ (elevated temperature tensile strength), for instance, ${\sigma}_b$ was 315.8 MPa, which was tested at $315^{\circ}C$, meanwhile the figure was 232.6 MPa tested at $400^{\circ}C$, and the elongations were 2.5% and 1.4%, respectively. Furthermore, the composite sheets exhibited excellent thermal stability: the hardness showed no significant decline after annealing at $550^{\circ}C$ for 200 h or at $600^{\circ}C$ for 10 h. The good elevated temperature mechanical properties and excellent thermal stability should mainly be attributed to the formation of spherical ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase particulates in the aluminum matrix. Furthermore, the addition of SiC particles into the alloy is another important factor, which the following properties are responsible for. The resultant Si of the reaction between Al matrix and SiC particles diffused into Al matrix can stabilize ${\alpha}-Al_{12}(Fe,\;V)_3Si$ dispersed phase; in addition, the interface (Si layer) improved the wettability of Al/$SiC_P$, hence, elevated the bonding between them. Furthermore, the fine $Al_4C_3$ phase also strengthened the matrix as a dispersion-strengthened phase. Meanwhile, load is transferred from Al matrix to SiC particles, which increased the cooling rate of the melt droplets and improved the solution strengthening and dispersion strengthening.

Thermal and Electrochemical Studies of Tris(2,4,6-trimethoxyphenyl)Phosphine as a Flame Retardant Additive for Li-ion Battery (리튬이차전지 난연성 전해액 첨가제로서의 Tris(2,4,6-trimethoxyphenyl)Phosphine의 열적, 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1130-1134
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    • 2008
  • Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

Thermal Stability of Ta-Mo Alloy Film on Silicon Dioxide (실리콘 산화막에 대한 Ta-Mo 합금 게이트의 열적 안정성)

  • 노영진;이충근;홍신남
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.4
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    • pp.361-366
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    • 2004
  • The interface stability of Ta-Mo alloy film on SiO$_2$ was investigated. Ta-Mo alloy films were formed by co-sputtering method, and the alloy composition was varied by controlling Ta and Mo sputtering power, When the atomic composition of Ta was about 91%, the measured work function was 4.24 eV that is suitable for NMOS gate. To identify interface stability between Ta-Mo alloy film and SiO$_2$, C-V and XRD measurements were performed on the samples annealed with rapid thermal processor between $600^{\circ}C$ and 90$0^{\circ}C$. Even after 90$0^{\circ}C$ rapid thermal annealing, excellent interface stability and electrical properties were observed. Also, thermodynamic analysis was studied to compare with experimental results.

Thermal Durability of Neon Transformer with Diluent Mixing Ratio (증량제 혼합비율에 따른 네온변압기의 열내구성 평가)

  • Hong, In Kwon;Jeon, Gil Song;Lee, Seung Bum
    • Applied Chemistry for Engineering
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    • v.26 no.4
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    • pp.452-457
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    • 2015
  • The physical properties, such as the heat resistance and thermal durability of the temperature difference fatigue resistance should be excellent when preparing an epoxy type resin for a neon transformer housing. In this study, 50 wt% of $SiO_2$ and silica were selected as a reinforcement and diluent filler for epoxy type resins, respectively. Thermal conductivity and thermal stability were measured as the mixing ratio varied upon the particle sizes. The optimal amount of the mixed silica was 50 wt%. Thermal stability was improved with increasing the amount of larger silica particles. The optimal mixing ratio of differently sized silica particles was 28/3 : 14/18 : 8/10 mesh = 1 : 1 : 1. From these results, it is thought that neon transformer is producible which has excellent thermal durability.

Recent Progress in Cathode Materials for Thermal Batteries

  • Ko, Jaehwan;Kang, Seung Ho;Cheong, Hae-Won;Yoon, Young Soo
    • Journal of the Korean Ceramic Society
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    • v.56 no.3
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    • pp.233-255
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    • 2019
  • Thermal batteries are reserve batteries with molten salts as an electrolyte, which activates at high temperature. Due to their excellent reliability, long shelf life, and mechanical robustness, thermal batteries are used in military applications. A high-performance cathode for thermal batteries should be considered in terms of its high capacity, high voltage, and high thermal stability. Research progress on cathode materials from the recent decade is reviewed in this article. The major directions of research were surface modification, compounding of existing materials, fabrication of thin film cathode, and development of new materials. In order to develop a high-performance cathode, a proper combination of these research directions is required while considering mass production and cost.