Journal of the Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회논문지)

The Korean Institute of Electrical and Electronic Material Engineers (한국전기전자재료학회)
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Thermal and Electrochemical Studies of Tris(2,4,6-trimethoxyphenyl)Phosphine as a Flame Retardant Additive for Li-ion Battery

리튬이차전지 난연성 전해액 첨가제로서의 Tris(2,4,6-trimethoxyphenyl)Phosphine의 열적, 전기화학적 특성

  • 안세영 (한국전기연구원 전지연구그룹) ;
  • 김기택 (한국전기연구원 전지연구그룹) ;
  • 김현수 (한국전기연구원 전지연구그룹)
  • Published : 2008.12.01
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Abstract

Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

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References

  1. J. S. Hong, H. Maleki, S. Al Hallaj, L. Reddy, and J. R. Selman, "Electrochemical calorimetric studies of lithium-ion cells", J. Electrochem. Soc., Vol. 145, p. 1469, 1998 https://doi.org/10.1149/1.1838506
  2. S. Tobisima and J. Yamaki, "A consiferation of lithium cell safety", J. Power Sources, Vol. 81-82, p. 882, 1999 https://doi.org/10.1016/S0378-7753(98)00240-7
  3. X. L. Yao, S. Xie, C. H. Chen, Q. S. Wang, J. H. Sun, Y. L. Li, and S. X. Lu, "Comparative study of trimethyl phophite and trimethyl phosphate as electrolyte additives in lithium ion batteries", J. Power Sources, Vol. 144, p. 170, 2005 https://doi.org/10.1016/j.jpowsour.2004.11.042
  4. K. Xu, S. Zhang, J. L. Allen, and T. R. Jow, "Nonflammable electrolytes for Li-ion batteries based on a fluorinated phosphate", J. Electrochem. Soc., Vol. 149, p. A1079, 2002 https://doi.org/10.1149/1.1490356
  5. N. Yoshimoto, Y. Niida, M. Egashira, and M. Morita, "Nonflammable gel electrolyte containing alkyl phosphate for rechargeable lithium battries", J. Power Sources, Vol. 163, p. 238, 2006 https://doi.org/10.1016/j.jpowsour.2006.02.090
  6. S. S. Zhang, K. Xu, and T. R. Jow, "Tris(2,2,2-trifluoroethyl) phosphate as a co-solvent for nonflammable electrolyte in Li-ion batteries", J. Power Sources, Vol. 113, p. 166, 2003 https://doi.org/10.1016/S0378-7753(02)00537-2
  7. C. W. Lee, R. Venkatachalapathy, and J. Prakash, "A novel flame-retardant additive for lithium batteries", Electrochem. Solid-State Letters, Vol. 3, No. 2, p. 63, 2000
  8. K. Xu, M. S. Ding, S. Zhang, J. L. Allen, and T. R. Jow, "Evaluation of fluornated alkyl phosphates as flame retardants in electrolytes for li-ion batteries", J. Electrochem. Soc., Vol. 150, No. 2, p. A161, 2003 https://doi.org/10.1149/1.1533040
  9. Y. E. Hyung, D. R. Visser, and K. Amine, "Flame-retardant additives for lithium-ion batteires", J. Power Sources, Vol. 119-121, p. 383, 2003 https://doi.org/10.1016/S0378-7753(03)00225-8
  10. D. H. Doughty, E. P. Roth, C. C. Crafts, G. Nagasubramamian, G. Henriksen, and K. Amine, "Effects of additives in thermal stability of Li ion cells", J. Power Sources, Vol. 146, p. 116, 2005 https://doi.org/10.1016/j.jpowsour.2005.03.170
  11. E. P. Roth, "Thermal characterization of li-ion cells using calorimetric techniques", Proceedings of the intersociety Energy Conversion Engineering Conference 2, p. 962, 2000
  12. B. C. Park, H. B. Kim, S. T. Myung, K. Amine, I. Belharouak S. M. Lee, and Y. K. Sun, "Improvement of structural and electro- hemical properties of $AlF_3$-coated Li[$Ni_{1/3} Co_{1/3}Mn_{1/3}]O_{2}$cathode materials on high voltage region", J. Power Sources, Vol. 178, p. 826, 2008 https://doi.org/10.1016/j.jpowsour.2007.08.034
  13. 안세영, 김기택, 김현수, 남상용, "리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성", 전기전자재료학회논문지, 20권, 9호, p. 756, 2007 https://doi.org/10.4313/JKEM.2007.20.9.756