• Title/Summary/Keyword: equilibrium data

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2020 Korean Dietary Reference Intakes for Protein: Estimation of protein requirements and the status of dietary protein intake in the Korean population (2020 단백질 섭취기준: 결핍과 만성질환 예방을 위한 한국인의 단백질 필요량 추정과 섭취현황)

  • Kim, Eunjung;Chung, Sangwon;Hwang, Jin-Taek;Park, Yoon Jung
    • Journal of Nutrition and Health
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    • v.55 no.1
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    • pp.10-20
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    • 2022
  • This article evaluated levels of Estimated Average Requirements (EARs), Reference Nutrient Intakes (RNIs), and Acceptable Macronutrient Distribution Ranges (AMDRs) of protein using the recently revised Dietary Reference Intakes (DRIs) for Koreans (2020). Dietary protein requirements are based on amounts sufficient to satisfy physiological demands to accomplish nitrogen equilibrium. The same principle was applied to estimate EARs and RNIs, for adults in DRIs conducted in 2015 and 2020 in Koreans. EAR was estimated to be 0.73 g/kg body weight/day, according to data (0.66 g/kg body weight/day) obtained using the nitrogen balance method and adjusted by efficiency of protein use (90%). RNI was calculated as EAR increased by an amount equal to twice the standard deviation of an age group so as to cover 97.5% of the group and was found to be 0.91 g/kg body weight/day. For weaned infants, children, and adolescents, growth requirement was added to estimate EAR. In particular, growth requirement was adjusted by efficiency of protein use in the revised EAR, which led to higher EARs for weaned infants, children, and adolescents of both genders as compared with 2015 DRIs. The AMDR for protein was set at 7%-20% of energy intake, which was the same as 2015 DRIs. Current, average protein intake by the Korean population is almost twice times the EAR, which suggests it might be better to increase the minimal margin for AMDR. However, it was not adjusted in this revision due to lack of evidence.

Characterization and Adsorption Properties of Red Mud/Fly Ash Based Geopolymers Adsorbent with Calcination Temperature (Red mud/fly ash 기반 geopolymer 흡착제의 소성온도에 따른 특성 및 흡착거동)

  • Jin-Yeong Shin;Han-Seong Kim;Hwa-Yeong Kang;Soon-Do Yoon
    • Applied Chemistry for Engineering
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    • v.34 no.4
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    • pp.412-420
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    • 2023
  • In this study, red mud/fly ash based geopolymer adsorbents (RFGPA) were prepared with calcination temperatures of 200, 400, and 600 ℃, and the effects of these calcination temperatures on the adsorption of methylene blue (MB) were investigated. In addition, the prepared RFGPA was characterized using X-ray fluorescence (XRF), scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR) spectroscopy, and Brunauer-EmmettTeller (BET) analysis. The results of the adsorption kinetics of MB at RFGPA prepared calcination temperatures indicated that the adsorption equilibrium of MB was reached after about 72 h. From the results of the adsorption isotherm, we verified that the degree of adsorption increased with increasing MB concentrations. In addition, the adsorption amount (Q) of MB decreased with an increase in calcination temperature. The experimental adsorption isotherm data were well fitted to the Freundlich and Sips equations compared to the Langmuir equation. In order to verify the effects of photocatalytic decomposition (C/C0) of MB on Fe2O3 present in prepared RFGPA, the degree of decomposition of MB was examined under dark and visible conditions. Results indicated that the decomposition of MB in visible conditions was about 3.0 times faster than that in dark conditions.

Investing the relationship between R&D expenditure and economic growth (연구개발투자와 경제성장의 상호관계 실증분석)

  • hyunyi Choi;Cho Keun Tae
    • Journal of Technology Innovation
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    • v.31 no.2
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    • pp.59-82
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    • 2023
  • The purpose of this research is to conduct the empirical analysis of the short- and long-term causal relationship between public R&D investment, corporate R&D investment, and university R&D investment on economic growth in Korea. To this end, based on the time series data from 1976 to 2020, a causality test was conducted through the unit root test, cointegration test, and vector error correction model (VECM). As a result, it was found that there is a long-run equilibrium relationship between economic growth in Korea, public R&D investment, corporate R&D investment, and university R&D investment, in which a causal relationship exists in the long run. Also, while public R&D investment has a short-term effect on economic growth, corporate and university R&D investment does not have a short-term effect on economic growth. In addition, the results shows that there is a bidirectional causal relationship between economic growth and public R&D investment, corporate R&D investment and public R&D investment, and university R&D investment and public R&D investment in the short term. Through this research, it was empirically found that a highly mutual relationship exists between public R&D investment, corporate R&D investment, university R&D investment and economic growth. In order to increase the ripple effect of R&D investment on economic growth in the future, R&D investment between universities and corporations should be mutually promoted, and R&D investment by corporations should have a positive effect on public R&D investment so that public R&D investment can contribute to future economic growth.

Adsorption Removal of Eosin Y by Granular Activated Carbon (입자상 활성탄에 의한 Eosin Y의 홉착제거)

  • Lee, Jong-Jib
    • Clean Technology
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    • v.16 no.4
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    • pp.277-283
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    • 2010
  • Eosin Y is used a colorant and dye but eosin Y is harmful toxic substance. In this study, the adsorption characteristics of granular activated carbon have been investigated for the adsorption of eosin dye dissolved in water. The effects of initial dye concentration, contact time, pH and temperature on adsorption of eosin by a fixed amount of activated carbon have been studied in batch adsorber and fixed bed. The adsorptivity of activated carbon for eosin Y were largely improved by pH control. When the pH was 3 in the sample, the eosin Y could be removed 99% of initial concentration (10 mg/L). The adsorption equilibrium data are successfully fitted to the Freundlich isotherm equation in the temperature range from 293 to 333 K. The estimated values of k and ${\beta}$ are 19.56-134.62, 0.442-0.678, respectively. The effects of the operation conditions of the fixed bed on the breakthrough curve were investigated. When the inlet eosin Y concentration is increased from 10 to 30 mg/L, the corresponding adsorption breaktime appears to decrease from 470 to 268 min at bed height of 3 cm and a constant flow rate of 2 g/min. When the initial eosin Y flow rate is increased from 1 to 3 g/min, the corresponding adsorption breaktime appears to decrease from 272 to 140 min at bed height of 3 cm and inlet concentration of 10 mg/L. Also, breaktime increased with increasing bed height at flow rate of 2 g/min and inlet concentration of 10 mg/L. And length of adsorption zone showed similar patterns.

Vehicle-Bridge Interaction Analysis of Railway Bridges by Using Conventional Trains (기존선 철도차량을 이용한 철도교의 상호작용해석)

  • Cho, Eun Sang;Kim, Hee Ju;Hwang, Won Sup
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.29 no.1A
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    • pp.31-43
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    • 2009
  • In this study, the numerical method is presented, which can consider the various train types and can solve the equations of motion for a vehicle-bridge interaction analysis by non-iteration procedure through formulating the coupled equations of motion. The coupled equations of motion for the vehicle-bridge interaction are solved by the Newmark ${\beta}$ of a direct integration method, and by composing the effective stiffness matrix and the effective force vector according to a analysis step, those can be solved with the same manner of the solving procedure of equilibrium equations in static analysis. Also, the effective stiffness matrix is reconstructed by the Skyline method for increasing the analysis effectiveness. The Cholesky's matrix decomposition scheme is applied to the analysis procedure for minimizing the numerical errors that can be generated in directly calculating the inverse matrix. The equations of motion for the conventional trains are derived, and the numerical models of the conventional trains are idealized by a set of linear springs and dashpots with 16 degrees of freedom. The bridge models are simplified by the 3 dimensional space frame element which is based on the Euler-Bernoulli theory. The rail irregularities of vertical and lateral directions are generated by the PSD functions of the Federal Railroad Administration (FRA). The results of the vehicle-bridge interaction analysis are verified by the experimental results for the railway plate girder bridges of a span length with 12 m, 18 m, and the experimental and analytical data are applied to the low pass filtering scheme, and the basis frequency of the filtering is a 2 times of the 1st fundamental frequency of a bridge bending.

The Long-Run Relation of Public Debt and Fiscal Balance to Government Bond Rates: An Empirical Study on the Validity of Modern Monetary Theory (국가부채 및 재정수지와 국채이자율의 장기적 관계: 현대화폐이론 검증을 중심으로)

  • Kangwoo Park
    • Analyses & Alternatives
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    • v.7 no.3
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    • pp.181-230
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    • 2023
  • Evaluating the empirical validity of Modern Monetary Theory, this study implements panel cointegration analysis on annual panel data (2000-2022) of OECD countries. Specifically, the sample countries are divided into groups based on the presence of their own sovereign currencies, and for each group, the long-run equilibrium relation (cointegration) between the ratio of public debt or fiscal deficit and government bond rates is tested and estimated. Main findings are as follows: applying the pooled mean-group estimation for panel cointegration, it is found that both the ratios of public debt and fiscal deficit have significantly positive long-run correlation with government bond rates in countries without sovereign currency such as the Euro-zone or fixed exchange rate regime countries. However, in countries with sovereign currency such as non-Euro-zone or floating exchange rate regime countries, the long-run correlation is either negative or not statistically significant. Particularly, in countries without sovereign currency, the ratio of public debt has significantly positive correlation with the real government bond rates in the short run as well as the long run. These results are consistent with the prediction of Modern Monetary Theory, thus providing a supporting evidence for the empirical validity of the theory.

Analysis of High School Students' Conceptual Change in Model-Based Instruction for Blood Circulation (혈액 순환 모형 기반 수업에서 고등학생들의 개념 변화 분석)

  • Kim, Mi-Young;Kim, Heui-Baik
    • Journal of The Korean Association For Science Education
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    • v.27 no.5
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    • pp.379-393
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    • 2007
  • The purpose of this article is to analyze the conceptual change of nine 11th graders after implementing the model-based instruction of blood circulation by multidimensional framework, and to find some implications about teaching strategies for improving conceptual understanding. The model-based instruction consisted of 4 periods: (1) introduction for inducing students' interests using an episode in the science history of blood circulation, (2) vivisectional experiment on rats, (3) visual-linguistic model instruction using the videotape of heartbeat, and (4) modeling activity on the path of blood flow. Based on the data from pre-test, post-test and interviews, we classified students' models on the path of blood flow, and investigated their ontological features and the conceptual status of blood circulation. Most students could describe the path of blood flow and the changes of substances in blood precisely after the instructions. However, the modeling activity were not sufficient to improve students' understanding of the mechanisms of the blood distribution throughout various organs and the material exchanges between blood and tissues. From the interview of 9 students, we acquired informative results about conceptual status elements that were helpful to, preventing from, or not used for students' understanding. It was also found that conceptual status of students depended on the ontological categories into which students' conceptions of blood circulation fell. The results of this study can help design the effective teaching strategy for the understanding of concept of the equilibrium category.

OD matrix estimation using link use proportion sample data as additional information (표본링크이용비를 추가정보로 이용한 OD 행렬 추정)

  • 백승걸;김현명;신동호
    • Journal of Korean Society of Transportation
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    • v.20 no.4
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    • pp.83-93
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    • 2002
  • To improve the performance of estimation, the research that uses additional information addition to traffic count and target OD with additional survey cost have been studied. The purpose of this paper is to improve the performance of OD estimation by reducing the feasible solutions with cost-efficiently additional information addition to traffic counts and target OD. For this purpose, we Propose the OD estimation method with sample link use proportion as additional information. That is, we obtain the relationship between OD trip and link flow from sample link use proportion that is high reliable information with roadside survey, not from the traffic assignment of target OD. Therefore, this paper proposes OD estimation algorithm in which the conservation of link flow rule under the path-based non-equilibrium traffic assignment concept. Numerical result with test network shows that it is possible to improve the performance of OD estimation where the precision of additional data is low, since sample link use Proportion represented the information showing the relationship between OD trip and link flow. And this method shows the robust performance of estimation where traffic count or OD trip be changed, since this method did not largely affected by the error of target OD and the one of traffic count. In addition to, we also propose that we must set the level of data precision by considering the level of other information precision, because "precision problem between information" is generated when we use additional information like sample link use proportion etc. And we Propose that the method using traffic count as basic information must obtain the link flow to certain level in order to high the applicability of additional information. Finally, we propose that additional information on link have a optimal counting location problem. Expecially by Precision of information side it is possible that optimal survey location problem of sample link use proportion have a much impact on the performance of OD estimation rather than optimal counting location problem of link flow.

Solubility of Hydrogen Sulfide and Methane in Ionic Liquids: 1-Ethy-3-methylimidazolium Trifluoromethanesulfonate and 1-Butyl-1-methylpyrrolidinium Trifluoromethanesulfonate (1-Ethyl-3-methylimidazolium trifluoromethanesulfonate와 1-Butyl-1-methylpyrrolidinium trifluoromethanesulfonate 이온성 액체에 대한 황화수소와 메탄의 용해도)

  • Lee, Byung-Chul
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.213-222
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    • 2016
  • Solubility data of hydrogen sulfide ($H_2S$) and methane ($CH_4$) in two kinds of ionic liquids with the same anion: 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ([emim][TfO]) and 1-butyl-1-methylpyrrolidinium trifluoromethanesulfonate ([bmpyr][TfO]) are presented at pressures up to about 30 MPa and at temperatures between 303 K and 343 K. The gas solubilities in ionic liquids were determined by measuring the bubble point pressures of the gas + ionic liquid mixtures with various compositions at different temperatures using a high-pressure equilibrium apparatus equipped with a variable-volume view cell. The $H_2S$ solubilities in ionic liquid increased with the increase of pressure and decreased with the increase of temperature. On the other hand, the $CH_4$ solubilities in ionic liquid increased significantly with the increase of pressure, but there was little effect of temperature on the $CH_4$ solubility. For the ionic liquds [emim][TfO] and [bmpyr][TfO] with the same anion, the solubility of $H_2S$ as a molality basis was substantially similar, regardless of the temperature and pressure conditions as a molar concentration basis. Comparing the solubilities of $H_2S$ and $CH_4$ in the ionic liquid [emim][TfO], the solubilities of $H_2S$ were much greater than those of $CH_4$. For the same type of ionic liquid, the solubility data of $H_2S$ and $CH_4$ obtained in this study were compared to the solubility data of $CO_2$ from the literature. When compared at the same pressure and temperature conditions, the $CO_2$ solubility was in between the solubility of $H_2S$ and $CH_4$.

Proton Affinity Distributions of Humic Acid Extracted from Upland and Paddy Soils (논·밭토양으로부터 추출한 Humic Acid의 수소이온 친화력 분포)

  • Jeong, Chang-Yoon;Park, Chan-Won;Kim, Jeong-Gyu;Lim, Soo-Kil
    • Korean Journal of Soil Science and Fertilizer
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    • v.32 no.4
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    • pp.429-439
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    • 1999
  • Potentiometric titration data were collected for some humic acids purified from Korean upland and paddy soils over a range of pH (3.0 - 11.0) with $NaNO_3$ background electrolyte concentrations (0.01, 0.10, 0.50 and 1.00 M). The data were applied to model A and V which included both intrinsic heterogeneity of humic materials and electrostatic interaction influences on binding sites. The elemental analysis were conducted for various type of humic samples. The $E_4/E_6$ ratio proposed negative correlation with the total carboxyl groups ($r^2$= 0.9988). The charge ($cmol_c\;kg^{-1}$) on the humic acids became more negative as the ionic strength increased. In both continuous and batch titrations, the ionic strength effect was greater in Namweon series (pH 6.39) than others at pH 5.00. The effect of ionic strength on surface charge appears to be greater in batch titrations. This could suggest that continuous titrations do not represent an equilibrium state and the effects of electrolyte concentration was not fully realized during the course of titrations. Both models described experimental data obtained from continuous and batch titrations well over a range of ionic strengths. Model A is more simpler than model V but adaptes more fitted parameters. Thus, the observed change in apparent binding constants with surface charge is regarded solely due to electrostatic influences rather than functional group heterogeneity. However, Model V is more mechanistically realistic in a number of discrete ligand binding sites.

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