• Applied Chemistry for Engineering
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• 제23권2호
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• pp.148-152
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• 2012

Anatase and anatase/rutile $TiO_2$ samples were prepared at $HNO_3$/TTIP molar ratio of 0.1, 0.5, 1.0, and 1.5 to study the effects of the physical properties of $TiO_2$ on photocatalytic decomposition of methylene blue. The physical properties of the samples were measured with XRD, SEM, TEM, BET, FT-IR, and UV-vis spectroscopy. Anatase phase was observed at $HNO_3$/TTIP of 0.1 and anatase/rutile phases were observed at $HNO_3$/TTIP of 0.5~1.5. Rutile crystal phase, mesopore size between $TiO_2$ nanoparticles, and surface OH group on $TiO_2$ sample were gradually increased with increasing the molar ratio of $HNO_3$/TTIP and the residual methylene blue concentration before UV irradiation decreased from 78.0 to 53.3%. After UV irradiation, the residual methylene blue concentrations of the samples prepared at $HNO_3$/TTIP of 0.1, 0.5, 1.0, and 1.5 were 20, 14, 11, and 23%, respectively, and the sample prepared at $HNO_3$/TTIP of 1.0 showed the best photocatalytic ability.

• Journal of the Korea Academia-Industrial cooperation Society
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• 제12권11호
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• pp.5227-5237
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• 2011

Technology roadmap is a powerful tool that considers relationships of technology, product and market and referred as a supporting technology strategy and planning. There are numerous studies that have attempted to develop technology roadmap and case studies on specific technology areas. However, a number of studies have been dependant on brainstorming and discussion of expert group, delphi technique as qualitative analysis rather than systemic and quantitative analysis. To overcome the limitation, patent analysis considered as quite quantitative analysis is employed in this paper. Therefore, this paper proposes new technology roadmapping based on patent citation network considering technology life cycle and suggests planning for undeveloped technology but considered as promising. At first, patent data and citation information are collected and patent citation network is developed on the basis of collected patent information. Secondly, we investigate a stage of technology in the life cycle by considering patent application year and the technology life cycle, and duration of technology development is estimated. In addition, subsequent technologies are grouped as nodes of a super-level technology to show the evolution of the technology for the period. Finally, a technology roadmap is drawn by linking these technology nodes in a technology layer and estimating the duration of development time. Based on technology roadmap, technology planning is conducted to identify undeveloped technology through text mining and this paper suggests characteristics of technology that needs to be developed in the future. In order to illustrate the process of the proposed approach, technology for hydrogen storage is selected in this paper.

• Journal of Korean Home Economics Education Association
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• 제33권1호
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• pp.151-167
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• 2021

This study reports on the development of a dietary education program for Korean young adults in single-person households. The 7th National Health and Nutrition Survey (2016-2018) was used to compare and analyze the dietary behavior of single-person households and multi-person households, and an online survey was conducted on 350 young adults (age 19-39 years) living in Seoul. According to the analysis, single-person households had higher rates of breakfast and eating out than multi-person households, and significantly lower average intake of energy and nutrients (p<0.05). In particular, in the case of single-person households, the lower the frequency of cooking at home, the higher the rate of breakfast and the higher the frequency of eating out and delivery food (p<0.05). Based on the survey, a dietary education program for young adults single-person households was developed by applying the DESIGN six-step procedure and social cognitive theory as a conceptual model. The first session consisted of the health and economic benefits of home-cooked meals, the second session of the importance of the breakfast and the effect of exercise in life, the third session of the importance of balanced nutrition and the principles of a healthy diet, the fourth session of food safety and storage, and the fifth session of social dining. Each session was composed of a combination of theoretical lectures to motivate 'more making and eating healthy home-cooked meals' and cooking practice for improving behavioral performance.

• Journal of the Korea Academia-Industrial cooperation Society
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• 제22권4호
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• pp.587-593
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• 2021

Since 2017, a total of 29 fire accidents have occurred in energy storage systems (ESSs) as of June 2020. The common mode voltage (CMV) is one of the electrical hazards that is assumed to be a cause of those fire accidents. Several cases of CMV that violate the allowable insulation level of a battery section are being reported in actual ESS operation sites with △-Y winding connections. Thus, this paper evaluates the characteristics of CMV. An ESS site was modeled with an AC grid, PCS, and battery sections using PSCAD/EMTDC software. As a result of a simulation based on the proposed model, it was confirmed that characteristics of CMV vary significantly and are similar to actual measurements, depending on the grounding method of the internal transformer for PCS. The insulation level of the battery section may be severely degraded as the value of CMV exceeds the rated voltage in case of a grounding connection. It was found that the value of CMV dramatically declines when the internal transformer for PCS is operated as non-grounding connection, so it meets the standard insulation level.

• Applied Chemistry for Engineering
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• 제29권6호
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• pp.759-764
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• 2018

3D porous carbon electrodes (cNPIM), prepared by solution casting of a polymer of intrinsic microporosity (PIM-1) followed by nonsolvent-induced phase separation (NIPS) and carbonization are presented. In order to effectively control the pore size of 3D porous carbon structures, cNPIM was prepared by varying the THF ratio of mixed solvents. The SEM analysis revealed that cNPIMs have a unique 3D macroporous structure having a gradient pore structure, which is expected to grant a smooth and easy ion transfer capability as an electrode material. In addition, the cNPIMs presented a very large specific surface area ($2,101.1m^2/g$) with a narrow micropore size distribution (0.75 nm). Consequently, the cNPIM exhibits a high specific capacitance (304.8 F/g) and superior rate capability of 77% in an aqueous electrolyte. We believe that our approach can provide a variety of new 3D porous carbon materials for the application to an electrochemical energy storage.

• Journal of the Korea Academia-Industrial cooperation Society
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• 제20권6호
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• pp.80-85
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• 2019

Vanadium dioxide is a well-known metal-insulator phase transition material. Lots of researches of vanadium redox flow batteries have been researched as large scale energy storage system. In this study, vanadium oxide($VO_x$) thin films were applied to cathode for lithium ion battery. The $VO_x$ thin films were deposited on Si substrate($SiO_2$ layer of 300 nm thickness was formed on Si wafer via thermal oxidation process), quartz substrate by RF magnetron sputter system for 60 minutes at $500^{\circ}C$ with different RF powers. The surface morphology of as-deposited $VO_x$ thin films was characterized by field-emission scanning electron microscopy. The crystallographic property was confirmed by Raman spectroscopy. The optical properties were characterized by UV-visible spectrophotometer. The coin cell lithium-ion battery of CR2032 was fabricated with cathode material of $VO_x$ thin films on Cu foil. Electrochemical property of the coin cell was investigated by electrochemical analyzer. As the results, as increased of RF power, grain size of as-deposited $VO_x$ thin films was increased. As-deposited thin films exhibit $VO_2$ phase with RF power of 200 W above. The transmittance of as-deposited $VO_x$ films exhibits different values for different crystalline phase. The cyclic performance of $VO_x$ films exhibits higher values for large surface area and mixed crystalline phase.

• Parasites, Hosts and Diseases
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• 제57권4호
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• pp.341-357
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• 2019

Acanthamoeba, one of free-living amoebae (FLA), remains a high risk of direct contact with this protozoan parasite which is ubiquitous in nature and man-made environment. This pathogenic FLA can cause sight-threatening amoebic keratitis (AK) and fatal granulomatous amoebic encephalitis (GAE) though these cases may not commonly be reported in our clinical settings. Acanthamoeba has been detected from different environmental sources namely; soil, water, hotspring, swimming pool, air-conditioner, or contact lens storage cases. The identification of Acanthamoeba is based on morphological appearance and molecular techniques using PCR and DNA sequencing for clinico-epidemiological purposes. Recent treatments have long been ineffective against Acanthamoeba cyst, novel anti-Acanthamoeba agents have therefore been extensively investigated. There are efforts to utilize synthetic chemicals, lead compounds from medicinal plant extracts, and animal products to combat Acanthamoeba infection. Applied nanotechnology, an advanced technology, has shown to enhance the anti-Acanthamoeba activity in the encapsulated nanoparticles leading to new therapeutic options. This review attempts to provide an overview of the available data and studies on the occurrence of pathogenic Acanthamoeba among the Association of Southeast Asian Nations (ASEAN) members with the aim of identifying some potential contributing factors such as distribution, demographic profile of the patients, possible source of the parasite, mode of transmission and treatment. Further, this review attempts to provide future direction for prevention and control of the Acanthamoeba infection.

• Journal of the Korean Electrochemical Society
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• 제21권4호
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• pp.80-87
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• 2018

Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

• Journal of the Korean Electrochemical Society
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• 제22권3호
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• pp.87-103
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• 2019

Nonaqueous organic electrolyte solution in commercially available lithium-ion batteries, due to its flammability, corrosiveness, high volatility, and thermal instability, is demanding to be substituted by safer solid electrolyte with higher cycle stability, which will be utilized effectively in large-scale power sources such as electric vehicles and energy storage system. Of various types of solid electrolytes, composite solid electrolytes with polymer matrix and active inorganic fillers are now most promising in achieving higher ionic conductivity and excellent interface contact. In this review, some kinds and brief history of solid electrolyte are at first introduced and consequent explanations of polymer solid electrolytes and inorganic solid electrolytes (including active and inactive fillers) are comprehensively carried out. Composite solid electrolytes including these polymer and inorganic materials are also described with their electrochemical properties in terms of filler shapes, such as particle (0D), fiber (1D), plane (2D), and solid body (3D). In particular, in all-solid-state lithium batteries using lithium metal anode, the interface characteristics are discussed in terms of cathode-electrolyte interface, anode-electrolyte interface, and interparticle interface. Finally, current requisites and future perspectives for the composite solid electrolytes are suggested by help of some decent reviews recently reported.

• Composites Research
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• 제32권1호
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• pp.78-84
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• 2019

This study focused on the prediction of the long-term performance of carbon fiber/epoxy composites using Dynamic Mechanical Analysis (DMA) and Time-Temperature Superposition (TTS). Single-frequency test, multi-frequency test, and creep TTS test were performed. A sinusoidal load of $20{\mu}m$ amplitude was applied while increasing the temperature from $-30^{\circ}C$ to $240^{\circ}C$ at $2^{\circ}C/min$ for the single-frequency test and the multi-frequency test. The frequencies applied to the multi-frequency test were 0.316, 1, 3.16, 10 and 31.6 Hz. In the creep TTS test, a stress of 15 MPa was applied for 10 minutes at every $10^{\circ}C$ from $-30^{\circ}C$ to $230^{\circ}C$. The glass transition temperature was determined by single-frequency test. The activation energy and the storage modulus curve for each temperature were obtained from glass transition temperature for each frequency by the multi-frequency test. The master curve for the reference temperature was obtained by applying the shift factor using the Arrhenius equation. Also, TTS test was used to obtain the creep compliance curves for each temperature and the master curve for the reference temperature by applying the shift factors using the manual shift technique. The master curve obtained through this process can be applied to predict the long-term performance of carbon fiber/epoxy composites for a given environmental condition.