• Title/Summary/Keyword: energy degradation

검색결과 1,732건 처리시간 0.033초

PET분해효소(PETase) 과발현 전세포 촉매의 해양미세플라스틱 생분해 활성 연구 (Biodegradation of marine microplastics by the whole-cell catalyst overexpressing recombinant PETase)

  • 김현지;박종하;박애란;이대희;전준호;권혁택;임성인
    • 한국해양바이오학회지
    • /
    • 제14권2호
    • /
    • pp.133-142
    • /
    • 2022
  • The increased production and consumption of polyethylene terephthalate (PET)-based products over the past several decades has resulted in the discharge of countless tons of PET waste into the marine environment. PET microparticles resulting from the physical erosion of general PET wastes end up in the ocean and pose a threat to the marine biosphere and human health, necessitating the development of new technologies for recycling and upcycling. Notably, enzyme-mediated PET degradation is an appealing option due to its eco-friendly and energy-saving characteristics. PETase, a PET-hydrolyzing enzyme originating from Ideonella sakaiensis, is one of the most thoroughly researched biological catalysts. However, the industrial application of PETase-mediated PET recycling is limited due to the low stability and poor reusability of the enzyme. Here we developed the whole-cell catalyst (WCC) in which functional PETase is attached to the outer membrane of Escherichia coli. Immunoassays are used to identify the surface-expressed PETase, and we demonstrated that the WCC degraded PET microparticles most efficiently at 30℃ and pH 9 without agitation. Furthermore, the WCC increased the PET-degrading activity in a concentration-dependent manner, surpassing the limited activity of soluble PETase above 100 nM. Finally, we demonstrated that the WCC could be recycled up to three times.

Retrofitted built-up steel angle members for enhancing bearing capacity of latticed towers: Experiment

  • Wang, Jian-Tao;Wu, Xiao-Hong;Yang, Bin;Sun, Qing
    • Steel and Composite Structures
    • /
    • 제41권5호
    • /
    • pp.681-695
    • /
    • 2021
  • Many existing transmission or communication towers designed several decades ago have undergone nonreversible performance degradation, making it hardly meet the additional requirements from upgrades in wind load design codes and extra services of electricity and communication. Therefore, a new-type non-destructive reinforcement method was proposed to reduce the on-site operation of drilling and welding for improving the quality and efficiency of reinforcement. Six built-up steel angle members were tested under compression to examine the reinforcement performance. Subsequently, the cyclic loading test was conducted on a pair of steel angle tower sub-structures to investigate the reinforcement effect, and a simplified prediction method was finally established for calculating the buckling bearing capacity of those new-type retrofitted built-up steel angles. The results indicates that: no apparent difference exists in the initial stiffness for the built-up specimens compared to the unreinforced steel angles; retrofitting the steel angles by single-bolt clamps can guarantee a relatively reasonable reinforcement effect and is suggested for the reduced additional weight and higher construction efficiency; for the substructure test, the latticed substructure retrofitted by the proposed reinforcement method significantly improves the lateral stiffness, the non-deformability and energy dissipation capacity; moreover, an apparent pinching behavior exists in the hysteretic loops, and there is no obvious yield plateau in the skeleton curves; finally, the accuracy validation result indicates that the proposed theoretical model achieves a reasonable agreement with the test results. Accordingly, this study can provide valuable references for the design and application of the non-destructive upgrading project of steel angle towers.

열변형 저감을 위한 고분자 복합소재 배합 조건에 따른 재료특성 분석 (Analysis of Material Properties According to Compounding Conditions of Polymer Composites to Reduce Thermal Deformation)

  • 변상원;김영신;전의식
    • 반도체디스플레이기술학회지
    • /
    • 제21권1호
    • /
    • pp.148-154
    • /
    • 2022
  • As the 4th industrial age approaches, the demand for semiconductors is increasing enough to be used in all electronic devices. At the same time, semiconductor technology is also developing day by day, leading to ultraprecision and low power consumption. Semiconductors that keep getting smaller generate heat because the energy density increases, and the generated heat changes the shape of the semiconductor package, so it is important to manage. The temperature change is not only self-heating of the semiconductor package, but also heat generated by external damage. If the package is deformed, it is necessary to manage it because functional problems and performance degradation such as damage occur. The package burn in test in the post-process of semiconductor production is a process that tests the durability and function of the package in a high-temperature environment, and heat dissipation performance can be evaluated. In this paper, we intend to review a new material formulation that can improve the performance of the adapter, which is one of the parts of the test socket used in the burn-in test. It was confirmed what characteristics the basic base showed when polyamide, a high-molecular material, and alumina, which had high thermal conductivity, were mixed for each magnification. In this study, functional evaluation was also carried out by injecting an adapter, a part of the test socket, at the same time as the specimen was manufactured. Verification of stiffness such as tensile strength and flexural strength by mixing ratio, performance evaluation such as thermal conductivity, and manufacturing of a dummy device also confirmed warpage. As a result, it was confirmed that the thermal stability was excellent. Through this study, it is thought that it can be used as basic data for the development of materials for burn-in sockets in the future.

Seismic performance of CFS shear wall systems filled with polystyrene lightweight concrete: Experimental investigation and design methodology

  • Mohammad Rezaeian Pakizeh;Hossein Parastesh;Iman Hajirasouliha;Farhang Farahbod
    • Steel and Composite Structures
    • /
    • 제46권4호
    • /
    • pp.497-512
    • /
    • 2023
  • Using light weight concrete as infill material in conventional cold-formed steel (CFS) shear wall systems can considerably increase their load bearing capacity, ductility, integrity and fire resistance. The compressive strength of the filler concrete is a key factor affecting the structural behaviour of the composite wall systems, and therefore, achieving maximum compressive strength in lightweight concrete while maintaining its lightweight properties is of significant importance. In this study a new type of optimum polystyrene lightweight concrete (OPLC) with high compressive strength is developed for infill material in composite CFS shear wall systems. To study the seismic behaviour of the OPLC-filled CFS shear wall systems, two full scale wall specimens are tested under cyclic loading condition. The effects of OPLC on load-bearing capacity, failure mode, ductility, energy dissipation capacity, and stiffness degradation of the walls are investigated. It is shown that the use of OPLC as infill in CFS shear walls can considerably improve their seismic performance by: (i) preventing the premature buckling of the stud members, and (ii) changing the dominant failure mode from brittle to ductile thanks to the bond-slip behaviour between OPLC and CFS studs. It is also shown that the design equations proposed by EC8 and ACI 318-14 standards overestimate the shear force capacity of OPLC-filled CFS shear wall systems by up to 80%. This shows it is necessary to propose methods with higher efficiency to predict the capacity of these systems for practical applications.

에틸벤젠을 이용한 실리콘 산화물 음극재의 효과적인 카본 코팅 전략 (Effective problem mitigation strategy of lithium secondary battery silicon anode utilized liquid precursor)

  • 이상렬;박성수;채수종
    • 한국표면공학회지
    • /
    • 제56권1호
    • /
    • pp.62-68
    • /
    • 2023
  • Silicon (Si) is considered as a promising substitute for the conventional graphite due to its high theoretical specific capacity (3579 mAh/g, Li15Si4) and proper working voltage (~0.3V vs Li+/Li). However, the large volume change of Si during (de)lithiation brings about severe degradation of battery performances, rendering it difficult to be applied in the practical battery directly. As a one feasible candidate of industrial Si anode, silicon monoxide (SiOx) demonstrates great electrochemical stability with its specialized strategy, downsized Si nanocrystallites surrounded by Li+ inactive buffer phase (Li2O and Li4SiO4). Nevertheless, SiOx inherently has the initial irreversible capacity and poor electrical conductivity. To overcome those issues, conformal carbon coating has been performed on SiOx utilizing ethylbenzene as the carbon precursor of chemical vapor deposition (CVD). Through various characterizations, it is confirmed that the carbon is homogeneously coated on the surface of SiOx. Accordingly, the carbon-coated SiOx from CVD using ethylbenzene demonstrates 73% of the first cycle efficiency and great cycle life (88.1% capacity retention at 50th cycle). This work provides a promising synthetic route of the uniform and scalable carbon coating on Si anode for high-energy density.

스크린 프린팅 공정에 의해 제조된 비데용 Ag-Pd 봉형 발열체의 내구성 및 물성 평가 (Durability and Characteristics of Ag-Pd Rod Heater for Bidet Fabricated by Screen Printing Process )

  • 박태웅;현다은;김익수;이성철;이연숙;김용남;이동원;오종민
    • 한국전기전자재료학회논문지
    • /
    • 제36권1호
    • /
    • pp.81-87
    • /
    • 2023
  • Heaters using the resistance heating principle are used in various industrial fields that require heat and are also essentially used in bidet among small home appliances. A planar heater and a coil-inserted heater mounted on a conventional commercially used bidet have disadvantages and limitations of complicated manufacturing process and local heating. In this study, silver-palladium (Ag-Pd) powder material was used for a screen-printing process that is more advantageous in achieving simplification than the existing process, and a rod-type heater for bidet was manufactured. The on-off cycle test under actual conditions was conducted to confirm the durability and the capability of the fabricated heater, and the fabricated heater operated more than 2,600 on-off cycles, which means it could be applied for a commercial product. In addition, through the on-off cycles under harsh conditions, the cause of failure was identified after the test that the durability limit temperature of the heater was 850℃. Through Ag-Pd rod heater in this study, it is expected to contribute to the efficient development of electrode materials for heaters and the improvement of the durability of heaters in the future.

임베디드 엣지 플랫폼에서의 경량 비전 트랜스포머 성능 평가 (Performance Evaluation of Efficient Vision Transformers on Embedded Edge Platforms)

  • 이민하;이성재;김태현
    • 대한임베디드공학회논문지
    • /
    • 제18권3호
    • /
    • pp.89-100
    • /
    • 2023
  • Recently, on-device artificial intelligence (AI) solutions using mobile devices and embedded edge devices have emerged in various fields, such as computer vision, to address network traffic burdens, low-energy operations, and security problems. Although vision transformer deep learning models have outperformed conventional convolutional neural network (CNN) models in computer vision, they require more computations and parameters than CNN models. Thus, they are not directly applicable to embedded edge devices with limited hardware resources. Many researchers have proposed various model compression methods or lightweight architectures for vision transformers; however, there are only a few studies evaluating the effects of model compression techniques of vision transformers on performance. Regarding this problem, this paper presents a performance evaluation of vision transformers on embedded platforms. We investigated the behaviors of three vision transformers: DeiT, LeViT, and MobileViT. Each model performance was evaluated by accuracy and inference time on edge devices using the ImageNet dataset. We assessed the effects of the quantization method applied to the models on latency enhancement and accuracy degradation by profiling the proportion of response time occupied by major operations. In addition, we evaluated the performance of each model on GPU and EdgeTPU-based edge devices. In our experimental results, LeViT showed the best performance in CPU-based edge devices, and DeiT-small showed the highest performance improvement in GPU-based edge devices. In addition, only MobileViT models showed performance improvement on EdgeTPU. Summarizing the analysis results through profiling, the degree of performance improvement of each vision transformer model was highly dependent on the proportion of parts that could be optimized in the target edge device. In summary, to apply vision transformers to on-device AI solutions, either proper operation composition and optimizations specific to target edge devices must be considered.

저속 충격 하중을 받은 탄소섬유강화 복합재 압력용기의 잔류강도 저하 평가 (Evaluation of Residual Strength of CFRP Pressure Vessel After Low Velocity Impact)

  • 박재범;김동륜;김형근;황태경
    • Composites Research
    • /
    • 제21권3호
    • /
    • pp.9-17
    • /
    • 2008
  • 본 논문에서는 저속충격하중을 받은 필라멘트 와인딩 탄소섬유강화 복합재 압력용기의 잔류강도 저하특성에 대한 수치해석 및 실험결과에 대해서 논한다. 복합재 압력용기의 원통부의 여러 곳에 대해 낙하 공구의 끝단을 모사한 삼각형 충격자를 사용한 저속 충격시험이 실시되었고, 유한요소해석을 수행하여 충격시의 기계적 변형 및 응력분포 거동에 대한 예측을 실시하였다. 충격하중을 받은 복합재 압력용기의 잔류강도 저하 특성을 정량적으로 평가하기 위해, 충격부위를 포함하는 원환시편을 압력용기의 실린더부로부터 채취하여, 원주방향 내압인장강도 측정 수압시험법으로부터, 원환시편의 수압파열 압력을 측정하였다. 결과적으로 본 연구를 통해 충격 에너지의 수준에 따른 잔류강도 변화가 성공적으로 계측되었으며, 복합재 압력용기의 충격손상허용을 정량적으로 평가하기 위한 유용한 방법론이 정립되었다.

Mitigating Metal-dissolution in a High-voltage 15 wt% Si-Graphite‖Li-rich Layered Oxide Full-Cell Utilizing Fluorinated Dual-Additives

  • Kim, Jaeram;Kwak, Sehyun;Pham, Hieu Quang;Jo, Hyuntak;Jeon, Do-Man;Yang, A-Reum;Song, Seung-Wan
    • Journal of Electrochemical Science and Technology
    • /
    • 제13권2호
    • /
    • pp.269-278
    • /
    • 2022
  • Utilization of high-voltage electrolyte additive(s) at a small fraction is a cost-effective strategy for a good solid electrolyte interphase (SEI) formation and performance improvement of a lithium-rich layered oxide-based high-energy lithium-ion cell by avoiding the occurrence of metal-dissolution that is one of the failure modes. To mitigate metal-dissolution, we explored fluorinated dual-additives of fluoroethylene carbonate (FEC) and di(2,2,2-trifluoroethyl)carbonate (DFDEC) for building-up of a good SEI in a 4.7 V full-cell that consists of high-capacity silicon-graphite composite (15 wt% Si/C/CF/C-graphite) anode and Li1.13Mn0.463Ni0.203Co0.203O2 (LMNC) cathode. The full-cell including optimum fractions of dual-additives shows increased capacity to 228 mAhg-1 at 0.2C and improved performance from the one in the base electrolyte. Surface analysis results find that the SEI stabilization of LMNC cathode induced by dual-additives leads to a suppression of soluble Mn2+-O formation at cathode surface, mitigating metal-dissolution event and crack formation as well as structural degradation. The SEI and structure of Si/C/CF/C-graphite anode is also stabilized by the effects of dual-additives, contributing to performance improvement. The data give insight into a basic understanding of cathode-electrolyte and anode-electrolyte interfacial processes and cathode-anode interaction that are critical factors affecting full-cell performance.

Seismic performance of RC columns retrofitted using high-strength steel strips under high axial compression ratios

  • Yang, Yong;Hao, Ning;Xue, Yicong;Feng, Shiqiang;Yu, Yunlong;Zhang, Shuchen
    • Structural Engineering and Mechanics
    • /
    • 제84권3호
    • /
    • pp.345-360
    • /
    • 2022
  • In this paper, the impact on seismic performance of an economical effective technique for retrofitting reinforced concrete (RC) columns using high-strength steel strips under high axial compression ratios was presented. The experimental program included a series of cyclic loading tests on one nonretrofitted control specimen and three retrofitted specimens. The effects of the axial compression ratio and spacing of the steel strips on the cyclic behavior of the specimens were studied. Based on the test results, the failure modes, hysteretic characteristics, strength and stiffness degradation, displacement ductility, and energy dissipation capacity of the specimens were analyzed in-depth. The analysis showed that the transverse confinement provided by the high-strength steel strips could effectively delay and restrain diagonal crack development and improve the failure mode, which was flexural-shear failure controlled by flexural failure with better ductility. The specimens retrofitted using high-strength steel strips showed more satisfactory seismic performance than the control specimen. The seismic performance and deformation capacity of the retrofitted RC columns increased with decreasing axial compression ratio and steel strip spacing. Based on the test results, a hysteretic model for RC columns that considers the transverse confinement of high-strength steel strips was then established. The hysteretic model showed good agreement with the experimental results, which verified the effectiveness of the proposed hysteretic model. Therefore, the aforementioned analysis can be used for the design of retrofitted RC columns.