• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.33-38
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• 2019

In order to invigoration the hydrogen economy, production of hydrogen needed for hydrogen charging stations and hydrogen fuel cells is needed. Generally, it is reforming used to coal fuel or natural gas. Other technologies include water electrolysis using pure water. Among these water electrolysis technologies, development is mainly carried out using PEM(Polymer Electrolyte Membrane electrolysis). In this study, the company aims to identify potential harmful hazards to PEM electrolysis hydrogen stations in the development stage among hydrogen charging stations. In order to find the hazardous factors in the facilities of the electrolysis and hydrogen charging stations, we were analyzed by Failure Mode & Effect Analysis(FMEA).

• Journal of the Korean Society of Safety
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• v.9 no.1
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• pp.95-99
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• 1994

Recently, there has been considerable concern about waste water discharges of chromium. The Chromium(IV) is of particular concern because this form has been demonstrated to be public health hazard. Chromium(IV) could be removed by the method of electrolysis from plating waste water. It was found that almost all of chromium(IV) present could be treated by electrolysis at current, 3A and pH 8.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.4
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• pp.331-337
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• 2017

Proton Exchange Membrane Water Electrolysis (PEMWE) is one of the most popular and widely used methods for hydrogen production. PEMWE contributes to eco-friendly system via its energy storage system application, hence making it environmentally friendly to use. However, its main drawback is contamination of proton exchange membrane during water electrolysis. Existing cation such as magnesium, calcium and the likes are the cause for membrane contamination. As a result, the cation contamination give rise to degradation of performance of electrolysis and the reverse electrolysis is effective method to remove cation.

• Proceedings of the KIPE Conference
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• 2010.07a
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• pp.196-197
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• 2010

This paper investigates a high performance converter topology for hydrogen gas generation electrolysis system. The proposed converter topology consists of full-bridge inverter, medium frequency transformer, and diode rectifier. Hydrogen gas generation electrolysis process considered in the paper is analyzed and characterized by its equivalent circuit. The electrolysis cell is modeled as effective resistance, capacitance, inductance, and internal emf voltage source. The proposed converter topology provides enhanced efficiency of hydrogen gas generation process under the operating condition of dc output voltage with high frequency ripple on it. The high performance operation of proposed converter is confirmed through the simulation with the electrolysis cell considered in the equivalent circuit model.

• Journal of Korean Society on Water Environment
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• v.22 no.2
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• pp.264-270
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• 2006

In this research, volume reduction of activated sludge using electrolysis was studied to find an optimum condition using lab scale experiments. Wasted sludge was treated by electrolysis with controlling current density, chloride concentration, electrode distance, and reaction time. Volume of return sludge was reduced by 9.79% in average while maximum was 16.7%. Sludge volume reduction efficiency was affected by current density and reaction time. It was reversely proportional to the electrode distance. Especially current density was effective on the system performance significantly. Electric conductivity, salinity and COD were increased by electrolysis implying sludge disintegrated and converted to COD in part. An empirical equation for total solid removal efficiency by electrolysis was proposed by multiple linear regression analysis as: $TS_{rem}$(%) = 5.534 ${\times}$ current density (A/l) + 0.178 ${\times}$ reaction time (m) + 2.758.

• Proceedings of the KIEE Conference
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• 2001.04a
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• pp.198-201
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• 2001

The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electrical for the high efficiency of water electrolysis equipment. First, chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated. For basic experiment, unit electrode of singular electrolysis electrode is manufactured and experimented, results are compared and analyzed with simulation, and the electrolysis is electrically equivalent.

• Journal of the Korean institute of surface engineering
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• v.55 no.2
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• pp.38-50
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• 2022

As a low-cost and high-efficiency electrocatalysts with high performance and stability become a key challenge in the development of the practical use of water electrolysis, there is an intense interest in transition-metal oxalate-based materials. Transition-metal oxalate-based catalysts with excellent electrochemical performances have been widely applied in water electrolysis due to its low-cost and ease of synthesis. This review provides a useful summary on the development of transition-metal oxalate as potential catalysts for water electrolysis with a focus on the structural and compositional alteration, role of oxalate anion, and enhanced electrochemical performances.

• Transactions of the Korean hydrogen and new energy society
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• v.14 no.4
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• pp.335-347
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• 2003

High temperature electrolysis (HTE) can become a key target technology for fulfilling the hydrogen requirement for the future hydrogen economy. This technology is based upon the partial replacement of electricity with heat energy for the electrolysis. Although the current research status of high temperature electrolysis in many countries remains at the small laboratory scale, the technology has great potential for producing hydrogen at a higher efficiency than low-temperature electrolysis (LTE). The efficiency of LTE is not expected to rise above 40%, whereas the efficiency of HTE has been reported to be above 50%. The higher efficiency of HTE would reduce costs by more than 30% compared to LTE. In this study, the technical data regarding the HTE of water and the resulting hydrogen production are reviewed, with an emphasis on the application of high temperature solid electrolyte and oxide electrodes for the HTE process.

• Journal of Environmental Science International
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• v.24 no.11
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• pp.1385-1391
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• 2015

A water reuse system was designed for a demonstration plant by combining fiber filtration and electrolysis. A discharged dye wastewater after treated with biomedia was used in this study. It was found that an additional removal of suspended solids (SS) was feasible with 2-stage filtration while electrolysis was not effective. Also, $COD_{cr}$ and $COD_{Mn}$ were not removed with 2 -stage filtration but electrolysis resulted in about 26.9% additional removal. This indicates that electrolysis play an important role in organic removal. Removal of T-N and T-P was negligible with 1 and 2-stage fiber filtration and low-level electrolyte. However, with 2000 ppm of electrolyte, their removal efficiencies were about 83.1 and 60%, respectively, suggesting that the removal rates are well associated with the electrolyte concentrations. With high-level electrolyte, colority was removed about 82% while chlorine ions were removed only about 10%. Therefore, to treat underground water containing high-level salinity in the follow-up study, based on the results in this paper, a combined system with selection of additional unit process and reverse osmosis will be designed.

• Transactions of the Korean hydrogen and new energy society
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• v.28 no.6
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• pp.657-662
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• 2017

This paper presents the reversible electrolysis characteristics of a solid oxide fuel cell (SOFC) using a $10{\times}10cm^2$ anode supported planar cell with an active area of $81cm^2$. In this work, current-voltage characteristic test and reversible electrolysis cycle test were carried out sequentially for 2,114 hours at a furnace temperature of $700^{\circ}C$. The current-voltage characteristics for reversible electrolysis mode was measured at a current of ${\pm}26.7A$ under various $H_2O$ utilization conditions. The reversible electrolysis cycle was performed 50 times at a current of ${\pm}32.4A$. As a result, The performance degradation of SOEC mode was larger than that of SOFC mode.