• 제목/요약/키워드: electrode contact resistance

검색결과 168건 처리시간 0.028초

Embedding Cobalt Into ZIF-67 to Obtain Cobalt-Nanoporous Carbon Composites as Electrode Materials for Lithium ion Battery

  • Zheng, Guoxu;Yin, Jinghua;Guo, Ziqiang;Tian, Shiyi;Yang, Xu
    • Journal of Electrochemical Science and Technology
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    • 제12권4호
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    • pp.458-464
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    • 2021
  • Lithium ion batteries (LIBs) is a kind of rechargeable secondary battery, developed from lithium battery, lithium ions move between the positive and negative electrodes to realize the charging and discharging of external circuits. Zeolitic imidazolate frameworks (ZIFs) are porous crystalline materials in which organic imidazole esters are cross-linked to transition metals to form a framework structure. In this article, ZIF-67 is used as a sacrificial template to prepare nano porous carbon (NPC) coated cobalt nanoparticles. The final product Co/NPC composites with complete structure, regular morphology and uniform size were obtained by this method. The conductive network of cobalt and nitrogen doped carbon can shorten the lithium ion transport path and present high conductivity. In addition, amorphous carbon has more pores that can be fully in contact with the electrolyte during charging and discharging. At the same time, it also reduces the volume expansion during the cycle and slows down the rate of capacity attenuation caused by structure collapse. Co/NPC composites first discharge specific capacity up to 3115 mA h/g, under the current density of 200 mA/g, circular 200 reversible capacity as high as 751.1 mA h/g, and the excellent rate and resistance performance. The experimental results show that the Co/NPC composite material improves the electrical conductivity and electrochemical properties of the electrode. The cobalt based ZIF-67 as the precursor has opened the way for the design of highly performance electrodes for energy storage and electrochemical catalysis.

극성/무극성 6H-SiC 쇼트키 베리어 다이오드 제조 및 전기적 특성 연구 (A Study About Electrical Properties and Fabrication Schottky Barrirer Diode Prepared on Polar/Non-Polar of 6H-SiC)

  • 김경민;박성현;이원재;신병철
    • 한국전기전자재료학회논문지
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    • 제23권8호
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    • pp.587-592
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    • 2010
  • We have fabricated schottky barrier diode (SBDs) using polar (c-plane) and non polar (a-, m-plane) n-type 6H-SiC wafers. Ni/SiC ohmic contact was accomplished on the backside of the SiC wafers by thermal evaporation and annealed for 20minutes at $950^{\circ}C$ in mixture gas ($N_2$ 90% + $H_2$ balanced). The specific contact resistance was $3.6{\times}10^{-4}{\Omega}cm^2$ after annealing at $950^{\circ}C$. The XRD results of the alloyed contact layer show that formation of $NiSi_2$ layer might be responsible for the ohmic contact. The active rectifying electrode was formed by the same thermal evaporation of Ni thin film on topside of the SiC wafers and annealed for 5 minutes at $500^{\circ}C$ in mixture gas ($N_2$ 90% + $H_2$ balanced). The electrical properties of SBDs have been characterized by means of I-V and C-V curves. The forward voltage drop is about 0.95 V, 0.8 V and 0.8 V for c-, a- and m-plane SiC SBDs respectively. The ideality factor (${\eta}$) of all SBDs have been calculated from log(I)-V plot. The values of ideality factor were 1.46, 1.46 and 1.61 for c-, a- and m-plane SiC SBDs, respectively. The schottky barrier height (SBH) of all SBDs have been calculated from C-V curve. The values of SBH were 1.37 eV, 1.09 eV and 1.02 eV for c-, a- and m-plane SiC SBDs, respectively.

중공사막 가습에 따른 PEMFC의 성능 평가 (Performance Test of PEMFC with Hollow Fiber Membrane)

  • 이호열;천광우;박창권;오병수
    • 한국수소및신에너지학회논문집
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    • 제16권1호
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    • pp.82-91
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    • 2005
  • Polymer membrane needs to maintain appropriate moisture. Insufficient moisture causes low conduction of hydrogen ion because of increased contact resistance between electrode and membrane by shrinking membrane, and abundant moisture decreases fuel cell performance as difficulty of diffusion reacting gas. Therefore, water controlling system is very consequential for the polymer membrane fuel cell. If hollow fiber membrane humidification is used between fuel and air lines, it is possible to supply heat to fuel and air by using thermal exchanger. It can supply appropriate humidity depending on operating temperature, and can recover heat from exhaust gas which contains water vapor and air. Because of simple structure of humidification system, this system can be easily applied in the PEMFC and cut down cost.

High Resolution Electrodes Fabrication for OTFT Array by using Microcontact Printing and Room Temperature Process

  • Jo, Jeong-Dai;Choi, Ju-Hyuk;Kim, Kwang-Young;Lee, Eung-Sug;Esashi, Masayoshi
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.186-189
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    • 2006
  • The flexible organic thin film transistor (OTFT) array to use as a switching device for an organic light emitting diode (OLED) was designed and fabricated in the microcontact printing and room temperature process. The gate, source, and drain electrode patterns of OTFT were fabricated by microcontact printing process. The OTFT array with dielectric layer and organic active semiconductor layer formed at room temperature or at a temperature lower than $40^{\circ}C$. The microcontact printing process using SAM and PDMS stamp made it possible to fabricate OTFT arrays with channel lengths down to even submicron size, and reduced the fabrication process by 10 steps compared with photolithography. Since the process was done in room temperature, there was no pattern shrinkage, transformation, and bending problem appeared. Also, it was possible to improve electric field mobility, to decrease contact resistance, to increase close packing of molecules by SAM, and to reduce threshold voltage by using a big dielectric.

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The Electrical Characterization of Magnetic Tunneling Junction Cells Using Conductive Atomic Force Microscopy with an External Magnetic Field Generator

  • Heo, Jin-Hee
    • Transactions on Electrical and Electronic Materials
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    • 제11권6호
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    • pp.271-274
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    • 2010
  • We examined the tunneling current behaviors of magnetic tunneling junction (MTJ) cells utilizing conductive atomic force microscopy (AFM) interfaced with an external magnetic field generator. By introducing current through coils, a magnetic field was generated and then controlled by a current feedback circuit. This enabled the characterization of the tunneling current under various magnetic fields. The current-voltage (I-V) property was measured using a contact mode AFM with a metal coated conducting cantilever at a specific magnetic field intensity. The obtained magnetoresistance (MR) ratios of the MTJ cells were about 21% with no variation seen from the different sized MTJ cells; the value of resistance $\times$ area (RA) were 8.5 K-12.5 K $({\Omega}{\mu}m^2)$. Since scanning probe microscopy (SPM) performs an I-V behavior analysis of ultra small size without an extra electrode, we believe that this novel characterization method utilizing an SPM will give a great benefit in characterizing MTJ cells. This novel method gives us the possibility to measure the electrical properties of ultra small MTJ cells, namely below $0.1\;{\mu}m\;{\times}\;0.1\;{\mu}m$.

미세접촉프린팅공정을 이용한 플렉시블 디스플레이 유기박막구동소자 제작 (Fabrication of Organic Thin Film Transistor(OTFT) for Flexible Display by using Microcontact Printing Process)

  • 김광영;조정대;김동수;이제훈;이응숙
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.595-596
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    • 2006
  • The flexible organic thin film transistor (OTFT) array to use as a switching device for an organic light emitting diode (OLED) was designed and fabricated in the microcontact printing and low-temperature processes. The gate, source, and drain electrode patterns of OTFT were fabricated by microcontact printing which is high-resolution lithography technology using polydimethylsiloxane(PDMS) stamp. The OTFT array with dielectric layer and organic active semiconductor layers formed at room temperature or at a temperature tower than $40^{\circ}C$. The microcontact printing process using SAM(self-assembled monolayer) and PDMS stamp made it possible to fabricate OTFT arrays with channel lengths down to even nano size, and reduced the procedure by 10 steps compared with photolithography. Since the process was done in low temperature, there was no pattern transformation and bending problem appeared. It was possible to increase close packing of molecules by SAM, to improve electric field mobility, to decrease contact resistance, and to reduce threshold voltage by using a big dielecric.

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인체전류를 기반으로 하는 감전의 위험성 평가방법 (A Method for Evaluating Electric Shock Hazards Based on Human Body Current)

  • 이복희;유양우;최종혁
    • 조명전기설비학회논문지
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    • 제25권6호
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    • pp.108-114
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    • 2011
  • In order to mitigate the possible hazards from electric shock due to the touch and step voltages, the high resistivity material such as gravel is often spread on the earth's surface in substations. When the grounding electrode is installed in two-layer soil structures, the surface layer soil resistivity is different with the resistivity of the soil contacted with the grounding electrodes. The design of large-sized grounding systems is fundamentally based on assuring safety from dangerous voltages within a grounding grid area. The performance of the grounding system is evaluated by tolerable touch and step voltages. Since the floor surface conditions near equipment to be grounded are changed after a grounding system has been constructed, it may be difficult to determine the tolerable touch and step voltage criteria. In this paper, to propose an accurate and convenient method for evaluating the protective performance of grounding systems, the propriety of the method for evaluating the current flowing through the human body around on a counterpoise buried in two-layer soils is presented. As a result, it is reasonable that the grounding system performance would be evaluated by measuring and analyzing the current flowing through the human body based on dangerous voltages such as the touch or step voltages and the contact resistance between the ground surface and feet.

기판의 코로나 표면처리에 의한 탄소 나노튜브 투명전극의 물성 향상 (Improvement of Transparent Electrodes Based on Carbon Nanotubes Via Corona Treatment on Substrate Surface)

  • 한상훈;김부종;박진석
    • 반도체디스플레이기술학회지
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    • 제13권1호
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    • pp.7-12
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    • 2014
  • In this study, we investigate the effects of corona-discharge pre-treatment on the properties of carbon nanotubes (CNTs) which are used as flexible transparent electrodes. The CNTs are deposited on PET (polyethylene terephthalate) substrates using a spray coating method. Prior to the deposition of CNTs, the PET substrates are corona-treated by varying the feeding directions of the PET substrate and the numbers of treatments. The variations in the surface morphologies and roughnesses of the PET substrates due to corona-treatment are characterized via atomic force microscopy (AFM). Dynamic contact angles (DCAs) of the corona-treated PET substrates are measured and analyzed as functions of the treatment conditions. Also, the sheet resistances and visible-range transmittances of the CNTs deposited on PET substrates are measured before and after bending test. The experimental results obtained in this study provide strong evidences that the adhesive forces between CNTs and PET substrates can be substantially enhanced by corona-discharge pretreatment.

약물치료의 부작용개선을 위한 이온도입 시스템(WIT-I)에 관한 연구 (A Study on the Ion Transfer System(WIT-I) for Improve on Side effect of Pharmacotherapy)

  • 어윤기;양경모;채진욱;이인섭;이재형;정동명
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1996년도 춘계학술대회
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    • pp.226-231
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    • 1996
  • Recently Iontophoresis is tried to physical therapy field.. It is method for direct penetrate to skin with ionization pharmacon because it is decreased side effect of pharmacon treatment such as gastrophathy and aphylaris of disease-causing germs. We designed WIT-I that is trial manufacture for clinical experiment This system is has been elrectrical paramete with 0-140V out range, 1-7mA current 1-15mim time set. Invite experiment, WIT-I kept designed performance which is a constant current in variable load resistance such as skin and electrode contact. It is estimated to have a practical use for physical therapy by iontophcresis.

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태양광 발전단지 내부 그리드의 안전 특성화 접지 설계에 관한 연구 (A Study on the Safety Characterization Grounding Design of the Inner Photovoltaic System)

  • 김홍용;윤석호
    • 한국재난정보학회 논문집
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    • 제14권2호
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    • pp.130-140
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    • 2018
  • 연구목적: 본 논문에서는 우리사회의 대체 전력 에너지원으로 적합하고 유용하게 활용 할 수 있는 태양광 발전 단지 건설 시 안전 특성화 접지에 관한 설계 기법을 제안하고자 한다. 즉, 태양광 발전 단지 내의 셀 모듈부터 전기실까지 내부 그리드의 신뢰성을 향상하고 최적화 할 수 있는 용도별 안전 접지를 적용한 사례들을 소개하고자 한다. 연구방법: 태양광 발전 단지 내 토양의 대지 고유저항을 분석하고 컴퓨터 프로그램(CDEGS)을 활용해 전격을 일으키는 접촉전압과 보폭전압을 해석하여 안전접지에 관한 계산과 산출방법에 대해 제안한다. 또한, 토양 환경을 고려한 반영구적인 접지전극의 재료 선정에 관한 연구에 중요성을 논하고자 한다. 연구결과: Wenner 4 전극법으로 측정한 데이터 중 3개 지역의 CASE별 대지 고유저항 최대값과 최소값을 얻을 수 있었고 이 두 값으로 토양의 두께를 알 수 있다. 측정된 데이터를 기본수식 ${\rho}=6.28aR$에 대입하여 MATLAB 컴퓨터 프로그램으로 계산하였다. 즉, 최소 저항값의 두께는 접지전극을 설치하기에 가장 유리한 토양 환경임을 판단 할 수 있다. 결론: 본 연구를 통해 지역의 CASE별 태양광 발전소 내부 그리드에 대지 표면에 전위상승을 억제 할 수 있는 접지시스템 설계기법을 제안하였다. 하지만 대지의 고유저항과 접지시스템에 경련변화를 실시간으로 확인 할 수 있는 모니터링 시스템과 빅 데이터를 축적 할 수 있는 스마트 디바이스의 개발이 추가적으로 연구되어야 할 것이다.