• 제목/요약/키워드: electrochemical pump

검색결과 22건 처리시간 0.024초

자발 구동형 종이 펌프를 이용한 종이 전기화학 센서 (Paper-based Electrochemical Sensor Using a Self-operated Paper Pump)

  • ;김치관;;김용신
    • 센서학회지
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    • 제33권3호
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    • pp.158-164
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    • 2024
  • We developed a self-operated paper pump that can maintain a nearly constant flow rate of an aqueous solution along a paper strip channel in paper-based analytical devices (PADs). The quasi-stationary flow rate was controlled by increasing the crosssectional channel area (capillary force) using a fan-shaped absorption pad coupled with a paper strip channel. The flow rate is regulated by varying the fan angle of the circular absorbing pad. Furthermore, the flow rate can be increased by furnishing a hollow cavity at the center of a conventional paper strip channel. The rate was regulated by varying the length of the hollow paper channel in the flow rate range of 5.1-26.4 mm/min. As a preliminary work, a paper-pump-coupled PAD was fabricated, and its CV detection capability was evaluated for the redox reaction of Fe(CN)6+4/+3. The combination of a paper pump with a PAD resulted in an ideal CV curve with a higher limiting current and faster response time. These results are interpreted well by the Levich equation, which suggests that the paper pump is a very useful component in paper-based sensors.

Development of LiFePO4/FePO4 Electrode for Electro-Osmotic Pump using Li+ Migration

  • Baek, Jaewook;Kim, Kyeonghyeon;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • 제9권2호
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    • pp.85-92
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    • 2018
  • Olivine structure of $LiFePO_4$ (LFP) is one of the most commonly used materials in aqueous rechargeable lithium batteries (ARLBs), and can store and release charge through the insertion/de-insertion of $Li^+$ between LFP and FP. We have fabricated LFP and LFP/FP electrodes on titanium paper and studied their electrochemical properties in 2 M $Li_2SO_4$. The LFP/FP electrode was determined to be a suitable electrode for electo-ostmotic pump (EOP) in terms of efficiency in water and 0.5 mM $Li_2SO_4$ solution. Experiments to determine the effect of cations and anions on the performance of EOP using LFP/FP electrode have shown that $Li^+$ is the best cation and that the anion does not significantly affect the performance of the EOP. As the concentration of $Li_2SO_4$ solution was increased, the current increased. The flow rate peaked at $4.8{\mu}L/30s$ in 1.0 mM $Li_2SO_4$ solution and then decreased. When the EOP was tested continuously in 1.0 mM $Li_2SO_4$ solution, the EOP transported approximately 35 mL of fluid while maintaining a stable flow rate and current for 144 h.

Electrodeposition of Mn-Ni Oxide/PEDOT and Mn-Ni-Ru Oxide/PEDOT Films on Carbon Paper for Electro-osmotic Pump Electrode

  • Baek, Jaewook;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • 제9권2호
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    • pp.93-98
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    • 2018
  • $MnO_2$, a metal oxide used as an electrode material in electrochemical capacitors (EDLCs), has been applied in binary oxide and conducting polymer hybrid electrodes to increase their stability and capacitance. We developed a method for electrodepositing Mn-Ni oxide/PANI, Mn-Ni oxide/PEDOT, and Mn-Ni-Ru oxide/PEDOT films on carbon paper in a single step using a mixed bath. Mn-Ni oxide/PEDOT and Mn-Ni-Ru oxide/PEDOT electrodes used in an electro-osmotic pump (EOP) have shown better efficiency compared to Mn-Ni oxide and Mn-Ni oxide/PANI electrodes through testing in water as a pumping solution. EOP using a Mn-Ni-Ru oxide/PEDOT electrode was also tested in a 0.5 mM $Li_2SO_4$ solution as a pumping solution to confirm the effect of the $Li^+$ insertion/de-insertion reaction of Ruthenium oxide on the EOP. Experimental results show that the flow rate increases with the increase in current in a 0.5 mM $Li_2SO_4$ solution compared to that obtained when water was used as a pumping solution.

전기화학적 수소 압축기 기술 (A Review of Electrochemical Hydrogen Compressor Technology)

  • 김상경
    • 한국수소및신에너지학회논문집
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    • 제31권6호
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    • pp.578-586
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    • 2020
  • There is growing interest worldwide in a hydrogen economy that uses hydrogen as an energy medium instead of hydrocarbon-based fossil fuels as a way to combat climate change. Since hydrogen has a very low energy density per unit volume at room temperature, hydrogen must be compressed and stored in order to use as an energy carrier. There are mechanical and non-mechanical methods for compressing hydrogen. The mechanical method has disadvantages such as high energy consumption, durability problems of moving parts, hydrogen contamination by lubricants, and noise. Among the non-mechanical compression methods, electrochemical compression consumes less energy and can compress hydrogen with high purity. In this paper, research trends are reviewed, focusing on research papers on electrochemical hydrogen compression technology, and future research directions are suggested.

해수와 청수환경에서 선박용 원심펌프 임펠러 재료의 캐비테이션 특성 (Cavitation Characteristics on Impeller Materials of Centrifugal Pump for Ship in Sea Water and Fresh Water)

  • 임명환
    • Corrosion Science and Technology
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    • 제10권6호
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    • pp.218-224
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    • 2011
  • The fresh water and sea water in present ships is used as cooling water for marine engine. Therefore, corrosion damage in seawater system is frequently occurred. In particular, in the impeller of pump, the performance and material span due to the corrosion and cavitation erosion has adverse effects. Most of the pump impellers in vessels are used Cu-Al alloy. Cu-Al alloy which having the excellent mechanical properties and corrosion resistance is widely used in marine environments. However, despite the excellent characteristics, the periodic replacement parts due to the cavitation damage in seawater is vulnerable to economic viewpoint. In this study, Cu-Al alloy used with impeller for centrifugal pump were conducted various experiments to evaluate its characteristics in seawater and fresh water solutions. As an electrochemical result, the dynamic conditions that exposed to the cavitation environment presented high corrosion current density with collapse of the cavity compared with the static conditions. Cavitation test results, the weightloss and weightloss rate in fresh water are observed more than those of seawater.

원자로 냉각재 펌프용 재료의 화학 제염 공정 시 적용 가능성 평가 (Evaluation of application possibility in chemical decontamination of materials for reactor coolant pump)

  • 김정일;김기준;김성종
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권1호
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    • pp.84-94
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    • 2007
  • As a reactor coolant pump(RCP) is operated in the nuclear power system for a long time. so its surface is continuously contaminated by radioactive scales. In order to perform regular or emergency repair about RCP internals a special decontamination process should be used to reduce the radiation from the RCP surface by means of chemical cleaning. In this study, applicable possibility in chemical decontamination for RCP was investigated on the various materials. The STS 304 showed the best electrochemical properties for corrosion resistance than other materials. However, the pitting corrosion was slightly generated in both STS 415 and STS 431 with the increasing numbers of cycle and intergranular corrosion were sporadically observed. The size of their pitting corrosion and intergranular corrosion were also increased with increasing cycle numbers.

원자로 냉각재 펌프용 스테인리스강에 대한 화학적 제염 공정 개발(II) (Development of Chemical Decontamination Process of Stainless Steel for Reactor Coolant Pump(II))

  • 김성종;김정일;김기준
    • 한국표면공학회지
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    • 제40권6호
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    • pp.271-278
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    • 2007
  • In this study, applicable possibility in chemical decontamination for reactor coolant pump(RCP) was investigated for the various stainless steels. The stainless steel(STS) 304 showed the best electrochemical properties for corrosion current density and the lowest weight loss ratio in chemical decontamination process model 3-3 than other materials. The weightloss quantity in chemical decontamination process model 3-3 presents the lowest value compare to the other chemical decontamination process model 1, 2, 3-1 and 3-2. In the case of SEM observation, the pitting corrosion was generated in both STS 415 and STS 431 with the increasing numbers of cycle. The intergranular corrosion in STS 431 was sporadically observed. The sizes of their pitting corrosion were also increased with increasing cycle numbers.

Effects of Cofilin and PMA on $NA^+-K^+$ Pump Current in Guinea- pig Ventricular Myocytes

  • Lee, So-Young;Jaehoon Jung;Lee, Chin O.;Lee, Kyunglim
    • 한국생물물리학회:학술대회논문집
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    • 한국생물물리학회 2001년도 학술 발표회 진행표 및 논문초록
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    • pp.45-45
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    • 2001
  • The Na$^{+}$-K$^{+}$ pump, a plasma membrane Na$^{+}$-K$^{+}$ ATPase is plays a key role in the regulation and maintenance of Na$^{+}$ and $K^{+}$ ion concentration gradients across cell membranes. This enzyme pumps three Na$^{+}$ out of and two $K^{+}$ into the cell against their electrochemical gradient by utilizing the energy derived from ATP. Therefore, the Na$^{+}$-K$^{+}$ pump generates a net outward electrical current.(omitted)ted)

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휴대용 연료전지 시스템의 소음 저감에 대한 연구 (A Study on the Noise Reduction of a Portable Fuel Cell System)

  • 전인열;배준수;오민정;최상현;이충호
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2006년도 춘계학술대회논문집
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    • pp.858-861
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    • 2006
  • In this paper, a study on the noise reduction in a mobile fuel cell system is presented. Among various fuel cell systems around 20W capacities designed for mobile electronic devices, the active direct methanol fuel cell (DMFC) systems have been recently developed. In such systems, the primary noise source is the air pump which provides sufficient air flow ($5{\sim}6$ liter/min) for electrochemical reaction with methanol fuel while the noise contributions from other auxiliary parts are relatively small. Especially, the discrete noise tones generated by the air pump are dominant and those frequency peaks related to the rotor harmonics are needed to be suppressed by a silencer. Therefore. the Herschel/Quinke (HQ) tubes, which use the out-of-phase cancellation of acoustic waves propagating through direct and indirect pathways, are applied to the inlet of the air pump. Performance of noise reduction with HQ silencer is analytically estimated by calculating the transmission. The length and number of thin HQ tubes are optimized to decrease the radiated noise. As a result, the sound pressure level could be successfully reduced by about 10 dB after applying three serially connected HQ tubes.

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원자로 냉각재 펌프용 스테인리스강에 대한 화학적 제염 공정 개발 (Development of Chemical Decontamination Process of Stainless Steel for Reactor Coolant Pump)

  • 김성종;한민수;김정일;김기준
    • 한국표면공학회지
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    • 제40권5호
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    • pp.234-240
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    • 2007
  • As a reactor coolant pump (RCP) is operated in the nuclear power system for a long time, so its surface is continuously contaminated by radioactive scales. In order to maintain for RCP internals, a special chemical decontamination process should be used to reduce the radiation from the RCP surface. In this study, applicable possibility in chemical decontamination for RCP was investigated for the various stainless steels. The stainless steel (STS) 304 showed the best electrochemical properties for corrosion resistance and the lowest weight loss ratio in chemical decontamination process model 3-1 than other materials. However, the pitting corrosion was generated in both STS 415 and STS 431 with the increasing numbers of cycle. The intergranular corrosion in STS 415 was sporadically observed. The sizes of their pitting corrosion were also increased with increasing cycle numbers.