Browse > Article
http://dx.doi.org/10.5229/JECST.2018.9.2.93

Electrodeposition of Mn-Ni Oxide/PEDOT and Mn-Ni-Ru Oxide/PEDOT Films on Carbon Paper for Electro-osmotic Pump Electrode  

Baek, Jaewook (Department of Chemistry, Sogang University)
Shin, Woonsup (Department of Chemistry, Sogang University)
Publication Information
Journal of Electrochemical Science and Technology / v.9, no.2, 2018 , pp. 93-98 More about this Journal
Abstract
$MnO_2$, a metal oxide used as an electrode material in electrochemical capacitors (EDLCs), has been applied in binary oxide and conducting polymer hybrid electrodes to increase their stability and capacitance. We developed a method for electrodepositing Mn-Ni oxide/PANI, Mn-Ni oxide/PEDOT, and Mn-Ni-Ru oxide/PEDOT films on carbon paper in a single step using a mixed bath. Mn-Ni oxide/PEDOT and Mn-Ni-Ru oxide/PEDOT electrodes used in an electro-osmotic pump (EOP) have shown better efficiency compared to Mn-Ni oxide and Mn-Ni oxide/PANI electrodes through testing in water as a pumping solution. EOP using a Mn-Ni-Ru oxide/PEDOT electrode was also tested in a 0.5 mM $Li_2SO_4$ solution as a pumping solution to confirm the effect of the $Li^+$ insertion/de-insertion reaction of Ruthenium oxide on the EOP. Experimental results show that the flow rate increases with the increase in current in a 0.5 mM $Li_2SO_4$ solution compared to that obtained when water was used as a pumping solution.
Keywords
Electro-osmotic pump (EOP); Supercapacitor; Manganese oxide; Nickel oxide; Ruthenium oxide;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
연도 인용수 순위
1 W. Shin, E. Zhu, R. K. Nagarale, C. H. Kim, J. M. Lee, S. J. Shin, A. Heller, Anal. Chem., 2011, 83(12), 5023-5025.   DOI
2 A. Nishino, J. Power Sources, 1996, 60(2), 137-147.   DOI
3 E. Faggioli, P. Rena, V. Danel, X. Andrieu, R. Mallant, H. Kahlen, J. Power Sources, 1999, 84(2), 261-269.   DOI
4 A. Burke, J. Power Sources, 2000, 91(1), 37-50.   DOI
5 P. Simon, Y. Gogotsi, Nat. Mater., 2008, 7(11), 845-854.   DOI
6 Y. Wang, Y. Song, Y. Xia, Chem. Soc. Rev., 2016, 45(21), 5925-5950.   DOI
7 C. D. Lokhande, D. P. Dubal, O.-S. Joo, Curr. Appl. Phys., 2011, 11(3), 255-270.   DOI
8 W. Deng, X. Ji, Q. Chen, C. E. Banks, RSC Adv., 2011, 1(7), 1171-1178.   DOI
9 G. A. Snook, P. Kao, A. S. Best, J. Power Sources, 2011, 196(1), 1-12.   DOI
10 L. Nyholm, G. Nystrom, A. Mihranyan, M. Stromme, Adv. Mater., 2011, 23(33), 3751-3769.   DOI
11 L.-M. Huang, H.-Z. Lin, T.-C. Wen, A. Gopalan, Electrochim. Acta., 2006, 52(3), 1058-1063.   DOI
12 R. Liu, S. B. Lee, J. Am. Chem. Soc., 2008, 130(10), 2942-2943.   DOI
13 D. Szymanska, I. A. Rutkowska, L. Adamczyk, S. Zoladek, P. J. Kulesza, J. Solid State Electrochem., 2010, 14(11), 2049-2056.   DOI
14 B. Babakhani, D. G. Ivey, Electrochim. Acta., 2010, 55(12), 4014-4024.   DOI
15 S. C. Pang, M. A. Anderson, T. W. Chapman, J. Electrochem. Soc., 2000, 147(2), 444-450.   DOI
16 M. Ghaemi, L. Binder, J. Power Sources, 2002, 111(2), 248-254.   DOI
17 Y.-S. Chen, C.-C. Hu, Electrochem. Solid State Lett., 2003, 6(10), A210-A213.   DOI
18 Z. Sun, S. Firdoz, E. Ying-Xuan Yap, L. Li, X. Lu, Nanoscale, 2013, 5(10), 4379-4387.   DOI
19 H.-M. Lee, K. Lee, C.-K. Kim, Materials, 2014, 7, 265-274.   DOI
20 P.-Y. Chuang, C.-C. Hu, Mater. Chem. Phys., 2005, 92(1), 138-145.   DOI
21 D.-S. Lin, C.-T. Chou, Y.-W. Chen, K.-T. Kuo, S.-M. Yang, J. Appl. Polym. Sci., 2006, 100(5), 4023-4044.   DOI
22 L.-J. Bian, F. Luan, S.-S. Liu, X.-X. Liu, Electrochim. Acta., 2012, 64, 17-22.   DOI
23 J. Jiang, Y. Li, J. Liu, X. Huang, C. Yuan, X. W. Lou, Adv. Mater., 2012, 24(38), 5166-5180.   DOI
24 L. Groenendaal, F. Jonas, D. Freitag, H. Pielartzik, J. R. Reynolds, Adv. Mater., 2000, 12(7), 481-494.   DOI
25 Z. Liu, C. Tang, P. Chen, Q. Yu, W. Li, RSC Adv., 2014, 4(51), 26881-26887.   DOI
26 Y. R. Ahn, M. Y. Song, S. M. Jo, C. R. Park, D. Y. Kim, Nanotechnology, 2006, 17(12), 2865.   DOI
27 D. Susanti, D.-S. Tsai, Y.-S. Huang, Sci. Adv. Mater., 2010, 2(4), 552-559.   DOI
28 J. Jung, M. Cho, M. Zhou, AIP Adv., 2014, 4(1), 017104.   DOI
29 Y.-Y. Hu, Z. Liu, K.-W. Nam, O. J. Borkiewicz, J. Cheng, X. Hua, M. T. Dunstan, X. Yu, K. M. Wiaderek, L.-S. Du, K. W. Chapman, P. J. Chupas, X.-Q. Yang, C. P. Grey, Nat. Mater., 2013, 12(12), 1130-1136.   DOI
30 A. S. Hassan, A. Navulla, L. Meda, B. R. Ramachandran, C. D. Wick, J. Phys. Chem. C, 2015, 119(18), 9705-9713.   DOI