• 제목/요약/키워드: dye addition

Search Result 385, Processing Time 0.03 seconds

Analysis of an ancient textiles from the Xianbei period tombs of the Shiveet Khairkhan site, Mongolia (몽골 시베트 하이르한 유적 선비 시기(1~3세기) 고분 출토 직물의 섬유와 염료 분석)

  • YUN Eunyoung;YU Jia;PARK Serin;AN Boyeon
    • Korean Journal of Heritage: History & Science
    • /
    • v.55 no.4
    • /
    • pp.166-177
    • /
    • 2022
  • The Shiveet Khairkhan is located on Tsengel Som in the middle of Bayan-ulgi Aimag in the Altai region. Various remains have been identified, and it has been found to be an important area of the Eurasian steppe. In this study, the characteristics of textile fibers and dyes excavated from the tombs of the 1st~3rd century Xianbei period in the sites of Shiveet Khairkhan, Mongolia were investigated. As a result of analysis using optical microscopic observation and attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR) for fiber identification, green and yellow fabrics were identified as silk fabrics. To investigate the properties of the dye, the surface reflectance of the dyed fabric was measured using an fiber optic reflectance spectrophotometer for non-destructive analysis. The green fabric appeared similar to the reflection spectrum of indigo dye. In addition, as a result of component analysis using gas chromatography-mass spectrometry, isatin and indigotine were detected. Isatin and indigotine are characteristic components of indigo dye, and it was found that the green fabric of the tombs of the Xianbei period was dyed using indigo dye. It was difficult to identify the type of dye in the yellow fabric as a result of reflectance spectrum and gas chromatography analysis. Indigo plants are a dye used for blue dyeing from thousands of years ago, and many species are distributed around the world. It was confirmed that the fabric was relatively well preserved and indigo dye was used for the green Jikryeongui (garment with a straight collar) in the ancient tomb of the Xianbei period about 1,800 years ago, even though it was buried for a long time. Scientific investigation of textile cultural heritage is an essential process for conservation treatment, restoration, exhibition, and the creation of a conservation environment. It is expected that related research will be activated in the future and will be helpful in interpreting the living culture at the time, preserving textiles, and a conservation environment.

A study on a power plant using Dye-sensitized solar cells in low light environments (저조도 환경에서의 염료감응형 태양전지를 활용한 발전소자에 관한 연구)

  • Kim, Sun-Geum;Baek, Sung-June
    • Journal of IKEEE
    • /
    • v.25 no.2
    • /
    • pp.267-272
    • /
    • 2021
  • Recently, attention has been focused on renewable energy and carbon neutrality to resolve fossil energy depletion and environmental problems. In addition, high-rise urban buildings and an increase in building energy are rapidly increasing. There are many restrictions on installing solar power in urban areas. In addition, as buildings become taller, a lot of low-light environments in which shade is formed occur. Therefore, in this study, we intend to develop a power plant capable of generating electric power in an outdoor low-light environment and indoor lighting environment. The power plant in a low-light environment used a dye-sensitized solar cell. A unit cell and a 20cm×20cm module were manufactured, and the electrical characteristics of the power plant were measured using light sources of LED, halogen lamp, and 3-wavelength lamp. The photoelectric conversion efficiency of the unit cell was 17.2%, 1.28%, 19,2% for each LED, halogen lamp, and 3-wavelength lamp, and the photoelectric conversion efficiency of the 20cm×20cm module was 10.9%, 8.7%, and 11.8%, respectively. In addition, the maximum power value of the module was 13.1mW, 15.7 mW, and 14.2 mW for each light source, respectively, confirming the possibility of power generation in a low-light environment

Removal of Basic Dye from Aqueous Solution using Coal-based Granular Activated Carbon (석탄계 입상활성탄을 이용한 수용액으로부터 염기성 염료의 제거)

  • Choi, Han Ah;Park, Ha Neul;Moon, Hye Woon;Kim, Eun Bin;Jang, Yeon Woo;Won, Sung Wook
    • Clean Technology
    • /
    • v.23 no.2
    • /
    • pp.188-195
    • /
    • 2017
  • This research studied the adsorption of basic dye, Basic Blue 3 (BB3) by using coal-based granular activated carbon (C-GAC) from aqueous solution. All experiments were performed in batch processes, and adsorption parameters such as C-GAC dosage, contact time, initial dye concentration and temperature were evaluated. The removal efficiency of BB3 was increased with increasing the C-GAC dosage and 100% of initial concentration, $50mg\;L^{-1}$ was removed above 0.2 g of C-GAC. Also, the time to reach equilibrium depended on the initial dye concentration. According to the Langmuir model, the maximum uptakes of C-GAC were calculated to be 66.45, 84.97 and $87.19mg\;g^{-1}$ at 25, 35 and $45^{\circ}C$, respectively. In addition, thermodynamic parameters such as Gibbs free energy change, enthalpy change and entropy change were investigated.

Effects of the Addition of Water-soluble Polymers on Silk Dyeing (수용성 고분자를 이용한 견의 염색)

  • 황은경;김문식;이동수
    • Journal of Sericultural and Entomological Science
    • /
    • v.40 no.2
    • /
    • pp.136-142
    • /
    • 1998
  • The low-pollution dyeing condition and dyeing method suitable for the silk fiber were investigated. Instead of surfactants, water-soluble polymers and electrolytes were added as auxiliary agents in the new process of dyeing. By the new method, the level dyeing and sufficient exhaustion were achieved. The K/S values of silk fabrics were little different among electrolytes added in the dye-bath.

  • PDF

Urea Receptors which Have Both a Fat Brown RR and a Nitrophenyl Group as a Signaling Group

  • Lee, Sung-Kyu;Kang, Jong-Min
    • Bulletin of the Korean Chemical Society
    • /
    • v.30 no.12
    • /
    • pp.3031-3033
    • /
    • 2009
  • A new colorimetric anion sensor 1 has been synthesized based on both Fat brown RR dye and a nitrophenyl group. This new receptor 1 could recognize the presence of fluoride ion effectively and selectively by the change of color of solution. In addition, receptor 1 shows higher affinity for acetate, dihydrogenphosphate, and hydrogensulfate than the other anions such as chloride, bromide, iodide, perchlorate, and nitrate in acetonitrile.

Surfactant Effect on the Hydrophobic Interaction between Rhodamine 6G and Sodium Tetraphenylborate

  • Oh, Sae-Yung;Lee, Beom-Gyu;Kim, Kang-Jin
    • Bulletin of the Korean Chemical Society
    • /
    • v.9 no.5
    • /
    • pp.308-311
    • /
    • 1988
  • The hydrophobic interaction occurring between rhodamine 6G and tetraphenylborate was investigated spectroscopically by varying the medium with the addition of surfactants or ethanol. The ion aggregates formed between the two ions were destroyed by the additives. The dye existed as monomeric species in the presence of a cationic surfactant whereas it was incorporated with anionic and nonionic surfactants. For the complete dissociation more than the critical micelle concentration (cmc) was required with a nonionic surfactant while less than cmc was necessary with the others.

The Dyeing Properties of Woody Fiber Regenerated from Waste MDF by Reactive Dyes (반응성염료에 의한 폐MDF 재생 목질섬유의 염색특성)

  • Ju, Seon-Gyeong;Roh, JeongKwan
    • Journal of the Korean Wood Science and Technology
    • /
    • v.47 no.2
    • /
    • pp.163-177
    • /
    • 2019
  • This study aims to review the relations between the dyeing conditions (i.e., dye concentration, addition amounts of salt and alkali, and dyeing temperature) and dyeing properties and color fastness to light for identifying the optimal dyeing conditions when dyed regenerated woody fibers were obtained through the defibration of waste medium density fiberboard (MDF) using reactive Red H-E3B (Bis-monochlorotriazine (MCT)/MCT type) and reactive Red RB133% (Bis-MCT/Vinyl sulphone type). The dyeing yield (K/S) obtained using two types of reactive dyes increased as the dye concentration increased by 1-10% (on the weight of fiber (OWF)). In addition, the K/S of H-E3B was higher than that of RB133% irrespective of the dye concentration. The color difference of H-E3B after ultraviolet (UV) radiation was lower than that of RB133%, denoting good resistance to discoloration by UV. As the amount of sodium sulfate increased, the color difference and K/S also increased, and the adequate salt content was determined to be 50-70 g/L. Further, the color difference and K/S significantly increased only the addition of 2 g/L of sodium carbonate; however, almost no difference was observed when more than 2 g/L of sodium carbonate was added. The addition amount of sodium carbonate was adequate 5-10 g/L to dyeing the fiber and the pH at this addition level was 10. The dyeing yield of H-E3B increased when the dyeing temperature increased; however, it subsequently decreased after the dyeing temperature became $80^{\circ}C$. The dyeing yield of RB133% was almost the same up to $60-70^{\circ}C$ but declined subsequently. Thus, the adequate temperatures were $80^{\circ}C$ and $60^{\circ}C$ for H-E3B and RB133%, respectively. If the waste MDF woody fiber was dyed under the aforementioned optimal conditions, dyed regenerated woody fiber can be obtained having the following colors: 1.5 to 2.0R with the H-E3B dye and 9.6 to 10.0 PR with RB133%.

Properties of Dye Sensitized Solar Cells with Adding Nano Carbon Black into Blocking Layer

  • Kim, Kwangbae;Noh, Yunyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
    • /
    • v.52 no.4
    • /
    • pp.294-298
    • /
    • 2015
  • Blocking layers with nano carbon blacks (NCBs) were prepared by adding 0.0 ~ 0.5 wt% NCBs to the $TiO_2$ blocking layer. Then, dye sensitized solar cells (DSSCs) were fabricated with a $0.45cm^2$ active area. TEM and micro-Raman spectroscopy were used to characterize the microstructure and phases of the NCBs, respectively. Optical microscopy and AFM were used to analyze the microstructure of the $TiO_2$ blocking layer with NCBs. UV-VIS-NIS spectroscopy was used to determine the band gap of the $TiO_2$ blocking layer with NCBs. A solar simulator and potentiostat were used to determine the photovoltaic properties and impedance of DSSCs with NCBs. The energy conversion efficiency (ECE) increased from 3.53 to 6.20 % when the NCB content increased from 0.0 to 0.3 wt%. This indicates that the effective surface area and electron mobility increased in the $TiO_2$ blocking layer with NCBs. However, the ECE decreased when the NCB content was increased to over 0.4 wt%. This change occurred because the effective electron transport area decreased with the addition of excessive NCBs to the $TiO_2$ blocking layer. The results of this study suggest that the ECE of DSSCs can be enhanced by adding the appropriate amount of NCBs to the $TiO_2$ blocking layer.

Empirical modeling and statistical analysis of the adsorption of reactive dye on nylon fibers (나일론섬유에 대한 반응성 염료 흡착의 실험적 모델링 및 통계적 분석)

  • Kim, Byung-Soon;Ravikumar, K.;Son, Young-A
    • Textile Coloration and Finishing
    • /
    • v.18 no.4
    • /
    • pp.43-48
    • /
    • 2006
  • A phthalocyanine reactive dye was applied to nylon fibers to study the effects of the temperature and pH on % exhaustion and fixation. In addition, appropriate predictable empirical models, relatively new approaches in dyeing process, were developed incorporating interactions effects of temperature and pH for predicting the both % exhaustion and fixation. The significance of the mathematical model developed was ascertained using Excel regression (solver) analysis module. A very high correlation coefficient was obtained ($R^2=0.9895$ for % exhaustion, $R^2=0.9932$ for fixation) for the model which shows prominent prediction capacity of the model for the unknown conditions. The predictable polynomial equations developed from the Experimental results were thoroughly analyzed by ANOVA (Analysis of Variance) statistical concepts.

Glutathione is the Major Defensive Mechanism against Oxidative Stress in Human Embryonic Stem Cell

  • 이건섭;이영재;김은영;박세필;임진호
    • Proceedings of the KSAR Conference
    • /
    • 2003.06a
    • /
    • pp.78-78
    • /
    • 2003
  • Embryonic stem (ES) cells, derived from preimplantation embryo, are able to differentiate into various types of cells consisting the whole body, or pluripotency. In contrast, terminally differentiated cells do not usually alter their nature but frequently die or transform if they are exposed to inappropriate external stimulations. In addition to the plasticity, ES cells are expected to be different from terminally differentiated cells in very many ways, such as patterns of gene expressions, ability and response of the cells in confronting environmental stimulations, metabolism, and growth rate. As a model system to differentiate these two types of cells, human ES cells (MB03) and terminally differentiated cells (HeLa), we examined the ability of these two types of cells in confronting a severe oxidative insult, that is $H_2O$$_2$. Approximately 1$\times$10$^4$ cells were plated in 96 well plate and serum starved for overnight. The conditioned cells were exposed to a various concentration of $H_2O$$_2$ fur 24 hrs and loaded with neutral red (50$\mu\textrm{g}$/ml) for 4 hrs, washed with PBS for 2 min three times, and entrapped dye was dissolved out using acetic ethanol. Cytotoxicity was determined by reading the amount of dye in the medium using microplate reader. equipped with 575 nm filter. Relative amount of the dye entrapped within MB03 or HeLa were not significantly different when cells were exposed up to 0.4 mM $H_2O$$_2$. However, this sharply decreased down to 0.12% in HeLa cells when the cells were exposed to 0.8 mM $H_2O$$_2$, while it was approximately 54% in MB03 suggesting that this concentration of $H_2O$$_2$ is the defensive threshold for HeLa cells. The resistance to oxidative stimulation reversed, however, when cells were co-treated with BSO (L-buthionine- 〔S, R〕-sulfoximine) which chelates intracellular GSH. This result suggests that cellular GSH is the major defensive mechanism of human ES cells. Induction of enzymes involved in GSH metabolism and type of cell death is currently being studied.

  • PDF