• Title/Summary/Keyword: dissolving

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Preparation of Platinum Amine Complex Solution from Pt Scrap and its Catalytic Activity of Soot Oxidation (백금 스크랩으로부터 아민산백금용액 제조 및 Soot Oxidation 특성)

  • Choi, Seung Hoon
    • Resources Recycling
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    • v.27 no.3
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    • pp.93-99
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    • 2018
  • Effective extraction of platinum group elements by dissolving waste platinum scrap from the display industry and solvent extraction, was studied. The extracted platinum solution was prepared as a precursor solution for diesel automotive exhaust gas purification catalyst and its catalytic activity was tested. The behavior of aqueous species of platinum was investigated through solution chemistry and based on the existence and behavior of these chemical species, the possibility of extraction and separation was established. By dissolving waste scrap by electrochemical method, the dissolution time of scrap was shortened and the extraction efficiency was increased. Through separation and removal of rhodium component, solvent extraction by TBP, and stripping by hydrochloric acid, Pt-Chloride-$H_2O$ solution was prepared. And then, an platinum amine complex solution through amination reaction with this solution as a raw material was prepared. The possibility of producing high-value platinum compounds from platinum group waste scrap was investigated by preparing platinum amine complex solution and then examining the catalytic activity with this amine precursor on the combustion reaction of carbon black.

Fundamental Studies on the Boiling off Test of Raw Silk (생사연감검사에 관한 기초시험)

  • 김현수;이덕로;김영진
    • Journal of Sericultural and Entomological Science
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    • v.13 no.1
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    • pp.69-72
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    • 1971
  • 1. To study proper sample size in boiling-of test, we extracted samples in size of 200, 100, 50, 20, and 10 grams and tested them. In the result of this test we couldn't find a statistical significance among them, but it is seemed that the proper sample size is 100 gram to think about the errors of measurement and treatment when the sample size is either too little or too much in ordinary test. 2. We tested boil-of result by twisted sample skein (sizing skein) and untwisted sample. In this test to use sodium carbonate (Na$_2$CO$_3$) having powerful sericin dissolving power as a scouring agent, boil-off percents made no statistical significance between two kinds of sample skein. And to use marseilles soap having less powerful sericin dissolving power as a scouring agent, boil-off percents made a difference between twisted and untwisted sample skein. 3. We compared five kinds of scouring agent, for example sodium carbonate, monogen, synthetic detergent (HiTi), marseilles soap A (made in Japan) and marseilles soap B (made in Korea). Among them synthetic detergent and marseilles soap B showed no statistical significance compared with marseilles soap A which we used in ordinary boil-off test. So synthetic detergent and marseilles soap B can be substituted for marseilles soap A. 4. Generally the higher pH value of boil of solution, tile more sericin dissolution, showed and vice versa.

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Shot Boundary Detection Algorithm using Multi-Pass Mechanism (Multi-Pass 구조를 가지는 Shot 경계 검출기법)

  • Seong Changwoo;Kang Dae-Seong
    • Journal of the Institute of Convergence Signal Processing
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    • v.1 no.1
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    • pp.58-63
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    • 2000
  • This paper describes an efficient algorithm for shot boundary detection in MPEG video stream. There are two types of shot boundary: abrupt and gradual. The proposed algorithm for detecting the abrupt shot boundaries used DCT DC value in compressed domain. The proposed algorithm of the gradual change detection consists of two-pass mechanism. In the first pass, the expected positions of shot boundaries are extracted using ratio value of motion vectors. After decoding frames that are extracted in the first pass, we will make the dissolving image using (n)th and (n+2)th image of expected position. The gradual shot boundaries are selected by similarity of the dissolving image and the image of (n+1)th expected position. As applying the algorithm for detecting shot boundaries, the gradual changes as well as the abrupt changes are detected efficiently. Experimental results indicate that the proposed method is computationally fast for detecting shot boundaries and robust to the variation of the video characteristic that is different for the kind of videos.

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The Effect of Mobile Phase and Dissolving Solvent on the Enantiomer Separation Using a Covalently Immobilized Chiral Column Derived from Polysaccharide Derivative (다당유도체로 공유결합된 카이랄 칼럼에서 이동상과 분석물질의 용매가 거울상 이성질체의 광학분할에 미치는 영향)

  • Huang, Hu;Lee, Beom-Gyu;Baek, Chae-Sun;Lee, Won-Jae
    • Journal of the Korean Chemical Society
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    • v.53 no.2
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    • pp.137-143
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    • 2009
  • Liquid chromatographic enantiomer separation of N-tert-butoxycarbonyl (BOC) $\alpha$-amino acids and their ethyl esters was performed on covalently immobilized chiral column (Chiralpak IC) derived from polysaccharide derivative. The solvent versatility of the covalently immobilized Chiralpak IC in enantiomer separation of N-BOC $\alpha$-amino acid ethyl ester derivatives was shown and the chromatographic parameters of their enantioselectivities and resolution factors were greatly influenced by the nature of the mobile phase. Also the effect on the dissolving solvent for these analytes on the enantiomer separation using the same mobile phase and the examples of preparative enantiomer separation on analytical column were shown.

Stability of Immunoglobulin G(IgG) by Heat Treatment (면역단백질 G(IgG)의 열처리에 대한 안정성)

  • 박종대;손동화;정관섭
    • Food Science and Preservation
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    • v.10 no.2
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    • pp.236-240
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    • 2003
  • This study was carried out to obtain fundamental data when developing new colostrum component fortified milk products. Residual immunoglobulin G (IgG) activities of both IgG fortified milk products under different pasteurization conditions and colostrum fortified milk powder products under different dissolving temperatures were measured. In the study, residual IgG activities of raw milk and IgG (50 mg and 250 mg) fortified milk products were sharply reduced upon increasing the temperature of heat treatment. After the low temperature long time (LTLT) treatment residual IgG activities of raw milk, IgG 50 mg and 250 mg fortified milk products decreased to 79%, 30% and 21.6%, as compared to those before heat treatment respectively. However, almost no residual IgG activities were detected when IgG fortified milk was heated at 95$^{\circ}C$ for 15 sec. There was no significant change in the residual IgG activities of IgG fortified milk powder products upon different dissolving temperatures (30$^{\circ}C$, 40$^{\circ}C$, 50$^{\circ}C$ and 60$^{\circ}C$).

Effects of Electrodeposition Conditions on Properties of Ni Thin Films Electrodeposited from Baths Fabricated by Dissolving Metal Ni Powders (금속 Ni 분말을 용해한 도금용액으로부터 전기도금 된 Ni 박막 특성에 미치는 도금조건의 영향)

  • Yoon, Pilgeun;Park, Keun-Yong;Uhm, Young Rang;Choi, Sun Ju;Park, Deok-Yong
    • Journal of the Korean institute of surface engineering
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    • v.48 no.3
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    • pp.73-81
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    • 2015
  • Chloride plating solution was fabricated by dissolving metal Ni powders in solution with HCl and deionized water. Effects of deposition conditions on the properties of Ni films electrodeposited from chloride baths were studied. Current efficiency of Ni films electrodeposited from the baths containing saccharin was decreased with increasing the current density. Residual stress of Ni thin films ware measured to be about 230 ~ 435 MPa in the range of current density of $10{\sim}25mA/cm^2$. Cathode current efficiency in baths without saccharin was initially increased with increasing pH, while it was decreased with increasing pH further. Cathode current efficiency in baths with saccharin (except at pH 2) exhibited less 10 ~ 20% than that in baths without saccharin. Residual stress of Ni films electrodeposited from baths without saccharin was measured to be 388 ~ 473 MPa in the range of pH 2 ~ pH 5 and then was increased to 551 MPa at pH 6. On the other hand, residual stress of Ni films electrodeposited from baths with saccharin was increased with increasing pH. Surface morphology was strongly affected by the change of current density, but slightly by solution pH and addition of saccharin.

Abatement of Metal Ion Contents from Cotton Linter for the Manufacture of Regenerated Cellulose (방직용 재생섬유 제조를 위한 면 린터의 금속이온 함량 저감에 관한 연구)

  • Park, Hee Jeong;Son, Ha Neul;Choi, Jin Sung;Seo, Yung Bum
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.17-23
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    • 2013
  • The reduction of metal ion from the cotton linter for the preparation of NMMO (N-methylmorpholine N-oxide)-based dissolving pulp was investigated. The NMMO-based dissolving pulp was usually used for the manufacture of high quality fabrics, and need to have high alpha cellulose content and high brightness. NMMO, which is environmentally friendly, and reusable after recovering process, is very sensitive to the metal ions such as Cu, Fe, Mg, and Cr. Electron beam, sulfuric acid, acetic acid, and ozone treatment before bleaching were used and the concentration changes of the metal ions were compared to that of EDTA, a chelating agent. It was found that both acid treatments (sulfuric and acetic acid) were very effective and comparable to EDTA treatment at the same dosage in metal ion reduction, but electron beam and ozone treatment were not. The sulfuric acid treatment turned out to be effective in metal ion reduction, and most inexpensive.

Study on Analyzing differences between Rural and Urban regions in operating Digital Multi-media Center at Public Libraries for Dissolving Digital Divide (정보격차 해소를 위한 공공도서관 디지털자료실의 지역간 차이분석에 관한 연구)

  • Kim, Keun-Hyung;Kim, Bong-Soeg;Lee, Dong-Cheol
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.11 no.9
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    • pp.1619-1625
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    • 2007
  • Many various digital contents came out to our world owing to the advance of information and communication technologies. More rapidly the technologies of information and communication develop, more classes disadvantaged might appear so that it might incur society with distinction in getting information which is called digital divide. In this time, public library has to play important rules in dissolving the digital divide of our society. In this paper, we will not investigate only how much users of digital multimedia centers in the public library satisfy, but also what factors affect the satisfaction of the users significantly. Specially, we will analyze difference of the influence factors between urban and rural region so that we will propose strategy for operating the digital multimedia centers in the public library efficiently and effectively in order to dissolve the digital divide.

Fermentation and Purification of LacZ-Fused Single Chain Insulin Precursor for($B^{30}$-Homoserine) Human Insulin

  • SeungYup Lee;Jeo
    • Biotechnology and Bioprocess Engineering:BBE
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    • v.1 no.1
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    • pp.9-12
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    • 1996
  • In order to produce the single chain precursor of a novel human insulin analogue, (B30-Homoserine) insulin, the fermentative behaviors of Escherichia coli JM103 were studied, which harbors pKBA plasmid carrying a hybrid gene in which the gene for a single chain precursor was fused with lacZ gene under tac promoter. The maximal induction of gene expression was achieved when more than 0.05 mM of isopropyl-$\beta$-D-thiogalactopyranoside(IPTG) was supplemented to fermentation medium after 4 h cultivation of E. coli, and followed by longer than 2-h fermentation. The hybrid protein of the single chain insulin precursor was isolated from cytoplasmic inclusion bodies by dissolving in 8M urea solution, and purified through DEAE-Sephacel and Sephadex G-200 column chromatographies with a recovery of 35%. The finally purified hybrid protein showed a single band on sodium dodecyl sulfate-polyacrylamide gel.

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Study on the Dissolution Behavior of Liquide $CO_2$ Hydrate Injected at the Intermediate Depth of the Ocean (중층심해에 분사된 액체 이산화탄소 하이드레이트 용해에 대한 연구)

  • Kim, Nam-Jin;Park, Sung-Seek;Seo, Hyan-Min
    • New & Renewable Energy
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    • v.4 no.2
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    • pp.12-20
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    • 2008
  • Calculations for the dissolution behavior of liquid CO2 droplets released in the East Sea and the Clipperton Clarion from a moving ship and a fixed pipeline have been carried out in order to estimate the CO2 dissolution characteristics in the ocean. The results show that the injection of liquid CO2 from a moving ship in a high temperature point is an effective method for dissolution. Also, it is noted that the ultimate plume generated from CO2 bubbles repeatsand shrinking due to the peeling from a fixed pipeline, and the presence of hydrate layer on a liquid CO2 droplet acts as a resistant layer in dissolving liquid CO2.

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