• Polymer(Korea)
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• v.32 no.5
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• pp.421-426
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• 2008

pH-responsive P(MAA-co-EGMA) hydrogel microparticles were synthesized via dispersion photo polymerization and the feasibility of the particles as the cosmetic formulation was investigated. Rh-B and the functional materials for the cosmetic application such as ascorbic acid, adenosine, EGCG, and arbutin were loaded in the P (MAA-co-EGMA) hydrogel microparticles in order to examine the interaction between the hydrogel and the loaded materials. In the loading experiments, Rh-B showed the highest loading efficiency to the P(MAA-co-EGMA) hydrogels due to the electrostatic attraction between the negative charge of the hydrogels and the positive charge of Rh-B at the ionized states. However, the functional materials showed relatively low loading efficiencies because of the electrostatic repulsions between the negative charges of both the hydrogels and the materials at the ionized states. In addition, P(MAA-co-EGMA) hydrogel microparticles showed pH-responsive release behavior of Rh-B according to the external pH changes.

• Korean Journal of Materials Research
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• v.31 no.11
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• pp.593-600
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• 2021

Herein, a series of g-C₃N₄ modified Bi₂MoO₆ nanocomposites using Bi₂MoO₆ and melamine as original materials are fabricated via sintering process. For presynthesis of Bi₂MoO₆ an ultrasonic-assisted hydrothermal technique is researched. The structure and composition of the nanocomposites are characterized by Raman spectroscopy, X-ray diffraction (XRD), and high-resolution field emission scanning electron microscopy (SEM). The improved photoelectrochemical properties are studied by photocurrent density, EIS, and amperometric i-t curve analysis. It is found that the structure of Bi₂MoO₆ nanoparticles remains intact, with good dispersion status. The as-prepared g-C₃N₄/Bi₂MoO₆ nanocomposites (BMC 5-9) are selected and investigated by SEM analysis, which inhibits special morphology consisting of Bi₂MoO₆ nanoparticles and some g-C₃N₄ nanosheets. The introduction of small sized g-C₃N₄ nanosheets in sample BMC 9 is effective to improve the charge separation and transfer efficiency, resulting in enhancing of the photoelectric behavior of Bi₂MoO₆. The improved photoelectronic behavior of g-C₃N₄/Bi₂MoO₆ may be attributed to enhanced charge separation efficiency, photocurrent stability, and fast electron transport pathways for some energy applications.

• Journal of Institute of Control, Robotics and Systems
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• v.11 no.9
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• pp.810-815
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• 2005

As the pharmaceutical industry grows and becomes more competitive, the need of automation increases to establish effective mass production and to maintain consistent quality control. Accurate counting and packing of medicinal pills is one of the most essential processes that the automation can benefit. In conventional automated counting and packing processes, the performance of counting process varies with the size, the shape and the dispersion degree of pills. In this research, the authors developed a new pill-counting algorithm based on carefully analyzed characteristics of the pill-drop behavior. Also a new scheme for the packing of an exact number of pills has been implemented. A pill counting and packing machine with the new pill-counting algorithm and the new packing scheme has been constructed and put in an actual production line. To achieve precise and quick sensing of pills dropping at a high speed from the preceding processors, the machine uses non-contact photo sensors. Experimental results from the actual process using the machine are included to verify the effectiveness of the proposed algorithm and the machine.

• Steel and Composite Structures
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• v.35 no.5
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• pp.659-670
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• 2020

This paper proposes the use of a porous core between layers of laminated composite plates to examine its effect on the natural frequencies of the resulted porous laminated composite sandwich plate (PLCSP) resting on a two-parameter elastic foundation. Moreover, it has been suggested that the dispersion of porosity has two different functionally graded (FG) patterns which are compared with a uniformly dispersed (UD) profile to find their best vibrational efficiency in the proposed PLCSPs. In FG patterns, two types of dispersions, including symmetric (FG-S) and asymmetric (FG-A) patterns have been considered. To derive the governing Eigen value equation of such structures, the first order shear deformation theory (FSDT) of plates has been employed. Accordingly, a finite element method (FEM) is developed to solve the derived Eigen value equation. Using the mentioned theory and method, the effects of porosity parameters, fiber orientation of laminated composite, geometrical dimensions, boundary conditions and elastic foundation on the natural frequencies of the proposed PLCSPs have been studied. It is observed that embedding porosity in core layer leads to a significant improvement in the natural frequencies of PLCSPs. Moreover, the natural frequencies of PLCSPs with FG porous core are higher than those with UD porous core.

• Journal of Powder Materials
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• v.25 no.3
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• pp.232-239
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• 2018

In this paper, the recovery and nanoparticle synthesis of Ag from low temperature co-fired ceramic (LTCC) by-products are studied. The effect of reaction behavior on Ag leaching conditions from the LTCC by-products is confirmed. The optimum leaching conditions are determined to be: 5 M $HNO_3$, a reaction temperature of $75^{\circ}C$, and a pulp density of 50 g/L at 60 min. For the selective recovery of Ag, the [Cl]/[Ag] equivalence ratio experiment is performed using added HCl; most of the Ag (more than 99%) is recovered. The XRD and MP-AES results confirm that the powder is AgCl and that impurities are at less than 1%. Ag nanoparticles are synthesized using a chemical reduction process for recycling, $NaBH_4$ and PVP are used as reducing agents and dispersion stabilizers. UV-vis and FE-SEM results show that AgCl powder is precipitated and that Ag nanoparticles are synthesized. Ag nanoparticles of 100% Ag are obtained under the chemical reaction conditions.

• Elastomers and Composites
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• v.52 no.4
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• pp.257-265
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• 2017

In this work, CR (Chloroprene Rubber) was emulsified by phase-inversion emulsification with nonionic surfactants (NP-1025, LE-1017, and OP-1019) and an anionic surfactant (SDBS; sodium dodecylbenzenesulfonate), and its stabilization was investigated through a study of its adsorption characteristics, zeta potential, and flow behavior. As the amount of the mixed surfactant increased, the droplet size decreased, resulting in the increase of viscosity. In particular, a CR emulsion with a lower absorbance in the UV spectrum exhibited the highest zeta potential. The results of this experiment showed that the CR emulsion prepared using (LE-1017) and SDBS was the most stable. In this study, calcium hydroxide and aluminum hydroxide were added to enhance the mechanical properties of the CR emulsion, and the relationship between tensile strength, tear strength and surface free energy were investigated. The tensile and tear strengths of the CR emulsion incresed as the amount of calcium hydroxide and aluminum hydroxide increased. The highest tensile and tear strengths and surface free energy were observed for additions of 1.0% calcium hydroxide and 0.80% aluminum hydroxide, respectively. It was concluded that the interfacial bonding strength was improved by the even dispersion of calcium hydroxide and aluminum hydroxide in the CR emulsion.

• Journal of Korean Society for Atmospheric Environment
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• v.19 no.4
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• pp.397-414
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• 2003

The performance of one-particle stochastic Lagrangian models for passive tracer dispersion are evaluated against measurements in horizontally-homogeneous neutrally-stratified atmospheric surface layer. State-of-the-technology models as well as classical Langevin models, all in class of well mixed models are numerically implemented for inter-model comparison study. Model results (far-downstream asymptotic behavior and vertical profiles of the time averaged concentrations, concentration fluxes, and concentration fluctuations) are compared with the reported measurements. The results are: 1) the far-downstream asymptotic trends of all models except Reynolds model agree well with Garger and Zhukov's measurements. 2) profiles of the average concentrations and vertical concentration fluxes by all models except Reynolds model show good agreement with Raupach and Legg's experimental data. Reynolds model produces horizontal concentration flux profiles most close to measurements, yet all other models fail severely. 3) With temporally correlated emissions, one-particle models seems to simulate fairly the concentration fluctuations induced by plume meandering, when the statistical random noises are removed from the calculated concentration fluctuations. Analytical expression for the statistical random noise of one-particle model is presented. This study finds no indication that recent models of most delicate theoretical background are superior to the simple Langevin model in accuracy and numerical performance at well.

• KSBB Journal
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• v.23 no.3
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• pp.239-244
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• 2008

For physiological function of aloe concentrate by ultrafiltration (UF) process, jack bean urease inhibitory activity and bentonite flocculating activity of UF aloe concentrate was investigated and compared with fresh aloe gel. Urease inhibitory activity of UF aloe concentrate ranged from 87 to 90% in 1 mL sample. Also, urease inhibitory activity of UF aloe concentrate increased about 10% by heat treatment showing the heat stability. From Lineweaver-Burk plot for UF aloe concentrate, urease inhibition pattern indicated general non-competitive inhibition. From flocculation test of UF aloe concentrate about 1% (w/v) bentonite suspension, maximum flocclulating activity of 97% was obtained at 0.5 mL addition of UF aloe concentrate/ 5 ml bentonite suspension. However, flocculating activity of 81% was obtained at 1 mL addition of UF aloe concentrate/ 5 mL bentonite suspension, which was typical flocculating behavior of polymers with re-dispersion at overdose area. FT-IR spectra of UF aloe concentrate showed the characteristic patterns of $\beta$-binding polysaccharide and less deacetylation indicating higher level of bioactive polysaccharide content.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.21 no.4
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• pp.619-624
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• 2012

In this study, MMT/fiber/polymer composites were fabricated by impregnating chopped strand glass mat into a vinylester resin mixed with clay. Tensile tests has been performed by using a universal testing machine to determine the effect of MMT addition on the tensile properties of MMT/chopped strand glass fiber/vinylester composites. And some pictures which are magnified cross section of breaking parts are has been taken by using a FE-SEM to confirm the behavior at breaking. The contents ratio of MMT applied in the composites were 0.5, 1.0, 1.5, and 2.0 wt% respectively. It has been found that the tensile strength and elastic modulus of MMT/chopped strand glass fiber/vinylester composites were improved at a proper content of MMT. Tensile strength and elastic modulus were maximized at a content of 1.0 wt% due to most effective dispersion of MMT. On the contrary, the failure strain was increased as MMT content was increased.

• Journal of Soil and Groundwater Environment
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• v.6 no.2
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• pp.57-67
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• 2001

The purpose of this study is to predict appropriate leachate rates and leachate transport velocity through weathered zone and basement rock on the transient condition at Nanji waste landfill. The leachate transport in the Nanji waste landfill is analyzed using MODFLOW(A Modular 3-D Finite Different Groundwater Flow Model) model which simulates three dimension groundwater flow and MT3D(A Modular Three Dimentional Transport Model) model which describes three dimensional transport for advection, dispersion and chemical reaction of dissolved constituents in groundwater system on the transient condition. Leachate production rates are estimated by HELP(Hydraulical Evaluation of Landfill Performance) model and used weather records for recent 10 years. Leachate transport is predicted by a change of leachate level to after/before established HDPE, established slurry wall and wells.