• Title/Summary/Keyword: direct synthesis

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Synthesis of Ultra-long Hollow Chalcogenide Nanofibers

  • Jwa, Yong-Ho
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.10a
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    • pp.3.1-3.1
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    • 2011
  • Nanoengineered materials with advanced architectures are critical building blocks to modulate conventional material properties or amplify interface behavior for enhanced device performance. While several techniques exist for creating one dimensional heterostructures, electrospinning has emerged as a versatile, scalable, and cost-effective method to synthesize ultra-long nanofibers with controlled diameter (a few nanometres to several micrometres) and composition. In addition, different morphologies (e.g., nano-webs, beaded or smooth cylindrical fibers, and nanoribbons) and structures (e.g., core-.shell, hollow, branched, helical and porous structures) can be readily obtained by controlling different processing parameters. Although various nanofibers including polymers, carbon, ceramics and metals have been synthesized using direct electrospinning or through post-spinning processes, limited works were reported on the compound semiconducting nanofibers because of incompatibility of precursors. In this work, we combined electrospinning and galvanic displacement reaction to demonstrate cost-effective high throughput fabrication of ultra-long hollow semiconducting chalcogen and chalcogenide nanofibers. This procedure exploits electrospinning to fabricate ultra-long sacrificial nanofibers with controlled dimensions, morphology, and crystal structures, providing a large material database to tune electrode potentials, thereby imparting control over the composition and shape of the nanostructures that evolved during galvanic displacement reaction.

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Effects of Electric Current on Flowering in Pharbitis and Floral Stimulus activity in the Phloem Exudate of Cotyledons

  • Jueson Maeng
    • Journal of Plant Biology
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    • v.37 no.2
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    • pp.159-166
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    • 1994
  • Direct current (DC) applied to cotyledons during a 16 h inductive dark period inhibited the flowering in the short-day plant, Pharbitis nil Choisy cv. Violet. The inhibitory effect of DC was more profound when the current flowed from roots to cotyledons, showing its polarity-dependent action. The second half on the inductive dark period was more sensitive to DC stimulus. The flowering was significantly depressed only when DC stimuli were applied to the translocation path of the floral stimulus from the induced cotyledon to the apex, suggesting that the transport of floral stimulus was damaged by the DC treatment. The vegetative apex culture bioassay system showed that a significant level of the floral stimulus activity existed in the phloem exudate from the cotyledons which would fail to form their own floral buds. These results strongly support the hypothesis that DC partially impede, at least temporarily, the transmission path of the floral stimulus from florally-induced cotyledon to the apex, rather than depressing in situ synthesis of the floral stimulus.

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A Study on Implementation of 6 Channel DSB Modulator using DDS (DDS(Direct Digital Synthesis)를 이용한 6채널DSB(Double-SideBand) 변조기 구현에 관한 연구)

  • 하재승
    • Journal of the Korea Computer Industry Society
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    • v.2 no.8
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    • pp.1063-1068
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    • 2001
  • In this paper, we designed a high resolution six channel DSB modulator of Acousto-Optic effect generator make use of DDS technology. Also, configured seamless connection for other instruments to use IEEE-488 bus interface. We programmed the device driver for DDS and DAC control by 80C51 assembler language. And, high resolution 6 channel DSB modulator has improved the important characteristics of that the frequency tuning range, the resolution, the switching time. This DSB modulator system can use high precision frequency synthesizer for instruments.

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Internet Virtual Reality-based Remote Control and Monitoring System and Implementation of Integrated Development Environment (인터넷 가상 현실 기반 원격 제어 및 감시 시스템과 통합 개발 환경의 구현)

  • Im, Hyeon-U;Kim, Yeong-Mo
    • The Transactions of the Korea Information Processing Society
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    • v.6 no.11S
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    • pp.3243-3250
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    • 1999
  • There are many problems to be satisfied the various commercial demand in the present VRML node, and the VRML-based system by the contact with other technology is burdened with the direct participation of developer related with it. In this study, remote control and monitoring system using EAI(External Authoring Interface) is reposed to overcome the limit of VRML. In other words, This study is about mechanism of interaction between control and monitoring subject in real world and object in virtual world mapped with it. Object oriented method by one to one mapping of the Java class which have VRML virtual world and the object control is proposed. Introduction method of video monitoring through method of image synthesis and the integrated development environment is described. Finally automobile-gate control system based on the development method of Internet virtual reality-based system which is proposed in this study is described.

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Frequency Response Based Multi-Objective Design Toolbox for PID Controller (PID 제어기의 주파수응답 기반 다목적 설계도구)

  • Jin, Lihua;Lim, Yeon-Soo;Kim, Young-Chol
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.10
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    • pp.1869-1875
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    • 2008
  • Recently, a direct data-driven synthesis of a proportional integral derivative(PID) controller for a linear time-invariant(LTI) plant was presented in [1]. The authors showed that a complete set of PID controllers achieving robust performance and stability can be calculated directly from frequency response(FR) data without an identified transfer function model. However, it is not convenient to use this method because it requires complicated numerical algorithms to find specific frequencies which are solutions of an identical equation. The method also requires determination of the boundary of the controller's parameters from a finite set of FR data. In this paper, we present the development of a user-friendly Matlab toolbox based on the method in [1]. This toolbox allows us to obtain a complete three-dimensional(3-D) graphical solution of PID controllers that meet multiple design objectives. Several examples are given to demonstrate the use of the toolbox.

Synthesis of Pd Dendritic Nanowires for Methanol Electrooxidation (전기도금을 이용한 팔라듐 나노와이어 합성 및 전기화학 촉매 특성 연구)

  • Song, You-Jung;Han, Sang-Beom;Lee, Jong-Min;Park, Kyung-Won
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.395-398
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    • 2009
  • 전기도금 방법을 사용해 각기 다른 환원 전압과 전기도금시간에서 Pd 수지상 나노와이어(Pd DNWs) 전극이 합성 되었으며 그 성장 기작을 논의하였다. 전기화학적인 도금 공정 동안 Pd DNWs 이<111>방향으로 성장하는 것을 확인할 수 있었는데, 이것은 전해질 속의 황산음이온들이 Pd 의 (111)면에 흡착하기 유리하기 때문이라고 사료된다. 가해준 환원전압이 증가함에 따라, 단 결정 수지상의 나노와이어의 가지는 길어지고 얇아지는 경향을 보였다. 이것은 전기도금 시간이 아니라 환원전압에 의해서만 나노와이어 가지의 직경이 조절됨을 보여준다

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Studies on the Polymeric Surfactants (III);Synthesis of Sodium ${\alpha}-Sulfo$ Fatty Acid Allyl Ester Oligomers (고분자(高分子) 계면활성제(界面活性劑)에 관한 연구(硏究) (제(第) 3 보(報));알릴에스테르 ${\alpha}$-술폰 지방산(脂肪酸) 고분자(高分子) 화합물(化合物)의 합성(合成))

  • Nam, Ki-Dae;Jeong, No-Hee;No, Sueng-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.6 no.2
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    • pp.45-51
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    • 1989
  • Allyl aliphatic carboxylates were synthesized by azotropic reaction with benzene between allyl alcohol and capric acid, lauric acid, myristic acid, palmitic acid or stearic acid respectively. allyl aliphatic carboxylates oligomers were prepared from polymerization giving allyl aliphatic carvboxylates in the presence of potassium persulfate in methanol, and the ${\alpha}-sulfonation$ of these five allyl aliphatic carboxylates oligomers were carried by direct addition of dry sulfur trioxide. Especially, molecular weights of fatty acid alylester oligomers and their sodium salts of ${\alpha}-sulfo$ fatty acid allylester oligomers were measured by boiling point method.

A Direct Synthesis System for Speed-independent Circuits (속도 독립 회로를 위한 직접 합성 시스템)

  • Kim, Hui-Suk;Jeong, Seong-Tae;Park, Hui-Sun
    • Journal of KIISE:Computer Systems and Theory
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    • v.28 no.1_2
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    • pp.110-123
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    • 2001
  • 본 논문에서는 자유 선택 신호 전이 그래프와 비동기 유한 상태기로 기술된 회로 명세로부터 직접 속도 독립 회로를 합성하는 시스템에 대해 기술한다. 기존의 상태 그래프 기반의 합성 시스템은 상태의 수가 지수승으로 증가할 수 있기 때문에 큰 규모의 회로에 대해서는 합성에 실패할 수 있다는 문제점을 가지고 있다. 이를 해결하기 위해 여러 직접 합성 방법들이 제안되었는데, 본 논문의 합성 시스템은 마크드 그래프 분할 방법과 임시 전이의 사용을 허용함으로써 합성할 수 있는 회로의 범위를 넓혔다. 기존의 벤치마크 회로에 대한 실험결과 본 합성 시스템은 기존의 상태 그래프 기반의 합성 시스템에 비하여 현저하게 수행 속도를 단축시킬 수 있었고 기존의 직접 합성 시스템에 비하여 보다 확장된 그리고 보다 실용적인 회로 명세를 처리할 수 있었다.

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Design of the Digital Frequency Synthesizer for High Speed Frequency Hopping by the DDS Method using CPLD (CPLD 소자를 사용한 DDS 방식의 고속 주파수 호핑용 디지털 주파수 합성기의 설계)

  • Kim Girae;Choi Youngkyu
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.9 no.2
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    • pp.402-407
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    • 2005
  • The PLL synthesizer is used in communication system until now because it have several merits, such as broad bandwidth, high accuracy and stability of frequency But it is difficult to use in the third generation mobile communication systems that need frequency hopping at a high speed because of its long frequency hopping time. In this paper, we designed the frequency synthesizer that generate frequencies randomly at a high speed using the DDS technology.