• Journal of the Korean institute of surface engineering
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• v.45 no.6
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• pp.248-256
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• 2012

A Pd-based hydrogen membranes for hydrogen purification and separation need high hydrogen perm-selectivity. The surface roughness of the support is important to coat the pinholes free and thin-film membrane over it. Also, The pinholes drastically decreased the hydrogen perm-selectivity of the Pd-based composite membrane. In order to remove the pinholes, we introduced various surface pre-treatment such as alumina powder packing, nickel electro-plating and micro-polishing pre-treatment. Especially, the micro-polishing pretreatment was very effective in roughness leveling off the surface of the porous nickel support, and it almost completely plugged the pores. Fine Ni particles filled surface pinholes with could form open structure at the interface of Pd alloy coating and Ni support by their diffusion to the membrane and resintering. In this study, a $4{\mu}m$ surface pore-free Pd-Cu-Ni ternary alloy membrane on a porous nickel substrate was successfully prepared by micro-polishing, high temperature sputtering and Cu-reflow process. And $H_2$ permeation and $N_2$ leak tests showed that the Pd-Cu-Ni ternary alloy hydrogen membrane achieved both high permeability of $13.2ml{\cdot}cm^{-2}{\cdot}min^{-1}{\cdot}atm^{-1}$ permation flux and infinite selectivity.

• Proceedings of the Korean Biophysical Society Conference
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• 2003.06a
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• pp.30-30
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• 2003

Without a definitive resolution of stoichiometry of cardiac Na$^{+}$-Ca$^{2+}$exchange (NCX), we cannot proceed to any quantitative analysis of exchange function as well as cardiac excitation-contraction coupling. The stoichiometry of cardiac NCX, however, is presently in doubt because reversal potentials determined by various groups range between those expected for a 3-to-1 and a 4-to-1 flux coupling. For a new perspective on this problem, we have used ion-selective microelectrodes to quantify directly exchanger-mediated fluxes of $Ca^{2+}$and Na$^{+}$in giant membrane patches. $Ca^{2+}$- and Na$^{+}$-selective microelectrodes, fabricated from quartz capillaries, are placed inside of the patch pipettes to detect extracellular ion transients associated with exchange activity. Ion changes are monitored at various distances from the membrane, and the absolute ion fluxes through NCX are determined via simulations of ion diffusion and compared with standard ion fluxes (Ca$^{2+}$ fluxes mediated by $Ca^{2+}$ ionophore, and Na$^{+}$ fluxes through gramicidin channels and Na$^{+}$/K$^{+}$pumps). Both guinea pig myocytes and NCX1-expressing BHK cells were employed, and for both systems the calculated stoichiometries for inward and outward exchange currents range between 3.2- and 3.4-to-1. The coupling ratios do not change significantly when currents are varied by changing cytoplasmic [Ca$^{2+}$] or by adding cytoplasmic Na$^{+}$. The exchanger reversal potentials, measured in both systems under several ionic conditions, range from 3.1- to 3.3-to-1. Taken together, a clear discrepancy from a NCX stoichiometry of 3-to-1 was obtained. Further definitive experiments are required to acquire a fixed number, and the present working hypothesis is that NCX current has an extra current via ‘conduction mode’.ent via ‘conduction mode’.

• Nuclear Engineering and Technology
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• v.35 no.4
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• pp.356-368
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• 2003

Material properties such as coolant specific heat, film heat transfer coefficient, cladding thermal conductivity, surface diffusion coefficient of the multi-bubble are improved in MACSIS-Mod1. The axial power and flux profile module was also incorporated with irradiation history. The performance and feasibility of the updated driver fuel pin have been analyzed for nominal parameters based on the conceptual design for the KALIMER breakeven core by MACSIS-MOD1 code. The fuel slug centerline temperature takes the maximum at 700mm from the bottom of the slug in spite of the nearly symmetric axial power distribution. The cladding mid-wall and coolant temperatures take the maximum at the top of the pin. Temperature of the fuel slug surface over the entire irradiation life is much lower than the fuel-clad eutectic reaction temperature. The fission gas release of the driver fuel pin at the end of life is predicted to be $68.61\%$ and plenum pressure is too low to cause cladding yielding. The probability that the fuel pin would fail is estimated to be much less than that allowed in the design criteria. The maximum radial deformation of the fuel pin is $1.93\%$, satisfying the preliminary design criterion ($3\%$) for fuel pin deformation. Therefore the conceptual design parameters of the driver fuel pin for the KALIMER breakeven core are expected to satisfy the preliminary criteria on temperature, fluence limit, deformation limit etc.

• Nuclear Engineering and Technology
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• v.50 no.3
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• pp.416-424
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• 2018

Microstructure of oxide formed on Zr-Nb-Sn tube sample was intensively examined by scanning transmission electron microscopy after exposure to simulated primary water chemistry conditions of various concentrations of Zn (0 or 30 ppb) and dissolved hydrogen ($H_2$) (30 or 50 cc/kg) for various durations without applying desirable heat flux. Microstructural analysis indicated that there was no noticeable change in the microstructure of the oxide corresponding to water chemistry changes within the test duration of 100 days (pretransition stage) and no significant difference in the overall thickness of the oxide layer. Equiaxed grains with nano-size pores along the grain boundaries and microcracks were dominant near the water/oxide interface, regardless of water chemistry conditions. As the metal/oxide interface was approached, the number of pores tended to decrease. However, there was no significant effect of $H_2$ concentration between 30 cc/kg and 50 cc/kg on the corrosion of the oxide after free immersion in water at $360^{\circ}C$. The adsorption of Zn on the cladding surface was observed by X-ray photoelectron spectroscopy and detected as ZnO on the outer oxide surface. From the perspective of $OH^-$ ion diffusion and porosity formation, the absence of noticeable effects was discussed further.

• Advances in materials Research
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• v.8 no.2
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• pp.117-135
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• 2019

The lifetime of a gas turbine combustor is typically limited by the durability of its liner, the structure that encloses the high-temperature combustion products. The primary objective of the combustor thermal design process is to ensure that the liner temperatures do not exceed a maximum value set by material limits. Liner temperatures exceeding these limits hasten the onset of cracking which increase the frequency of unscheduled engine removals and cause the maintenance and repair costs of the engine to increase. Hot gas temperature prediction can be considered a preliminary step for combustor liner temperature prediction which can make a suitable view of combustion chamber conditions. In this study, the temperature distribution of ceramic panels for a V94.2 gas turbine combustor subjected to realistic operation conditions is presented using three-dimensional finite difference method. A simplified model of alumina ceramic is used to obtain the temperature distribution. The external thermal loads consist of convection and radiation heat transfers are considered that these loads are applied to flat segmented panel on hot side and forced convection cooling on the other side. First the temperatures of hot and cold sides of ceramic are calculated. Then, the thermal boundary conditions of all other ceramic sides are estimated by the field observations. Finally, the temperature distributions of ceramic panels for a V94.2 gas turbine combustor are computed by MATLAB software. The results show that the gas emissivity for diffusion mode is more than premix therefore the radiation heat flux and temperature will be more. The results of this work are validated by ANSYS and ABAQUS softwares. It is showed that there is a good agreement between all results.

• Journal of the Korean Geotechnical Society
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• v.37 no.12
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• pp.25-31
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• 2021

Boundary conditions for thermal-hydraulic problems of soils play an essential role in the numerical accuracy. This study presents a boundary condition considering the thermo-hydraulic interaction between the ground and the atmosphere. Ground surface energy balance consists of solar radiation, ground radiation, wind convection, latent heat from water evaporation, and heat conduction to the ground. Equations for each heat flux are presented, and numerical analyses are performed in conjunction with the FEM program for the thermal-hydraulic phenomenon of unsaturated soils. Numerical results using the weather data at the Ulsan Meteorological Observatory are similar to the measured surface temperature. Latent heat caused by water evaporation during the daytime lowers the surface temperature of the bare soil, and a thermal equilibrium is reached at nighttime when the effect of the ground condition is significantly reduced. The temperature change of the surface ground is diminished at the deeper ground due to its thermal diffusion. Numerical analysis where the surface ground temperature is the primary concern requires considering the thermo-hydraulic interaction between the ground and the atmosphere.

• Journal of Electrochemical Science and Technology
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• v.13 no.2
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• pp.213-226
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• 2022

In the present study, the corrosion behavior of aluminum Al-7075 tempered (T-6 condition) alloy was evaluated by immersion testing and electrochemical testing in 1.75% and 3.5% NaCl environment at acidic, neutral and basic pH. The data obtained by both immersion tests and electrochemical corrosion tests (potentiodynamic polarization and electrochemical impedance spectroscopy tests) present that the corrosion rate of the alloy specimens is minimum for the pH=7 condition of the solution due to the formation of dense and well adherent thin protective oxide layer. Whereas the solutions with acidic and alkaline pH cause shift in the corrosion behavior of aluminum alloy to more active domains aggravated by the constant flux of acidic and alkaline ions (Cl^- and OH^-) in the media which anodically dissolve the Al matrix in comparison to precipitated intermetallic phases (cathodic in nature) formed due to T6 treatment. Consequently, the pitting behavior of the alloy, as observed by cyclic polarization tests, shifts to more active regions when pH of the solutions changes from neutral to alkaline environment due to localized dissolution of the matrix in alkaline environment that ingress by diffusion through the pores in the oxide film. Microscopic analysis also strengthens the results obtained by immersion corrosion testing and electrochemical corrosion testing as the study examines the corrosion behavior of this alloy under a systematic evaluation in marine environment.

• Journal of the Korean Society of Marine Environment & Safety
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• v.23 no.4
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• pp.347-353
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• 2017

In this study, numerical experiments were conducted to identify distribution of rising flow and flux in the East Sea of Korea, where the coastal upwelling occurs. Temperature and salinity data from CTD observations and NIFS during summer 2013 were applied to the model. Numerical experiments were carried out with different wind speed (3, 6 m/s and 9 m/s) and direction (southerly and southwesterly), which represent the most frequent in summer conditions. As a result of calculation, upwelling flow rate was found to be highest in Pohang between five coasts(Hupo, Youngduk, Pohang, Ulsan and Busan). Comparing with southerly wind conditions, the rising flow rate is about 1.5 times greater when southwesterly wind was applied. Horizontal diffusion of the upwelling area is expected to have a speed of 17~22 km/day when a 9 m/s southwesterly wind is applied. If this wind continues over one week, a cold pool will be generated by upwelling that may reach to the Ulleung area.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.7
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• pp.591-598
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• 2015

Pool boiling heat transfer coefficients of a LiBr solution were obtained for seven low fin tubes having different fin pitch and fin height. The test range covered saturation pressure from 7.38kPa to 101.3kPa, heat flux from $20kW/m^2$ to $40 kW/m^2$ and LiBr concentration from 0% to 50%. The optimum fin geometry for the present experimental range turned out to be 26 fpi with 0.18 mm fin height.The advantage of added heat transfer area and the disadvantage of slower bubble growth and departure appear to have yielded an optimum fin pitch. The heat transfer coefficient decreased as saturation pressure decreased and Libr concentration increased. The reason may be attributed to the low saturation pressure, which increased the bubble departure diameter and decreased the bubble departure frequency. As the LiBr concenreation increased, the saturation temperature increased and the mass diffusion rate decreased, which resulted in a reduced heat transfer coefficient. The heat transfer coefficients of the low fin tube were greater than those of the smooth tube. Correlations were developed based on the present data.

• Korean Journal of Ecology and Environment
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• v.34 no.4 s.96
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• pp.261-266
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• 2001

Effects of elevated carbon dioxide ($CO_2$) on soil microbial processes were studied in a northern peatland. Intact peat cores with surface vegetation were collected from a northern Welsh fen, and incubated either under elevated carbon dioxide (700 ppm) or ambient carbon dioxide (350 ppm) conditions for 4 months. Higher algal biomass was found under the elevated $CO_2$ condition, suggesting $CO_2$ fertilization effect on primary production, At the end of the incubation, trace gas production and consumption were analyzed using chemical inhibitors. For methane ($CH_4$ ), methyl fluoride ($CH_3F$) was applied to determine methane oxidation rates, while acetylene ($C_2H_2$) blocking method were applied to determine nitrification and denitrification rates. First, we have adopted those methods to optimize the reaction conditions for the wetland samples. Secondly, the methods were applied to the samples incubated under two levels of $CO_2$. The results exhibited that elevated carbon dioxide increased both methane production (210 vs. $100\;ng\;CH_4 g^{-1}\;hr^{-1}$) and oxidation (128 vs. $15\;ng\;CH_4 g^{-1}\;hr^{-1}$), resulting in no net increase in methane flux. For nitrous oxide ($N_2O$) , elevated carbon dioxide enhanced nitrous oxide emission probably from activation of nitrification process rather than denitrification rates. All of these changes seemed to be substantially influenced by higher oxygen diffusion from enhanced algal productivity under elevated $CO_2$.