• Title/Summary/Keyword: deposition rate

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Synthesis of Ag-Cu Composite Powders for Electronic Materials by Electroless Plating Method (무전해 도금법을 이용한 전자소재용 은-구리 복합분말의 제조)

  • Yoon, C.H.;Ahn, J.G.;Kim, D.J.;Sohn, J.S.;Park, J.S.;Ahn, Y.G.
    • Journal of Powder Materials
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    • v.15 no.3
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    • pp.221-226
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    • 2008
  • Silver coated copper composite powders were prepared by electroless plating method by controlling the activation and deposition process variables such as feeding rate of silver ions solution, concentration of reductant and molar ratio of activation solution $(NH_4OH/(NH_4)_2SO_4)$ at room temperature. The characteristics of the product were verified by using a scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic absorption (A.A.). It is noted that completely cleansing the copper oxide layers and protecting the copper particles surface from hydrolysis were important to obtain high quality Ag-Cu composite powders. The optimum conditions of Ag-Cu composite powder synthesis were $NH_4OH/(NH_4)_2SO_4$ molar ratio 4, concentration of reductant 15g/l and feeding rate of silver ions solution 2 ml/min.

Distribution of Marine Debris collected from the Sandbar Coastline of Nakdong River Estuary after the Typhoons' Passage (태풍 내습후 낙동강 하구 사주해안의 쓰레기 분포)

  • Park, Son;Yoon, Han-Sam
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.4
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    • pp.1-7
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    • 2007
  • Using field observations, this study estimated the total weight and types of marine debris along the coast of Jinu Island in the Nakdong River Estuary after typhoons Usagi and Nari had passed. A numerical wave model was used to calculate the spatial wave height distribution at the time of the typhoons' passage. This study found that the total accumulation rate of marine debris deposited on the coast after the two typhoons had passed was about $5,769.86\;kg/km^2/day$ at this site, which was 14.42 times as high as that in normal weather. The wave height distribution in the sea off Jinu Island, based on numerical modeling, was $4.1{\sim}3.5\;m$, which was 1.0-2.5 times greater than for the case of other islands. Therefore, it is likely that the concentration of wave energy led to the deposition of marine debris.

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A Luminescence Dating for a Relict Dune from the Sindu Dunefield (신두리 지역의 고사구(古砂丘)에 대한 OSL 연대 측정)

  • Seo, Jong-Cheol
    • Journal of the Korean association of regional geographers
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    • v.11 no.1
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    • pp.114-122
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    • 2005
  • To find out the buried age of the relict dune sediments, a luminescence dating bas conducted for a relict dune from the Sindu dunefield on the Taean Peninsula. It shows that the deposition of the dune sands at 3m depth began about 690$\sim$730 years ago. From 3m to l.5m depth, the lower part of the dune bas remained stable, but a relict dune deposit appear at 1.3m depth. This part yields an age of about 68 years. The two samples that were collected from the lower part of the dune at depths of the 1.5 m and 3.0 m below the surface show a net accumulation rate of around 0.75 cm/y which is relatively slow for a coastal dune. The chronology obtained in this study demonstrates that a significant amount of sediments has been replaced or remobilized in the area over the past 1000 years, and there was at least a soil formation process during the same time period. These suggest that a new approach is necessary to identify the formation age of the so-called paleo-dune at the Sind dunefield.

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EFFECT OF SILT AND SALINITY ON THE MORTALITY OF MERETRIX LUSORIA $(R\ddot{O}DING)$ (이질과 염분이 백합의 폐사에 미치는 영향)

  • CHANG Sun-duck;CHIN Pyung;SUNG Byung-oun
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.9 no.1
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    • pp.69-73
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    • 1976
  • Mortality of clam, Meretrix lusoria was measured during the experimental cultures in different sediments compositions and in different salinities of sea water. Experimental groups maintained in silt and clay showed significant mortality, while those treated in sand and in sand-silt showed little mortality. In the groups cultured in silt and clay, young groups of approximately 2.5cm in shell length were subjected to early and high mortality (approximately eighty-five per cent in foully-one days). The larger the shell size was, the later and the lower the mortality occurred. In different salinity, the groups maintained in silt and clay showed different mortalities. It is observed that the survival rate of the shell in the sea water of low salinity was higher than that in the high salinity water. Oxygen consumption of isolated gill tissue showed a little difference between the groups maintained in silt and clay and those in sand (the control-group). Consequently, it may be stated that the mortality results mainly from the deposition of silt and clay, although the survival rate of Meretrix lusoria depends also on water temperature, salinity, dissolved oxygen, body size ana other factors.

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Degradation of Chlorinated Phenols by Zero Valent Iron and Bimetals of Iron: A Review

  • Gunawardana, Buddhika;Singhal, Naresh;Swedlund, Peter
    • Environmental Engineering Research
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    • v.16 no.4
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    • pp.187-203
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    • 2011
  • Chlorophenols (CPs) are widely used industrial chemicals that have been identified as being toxic to both humans and the environment. Zero valent iron (ZVI) and iron based bimetallic systems have the potential to efficiently dechlorinate CPs. This paper reviews the research conducted in this area over the past decade, with emphasis on the processes and mechanisms for the removal of CPs, as well as the characterization and role of the iron oxides formed on the ZVI surface. The removal of dissolved CPs in iron-water systems occurs via dechlorination, sorption and co-precipitation. Although ZVI has been commonly used for the dechlorination of CPs, its long term reactivity is limited due to surface passivation over time. However, iron based bimetallic systems are an effective alternative for overcoming this limitation. Bimetallic systems prepared by physically mixing ZVI and the catalyst or through reductive deposition of a catalyst onto ZVI have been shown to display superior performance over unmodified ZVI. Nonetheless, the efficiency and rate of hydrodechlorination of CPs by bimetals depend on the type of metal combinations used, properties of the metals and characteristics of the target CP. The presence and formation of various iron oxides can affect the reactivities of ZVI and bimetals. Oxides, such as green rust and magnetite, facilitate the dechlorination of CPs by ZVI and bimetals, while oxide films, such as hematite, maghemite, lepidocrocite and goethite, passivate the iron surface and hinder the dechlorination reaction. Key environmental parameters, such as solution pH, presence of dissolved oxygen and dissolved co-contaminants, exert significant impacts on the rate and extent of CP dechlorination by ZVI and bimetals.

Application of Si3N4 Thin Film as a Humidity Protection Layer for Organic Light Emitting Diode (Si3N4 박막의 유기발광소자 수분침투 방지막으로의 응용)

  • Kim, Chang-Jo;Shin, Paik-Kyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.23 no.5
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    • pp.397-402
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    • 2010
  • In this paper, we studied WVTR(water vapor transmission rate) properties of $Si_3N_4$ thin film that was deposited using TCP-CVD (transformer coupled plasma chemical vapor deposition) method for the possibility of OLED(organic light emitting diode) encapsulation. Considering the conventional OLED processing temperature limit of below $80^{\circ}C$, the $Si_3N_4$ thin films were deposited at room temperature. The $Si_3N_4$ thin films were prepared with the process conditions: $SiH_4$ and $N_2$, as reactive gases; working pressure below 15 mTorr; RF power for TCP below 500 W. Through MOCON test for WVTR, we analyzed water vapor permeation per day. We obtained that WVTR property below 6~0.05 gm/$m^2$/day at process conditions. The best preparation condition for $Si_3N_4$ thin film to get the best WVTR property of 0.05 gm/$m^2$/day were $SiH_4:N_2$ gas flow rate of 10:200 sccm, working pressure of 10 mTorr, working distance of 70 mm, TCP power of 500 W and film thickness of 200 nm. respectively. The proposed results indicates that the $Si_3N_4$ thin film could replace metal or glass as encapsulation for flexible OLED.

Cathodic Electrochemical Deposition of Highly Ordered Mesoporous Manganese Oxide for Supercapacitor Electrodes via Surfactant Templating

  • Lim, Dongwook;Park, Taesoon;Choi, Yeji;Oh, Euntaek;Shim, Snag Eun;Baeck, Sung-Hyeon
    • Journal of Electrochemical Science and Technology
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    • v.11 no.2
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    • pp.148-154
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    • 2020
  • Highly ordered mesoporous manganese oxide films were electrodeposited onto indium tin oxide coated (ITO) glass using sodium dodecyl sulfate (SDS) and ethylene glycol (EG) which were used as a templating agent and stabilizer for the formation of micelle, respectively. The manganese oxide films synthesized with surfactant templating exhibited a highly mesoporous structure with a long-range order, which was confirmed by SAXRD and TEM analysis. The unique porous structure offers a more favorable diffusion pathway for electrolyte transportation and excellent ionic conductivity. Among the synthesized samples, Mn2O3-SDS+EG exhibited the best electrochemical performance for a supercapacitor in the wide range of scan rate, which was attributed to the well-developed mesoporous structure. The Mn2O3 prepared with SDS and EG displayed an outstanding capacitance of 72.04 F g-1, which outperform non-porous Mn2O3 (32.13 F g-1) at a scan rate of 10 mV s-1.

630 nm Light Emitting Diode Irradiation Improves Dermal Wound Healing in Rats

  • Lee, Jae-Hyoung;Jekal, Seung-Joo;Kwon, Pil-Seung
    • The Journal of Korean Physical Therapy
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    • v.27 no.3
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    • pp.140-146
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    • 2015
  • Purpose: To determine the effects of 630 nm light emitting diode (LED) on full-thickness wound healing. Methods: Twelve male Sprague-Dawley rats were randomly divided into LED (n=6) and control group (n=6). Two $19.63mm^2$ wounds were created on the mid dorsum. LED group received a 630 nm LED irradiation with $3.67mW/cm^2$ for 30 minutes ($6.60J/cm^2$) for 7 days, while control group received sham LED irradiation. Epithelial gap, collagen density, ${\alpha}$-SMA fibroblast and PCNA keratinocyte were measured on histochemical and immunohistochemical staining using image analysis system. An independent t-test was conducted to compare the difference between groups. Results: The wound closure rate, collagen density, ${\alpha}$-SMA fibroblast number, epithelial gap and PCNA keratinocyte number have shown no significant difference between LED and control group at day 3 after the treatment. At day 7 after the treatment, the wound closure rate in LED group was increased when compared with control group (p<0.05). The collagen density (p<0.05) and ${\alpha}$-SMA immunoreactive fibroblast number (p<0.001) were increased when compared with control group at day 7. The epithelial gap in LED group was significantly shorten than control group at day 7 (p<0.01). The PCNA positive cell number in LED group was higher than control group at day 7 (p<0.01). Conclusion: 630 nm LED with $3.67mW/cm^2$, $6.60J/cm^2$ accelerate collagen deposition by stimulating fibroblasts, and enhance wound contraction by differentiating myofibroblasts in the dermis, and accelerate keratinocyte proliferation by facilitating DNA synthesis in the epidermis. It may promote the healing process in proliferation stage of wound healing.

The Development and Application of Intelligent Welding Carriage with High Deposition Rate by 3-D Weaving (3차원 위빙 대용착 지능 용접캐리지 개발 및 적용)

  • Kim, Young-Zoo;Cho, Bang-Hyun;Amit, Amit;Lee, Sang-Bum;Lee, Weon-Gu;Kim, Jin-Yong;Huh, Man-Joo
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.65-65
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    • 2010
  • In shipbuilding industry, welding position are usually flat and vertical position at the erection stage. Application of SAW and EGW for these positions makes it possible to achieve enhanced productivity and high quality. But owing to their large size and weight it is difficult to apply these techniques in short and narrow regions. To overcome this problem, our company developed light weight and compact size 4-axis welding carriage which perform 3D weaving. The purpose of this study is to explain the development and application of intelligent welding carriage using 3D weaving pattern that can fill a large amount of welds and thereby making it possible to achieve high quality of welding. This study shows 3D weaving pattern, development of weaving database, and skill of adaptive control response for the variable gap. Also, it shows the results of procedure qualification test for the AH-grade steel when applied to the intelligent welding carriage.

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Inclusion of Ensiled Cassava KM94 Leaves in Diets for Growing Pigs in Vietnam Reduces Growth Rate but Increases Profitability

  • Ly, Nguyen T.H.;Ngoan, Le D.;Verstegen, Martin W.A.;Hendriks, Wouter H.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.8
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    • pp.1157-1163
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    • 2011
  • This study was conducted to determine the effect of the inclusion of different levels of ensiled cassava leaves (variety KM94) in the diets on performance and carcass characteristics of growing pigs in Vietnam. A total of 40 crossbreds pigs (Large White${\times}$Mong Cai, 20 males and 20 females) with an initial live weight of 23.5 kg (SD = 0.86) were randomly allocated to one of the four pens across 5 units. Four experimental diets were formulated for two growth periods, period 1 (60 days) for 20 to 50 kg and period 2 lasted 30 days, from 50 kg until slaughter. Four diets were formulated containing inclusion levels of ensiled cassava KM94 leaves diet of 0, 10, 15 and 20% in the DM. Diets were formulated based on previously determined ileal amino acid digestibility values of the KM94 products and were isonitrogenous and isocaloric on a metabolizable energy basis. Each pen of pigs was randomly assigned to one of the four dietary treatments. Dry matter intake and final weight tended to decreased with increasing levels of ensiled cassava KM94 leaves in the diet while there was a significant (p = 0.022) decrease in average daily gain. Protein depositions of the F1 pigs tended (p = 0.093) to decrease with increasing inclusion levels of ensiled cassava KM94 leaves. There was no significant difference in feed conversion ratio, carcass quality and fat gain between the groups of pigs. There were clear differences in feed costs among the experimental diets (p = 0.001) with increasing levels of ensiled cassava KM 94 leaves in the diet reducing feed costs. It was concluded that, in diets for growing pig, inclusion of ensiled cassava leaves reduces growth rate of pigs in Vietnam but increases profitability as measured by feed costs.