• Korean Journal of Materials Research
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• v.13 no.6
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• pp.398-403
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• 2003

Shallow $p^{＋}$ n junction was formed using a ULE(ultra low energy) implanter. Deactivation phenomena were investigated for the shallow source/drain junction based on measurements of post-annealing time and temperature following the rapid thermal annealing(RTA) treatments. We found that deactivation kinetics has two regimes such that the amount of deactivation increases exponentially with annealing temperature up to $850^{\circ}C$ and that it decreases linearly with the annealing temperature beyond that temperature. We believe that the first regime is kinetically limited while the second one is thermodynamically limited. We also observed "transient enhanced deactivation", an anomalous increase in sheet resistance during the early stage of annealing at temperatures higher than X$/^{\circ}C$. Activation energy for transient enhanced deactivation was measured to be 1.75-1.87 eV range, while that for normal deactivation was found to be between 3.49-3.69 eV.

• Biotechnology and Bioprocess Engineering:BBE
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• v.7 no.4
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• pp.225-230
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• 2002

Experiments on deactivation kinetics of immobilized lipase enzyme from Candida cyl-indracea were performed in stirred bath reactor using rice bran oil as the substrate and temperature as the deactivation parameter. The data were fitted In first order deactivation model. The effect of temperature on deactivation rate was represented by Arrhenius equation. Theoretical equations were developed based on pseudo-steady state approximation and Michaelis -Menten rate expression to predict the time course of conversion due to enzyme deactivation and apparent half-life of the immobilized enzyme activity in PFR and CSTH under constant feed rate polity for no diffusion limitation and diffusion limitation of first order. Stability of enzyme in these continuous reactors was predicted and factors affecting the stability were analyzed.

• Korean Chemical Engineering Research
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• v.57 no.2
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• pp.185-197
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• 2019

Deactivation of porous photocatalytic materials was studied using three types of microstructured particles: macroporous titania particles, titania microspheres, and porous silica microspheres containing CNTs and $TiO_2$ nanoparticles. All particles were synthesized by emulsion-assisted self-assembly using micron-sized droplets as micro-reactors. During repeated cycles of the photocatalytic decomposition reaction, the non-dimensionalized initial rate constants (a) were estimated as a function of UV irradiation time (t) from experimental kinetics data, and the results were plotted for a regression according to the exponentially decaying equation, $a=a_0\;{\exp}(-k_dt)$. The retardation constant ($k_d$) was then compared for macroporous titania microparticles with different pore diameters to examine the effect of pore size on photocatalytic deactivation. Nonporous or larger macropores resulted in smaller values of the deactivation constant, indicating that the adsorption of organic materials during the photocatalytic decomposition reaction hinders the generation of active radicals from the titania surface. A similar approach was adopted to evaluate the activation constant of porous silica particles containing CNT and $TiO_2$ nanoparticles to compare the deactivation during recycling of the photocatalyst. As the amount of CNTs increased, the deactivation constant decreased, indicating that the conductive CNTs enhanced the generation of active radicals in the aqueous medium during photocatalytic oxidation.

• Proceedings of the Korean Society for Applied Microbiology Conference
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• 1986.12a
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• pp.523.1-523
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• 1986

To extend the spectrum of enzyme utilization in the organic solvent system, C. rugosal lipase was selected as a model enzyme because its substrate is soluble to organic solvent. One of the serious disadvantages in this system was the deactivation of the lipase. The pattern of lipase deactivation was the biphasic model. The activation energies for the deactivation were 14.05${\times}$10$^4$ KJ/Kg mole in the first phase and 3.59 ${\times}$ 10$^4$ KJ/mole in the second phase. The several factors were studied for their influences on the pattern of deactivation. Iso-octane as organic solvent influenced more on the first phase than the second phase. Urea as the reagent affecting boty hydrophobic interaction and hydrogen bond of enzyme also influencea more on the first phase. And the optimum pH for the activity was not correlated to that of the stability.

• 한국신재생에너지학회:학술대회논문집
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• 2006.06a
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• pp.63-66
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• 2006

A long term deactivation study was carried out with commercial MEA provided by Hyundai Motor Co. The deactivation phenomena were observed only at high voltage region where there is no diffusion-limited reaction. A rapid deactivation was observed up to 40h owing to the sintering of Pt particles. This was followed a gradual increase in the activity up to 300 h, which is probably caused by improvement in the electrode properties in the presence of current during the reaction. After 300 h, monotonic decrease in the activity was observed owing to dissolution of Pt particles especially in the cathode. The presence oxygen is the cause of oxidation and dissolution of Pt. The dissolution rate can be somewhat retarded by generation of current, which reduces Pt ion back to Pt in the cathode.

• Journal of Korean Neurosurgical Society
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• v.54 no.6
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• pp.453-460
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• 2013

Objective : There is a rich literature confirming the default mode network found compatible with task-induced deactivation regions in normal subjects, but few investigations of alterations of the motor deactivation in patients with intracranial lesions. Therefore, we hypothesized that an intracranial lesion results in abnormal changes in a task-induced deactivation region compared with default mode network, and these changes are associated with specific attributes of allocated regions. Methods : Blood oxygenation level dependent (BOLD) functional magnetic resonance imaging (fMRI) during a motor task were obtained from 27 intracranial lesion patients (mean age, 57.3 years; range 15-78 years) who had various kinds of brain tumors. The BOLD fMRI data for each patient were evaluated to obtain activation or deactivation regions. The distinctive deactivation regions from intracranial lesion patients were evaluated by comparing to the literature reports. Results : There were additive deactivated regions according to intracranial lesions : fusiform gyrus in cavernous hemangioma; lateral occipital gyrus in meningioma; crus cerebri in hemangiopericytoma; globus pallidus, lateral occipital gyrus, caudate nucleus, fusiform gyrus, lingual gyrus, claustrum, substantia nigra, subthalamic nucleus in GBM; fusiform gyrus in metastatic brain tumors. Conclusion : There is increasing interest in human brain function using fMRI. The authors report the brain function migrations and changes that occur in patients with intracranial lesions.

• 한국전기화학회:학술대회논문집
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• 1998.10a
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• pp.67-67
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• 1998

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.1
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• pp.45-50
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• 2002

Use of a phenomenological model, developed far prediction of catalytic deactivation, is demonstrated in comparing harshness of different driving cycles that are currently used to rapidly age catalytic converters on engine test benches. The model shows that seemingly equivalent driving cycles cause the catalytic converters to reach significantly different levels of deactivation. The comparison of the model prediction with the limited vehicle data seems encouraging despite the simplicity of the model at the current stage of its infancy.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
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• 2003.10a
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• pp.242-247
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• 2003

An experimental study presents characteristics of combustion in a combustion chamber by port deactivation valve for economy and emissions standards. In order to use combustion properties data it is necessary to build some data base, which use cylinder pressure sensor, etc. Port deactivation valve has been developed to satisfy requirement of achieving sufficient swirl generation to improve the combustion. A feasibility and necessity of combustion pressure based cylinder spark timing control has been examined. So, this was obtained the Coefficient of Variation(COV) and the mass-burned(MFB). The characteristics of pressure ratio fraction is similar to that of mass-burned fraction. Using the results of the test, the effects of the combustion chamber can be improved combustion stability by port deactivation.

• Transactions of the Korean hydrogen and new energy society
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• v.31 no.1
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• pp.8-22
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• 2020

In this study, we investigated the deactivation characteristics of Ni-Zn-Fe electrodes due to intermittent operation in alkaline water electrolysis. To find suitable method to accelerate deactivation of electrode, the accelerated stress-test (AST) which repeated on/off step was performed with constant current/voltage control. The AST under constant voltage control is suitable to deactivate electrode so it were selected to investigate deactivation of electrode. The AST which repeated on/off step in range of -1.3 V and 0 V was performed and the relationship between oxidation current and electrode deactivation in the off step was investigate. As results, it was confirmed that the nickel and zinc on electrode surface were oxidized due to anodic current which occurred at off step.