• Journal of the Korean Electrochemical Society
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• v.9 no.3
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• pp.113-117
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• 2006

The electrochemical properties of the redox mediator, 2,2'-azinobis (3-ethylbenzothiazoline-6-sulfonate) ($ABTS^{2-}$) were studied using cyclic voltammetry. The measured potentials (${E^o}'$ vs SCE) of the two redox couples of ABTS are 0.45 V for $ABTS^{2-}/ABTS^{\cdot-}$ and 0.87 V for $ABTS^{\cdot-}/ABTS^0$. The rate constant for heterogeneous electron transfer and the diffusion coefficients for $ABTS^{2-}$ are $5x10^{-3}cm\;s^{-1}$ and $3.1x10^{-6}cm^2\;s^{-1}$, respectively. Our interest in $ABTS^{2-}$ stems from the fact that this molecule functions as a substrate to the copper oxidase, laccase, by providing the reducing equivalents necessary for the biocatalyzed reduction of dioxygen to water. Consequently, when laccase is tethered to an electrode surface or dissolved in solution, $ABTS^{2-}$ can be used to quantify enzyme activity electrochemically.

• Geomechanics and Engineering
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• v.17 no.2
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• pp.145-156
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• 2019

Since behaviors of loose, dense, silty sands vary under seismic loading, understanding the liquefaction mechanism of sandy soils continues to be an important challenges of geotechnical earthquake engineering. In this study, 36 deformation controlled cyclic simple shear tests were performed and the liquefaction potential of the sands was investigated using three different relative densities (40, 55, 70%), four different effective stresses (25, 50, 100, 150 kPa) and three different shear strain amplitudes (2, 3.5, 5%) by using energy based approach. Experiments revealed the relationship between per unit volume dissipated energy with effective stress, relative density and shear strain. The dissipate energy per unit volume was much less affected by shear strain than effective stress and relative density. In other words, the dissipated energy is strongly dependent on relative density and effective stress. These results show that the dissipated energy per unit volume is very useful and may contain the non-uniform loading conditions of the earthquake spectrum. When multiple regression analysis is performed on experiment results, a relationship is proposed that gives liquefaction energy of sandy soils depending on relative density and effective stress parameters.

• Journal of Ocean Engineering and Technology
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• v.9 no.2
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• pp.112-122
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• 1995

In this work, prediction of fatigue life and fatigue crack growth are studied. 4th order polynominal function is presented to describe the crack growth behaviors from artifical pit of SM45C steel. Crack growth curves obtained from 4th order polyminal growth equations are in good agreement with experimental data The crack growth behaviors at arbitrary stress levels and investigated by the concept of elastic-plastic fracture mechanics using ${\Delta}J$. Fatigue life prediction are carried out by numerical integral method. Prediction lives obtained by proposed method in this study, is in good agreement with the experimental ones. Life prediction results calculated by using of ${\Delta}J$ better than those of ${\Delta}K$.

• Carbon letters
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• v.14 no.1
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• pp.51-54
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• 2013

In this study, polyaniline (PANI)/graphene nanosheet (GNS) composites were synthesized through chemical oxidation polymerization by changing the weight ratio of aniline monomers. To examine the morphological structure of the composites, scanning electron microscopy and transmission electron microscopy (TEM) were conducted. TEM results revealed that fibril-like PANI with a diameter of 50 nm was homogeneously coated on the surface of the GNS. The electrochemical properties of the composites were studied by cyclic voltammetry in 1 M $H_2SO_4$ electrolyte. Among the prepared samples, the PANI/GNS (having 40 wt% aniline content) showed the highest specific capacitance, 528 $Fg^{-1}$, at 10 $mVs^{-1}$. The improved performance was attributed to the GNS, which provides a large number of active sites and good electrical conductivity. The resulting composites are promising electrode materials for high capacitative supercapacitors.

• Journal of Mechanical Science and Technology
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• v.19 no.3
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• pp.826-835
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• 2005

Exposed-type steel column bases are used widely in low-rise building construction. Numerous researchers have examined methods to identify their stiffness and strength, but those studies have heretofore been restricted to in-plane behaviors. This paper presents an experimental investigation of inelastic behaviors of square hollow section (SHS) steel column bases under biaxial bending. Two types of failure modes are considered : anchor bolt yielding and base plate yielding. Different pinching effects and interaction surfaces for biaxial bending are observed for these two modes during bi-directional quasi-static cyclic loading tests. Differences are elucidated using limit analyses based on a simple analytical model.

• Carbon letters
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• v.12 no.4
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• pp.252-255
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• 2011

Carbon-based electric double-layer capacitors are being evaluated as potential energy-storage devices in an expanding number of applications. In this study, samples of carbon black (CB) treated at different temperatures ranging from $650^{\circ}C$ to $1100^{\circ}C$ were used as electrodes to improve the efficiency of a capacitor. The surface properties of the heat-treated CB samples were characterized by X-ray photoelectron spectroscopy and X-ray diffraction. The effect of the heat-treatment temperature on the electrochemical behaviors was investigated by cyclic voltammetry and in galvanostatic charge-discharge experiments. The experimental results showed that the crystallinity of the CBs increased as the heat-treatment temperature increased. In addition, the specific capacitance of the CBs was found to increase with the increase in the heat-treatment temperature. The maximum specific capacitance was 165 $F{\cdot}g-1$ for the CB sample treated at $1000^{\circ}C$.

• Structural Engineering and Mechanics
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• v.47 no.6
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• pp.773-790
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• 2013

Bending behaviors of corroded reinforced concrete (RC) beams under repeated loading were investigated experimentally. A total of twenty test specimens, including four non-corrosion and sixteen corrosion reinforced concrete beams, were prepared and tested. A numerical model for flexural and cracking behaviors of the beam under repeated loading was also developed. Effects of steel corrosion on reinforced concrete beams regarding cracking, mid-span deflection, stiffness and bearing capacity of corroded beams were studied. The impact of corrosion on bond strength as the key factor was investigated to develop the computational model of flexural capacity. It was shown from the experimental results that the bond strength between reinforcement and concrete had increased for specimen of low corrosion levels, while this effect was changed when the corrosion level was higher. It was indicated that the bearing capacity of corrosion beam increased even at a corrosion level of about 5%.

• Bulletin of the Korean Chemical Society
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• v.29 no.4
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• pp.777-781
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• 2008

In this work, silver nanoparticles-containing polyacrylonitrile (PAN) solutions in N,N-dimethylformamide (DMF) were electrospun to be webs consisting of nanofibers. The inputted voltage and PAN content in the solution were fixed at 15 kV and 10 wt.% in DMF with 10 cm of tip-to-collector distance (TCD). The PAN/Ag nanofiber webs were stabilized by oxidation at 250 ${^{\circ}C}$ for 2 h in air and carbonized at 1000 ${^{\circ}C}$ for 2 h in $N_2$. The resultant diameter distribution and morphologies of the nanofibers were evaluated by scanning electron microscope analysis. The electrochemical behaviors of the nanofiber webs were also observed by cyclic voltammetry tests. It was found that the presence of silver nanoparticles in carbon nanofiber webs led to the increase of specific capacitance and the decrease of fiber diameters.

• International Journal of Railway
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• v.3 no.2
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• pp.73-82
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• 2010

Global and local behaviors of a lightly RC shear walls are investigated in this paper. For the sake of cyclic behaviors, nominal ground accelerations of 0.15 g, 0.40 g and 0.55 g which associated with natural periods of the walls are applied as listed in French CAMUS-2000 shake table test. Modified Kent & Park model, Drucker-Prager model for concrete material and $Giufr\acute{e}$-Menegotto-Pinto model for rebar are used for time history analyses using fiber/solids elements respectively. Alternatively, Eulerian beam analysis are discussed by imposing inelastic hinges at the most possible plastic hinge location using modified Takeda's trilinear model with stiffness reduction. Relative displacements, base shears, bending moments of 5-story shear building with 36-tons of mass under bi-lateral seismic excitation are extracted and compared with EC-8, PS-92 and KBC-09 provisions. Multi-scaled degradation process; material damage, elemental fracture and structural failure in turn is discussed in the view of numerical accuracy, efficiency and limitation depending on three different model-based analyses.

• Proceedings of the Earthquake Engineering Society of Korea Conference
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• 2003.03a
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• pp.140-147
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• 2003

There are many problems in the prediction of soil dynamic behaviors because undrained excess pore water pressure builds up and then the strain softening behavior is occurred simultaneously. A few analytical methods based on the dynamic constitutive model have been proposed but the model hardly predict the excess pore water pressure directly. In this study, the verification on the disturbed state concept (DSC) model, proposed by Dr, Desai was performed. Some laboratory tests such as conventional triaxial tests and cyclic triaxial tests were carried out to determine DSC Parameters and then disturbance values are determined by the proposed equation. Through this verification, it is proved that the disturbed state concept can express reliably the soil dynamic characteristics such as excess pore water pressure and strain softening behavior. It is also found that the critical disturbance which is determined at the minimum curvature of disturbance function can be a the specific index.