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Environmental Impact Assessment of Beverage Containers (음료 포장용기의 환경성 평가)

  • Seo, Yong-Chil;Chung, Jae-Chun;Shim, Sang-Guel;Kwon, Dong-Myung
    • Clean Technology
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    • v.3 no.1
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    • pp.88-95
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    • 1997
  • Energy required, air emission, and solid waste generation are calculated with available foreign data ad domestic status using Life Cycle Analysis in order to compare the environmental impact of beverage containers such as PET bottle, aluminum can, glass bottle, and paper pack. Glass bottles are found to be the worst acceptability when considering only recycling rate of glass cullet, however it becomme the best when the refill(reuse) rate of glass bottles is accounted into. To assess tile current and future environmental impact of beverage containers, energy required, air emission, solid waste generation of current data and recycling goals are compared. As a result of the study, recycling of each containers and the reuse of glass bottles must be increased by governmental enforcement to reduce the environmental impacts by beverage containers. Further study on this subject using detailed LCA(life cycle assessment) data should be implemented for the exact environmental and economic assessment.

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500-days Continuous Observation of Nutrients, Chlorophyll Suspended Solid and Salinity in the Keum Estuary, Korea (금강 하구역에서 영양염류, 엽록소, 부유물질과 염분변화에 대한 500일간의 연속관측)

  • Lee, Yong-Hyuk;Yang, Jae-Sam
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.2 no.1
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    • pp.1-7
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    • 1997
  • We have monitored nutrients, chlorophyll, suspended solids, and salinity in the Keum Estuary to understand the temporal fluctuation of oceanographic parameters and to illustrate any variation due to the gate operation of the Keum River Dike from June, 1995 to September, 1996, approximately for 500 days. Tidal range is used as the key factor to explain the fluctuations and atmospheric parameters such as air temperature, wind velocity and rainfall are also used supplementally. The fresh water discharge was selected as another major impact on the estuarine environment due to the gate operation of the Keum Dike. In addition, daily variation by tidal cycle was investigated twice in April and July, 1996. In diurnal variation, salinity was positively correlated with tidal elevation, whereas negatively correlated with nutrients. Relatively high suspended solid and chlorophyll contents were found in the period between high and low tide. In 500 days continuous observations, salinity was negatively correlated with the volume of fresh-water discharge, but positively correlated with nutrients. A major chlorophyll bloom occurred in spring. A similar pattern of variation was observed between suspended solid and the neap-spring tidal cycle. In comparison with the data of the Keurn Estuary before the gate operation of the Keum River dike, fresh-water discharge predominated other environmental factors during the rainy season. In addition, the velocity of tidal current and the concentration of suspended solid were decreased, while nutrients and chlorophyll contents were increased.

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Design and Fabrication of C-Band GaN Based on Solid State High Power Amplifier Unit for a Radar System (레이다용 C-대역 GaN 기반 고출력전력증폭장치 설계 및 제작)

  • Jung, Hyoung Jin;Park, Ji Woong;Jin, Hyoung Seok;Lim, Jae Hwan;Park, Se Jun;Kang, Min Woo;Kang, Hyun Chul
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.28 no.9
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    • pp.685-697
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    • 2017
  • In this paper, it is presented the result of design and fabrication for C-band solid state high power amplifier unit and components using in search radar. The solid state power amplifier(SSPA) assembly was fabricated using GaN(Gallium Nitride), which is semiconductor device, and the transmit signal output power of the solid state high power amplifier unit is generated by combining the transmit signal power of the solid state power amplifier configured in parallel through a design and fabricated waveguide type transmit signal combine assembler. Designed solid state high power amplifier unit demonstrated C-band 500 MHz bandwidth, maximum 10.5% duty cycle, transmit pulse width from $0.0{\mu}s{\sim}000{\mu}s$, and transmit signal power is 44.98 kW(76.53 dBm).

Investigating the Leaching Rate of TiTe3O8 Towards a Potential Ceramic Solid Waste Form

  • Noh, Hye Ran;Lee, Dong Woo;Suh, Kyungwon;Lee, Jeongmook;Kim, Tae-Hyeong;Bae, Sang-Eun;Kim, Jong-Yun;Lim, Sang Ho
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.18 no.4
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    • pp.509-516
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    • 2020
  • An important property of glass and ceramic solid waste forms is processability. Tellurite materials with low melting temperatures and high halite solubilities have potential as solid waste forms. Crystalline TiTe3O8 was synthesized through a solid-state reaction between stoichiometric amounts of TiO2 and TeO2 powder. The resultant TiTe3O8 crystal had a three-dimensional (3D) structure consisting of TiO6 octahedra and asymmetric TeO4 seesaw moiety groups. The melting temperature of the TiTe3O8 powder was 820℃, and the constituent TeO2 began to evaporate selectively from TiTe3O8 above around 840℃. The leaching rate, as determined using the modified American Society of Testing and Materials static leach test method, of Ti in the TiTe3O8 crystal was less than the order of 10-4 g·m-2·d-1 at 90℃ for durations of 14 d over a pH range of 2-12. The chemical durability of the TiTe3O8 crystal, even under highly acidic and alkaline conditions, was comparable to that of other well-known Ti-based solid waste forms.

Evaluation of Electrochemical Properties of Amorphous LLZO Solid Electrolyte Through Li2O Co-Sputtering (Li2O Co-Sputtering을 통한 비정질 LLZO 고체전해질의 전기화학 특성 평가)

  • Park, Jun-Seob;Kim, Jong-Heon;Kim, Hyun-Suk
    • Korean Journal of Materials Research
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    • v.31 no.11
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    • pp.614-618
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    • 2021
  • As the size of market for electric vehicles and energy storage systems grows, the demand for lithium-ion batteries (LIBs) is increasing. Currently, commercial LIBs are fabricated with liquid electrolytes, which have some safety issues such as low chemical stability, which can cause ignition of fire. As a substitute for liquid electrolytes, solid electrolytes are now being extensively studied. However, solid electrolytes have disadvantages of low ionic conductivity and high resistance at interface between electrode and electrolyte. In this study, Li7La3Zr2O12 (LLZO), one of the best ion conducting materials among oxide based solid electrolytes, is fabricated through RF-sputtering and various electrochemical properties are analyzed. Moreover, the electrochemical properties of LLZO are found to significantly improve with co-sputtered Li2O. An all-solid thin film battery is fabricated by introducing a thin film solid electrolyte and an Li4Ti5O12 (LTO) cathode; resulting electrochemical properties are also analyzed. The LLZO/Li2O (60W) sample shows a very good performance in ionic conductivity of 7.3×10-8 S/cm, with improvement in c-rate and stable cycle performance.

UV-cured Polymer Solid Electrolyte Reinforced using a Ceramic-Polymer Composite Layer for Stable Solid-State Li Metal Batteries

  • Hye Min Choi;Su Jin Jun;Jinhong Lee;Myung-Hyun Ryu;Hyeyoung Shin;Kyu-Nam Jung
    • Journal of Electrochemical Science and Technology
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    • v.14 no.1
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    • pp.85-95
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    • 2023
  • In recent years, solid-state Li metal batteries (SSLBs) have attracted significant attention as the next-generation batteries with high energy and power densities. However, uncontrolled dendrite growth and the resulting pulverization of Li during repeated plating/stripping processes must be addressed for practical applications. Herein, we report a plastic-crystal-based polymer/ceramic composite solid electrolyte (PCCE) to resolve these issues. To fabricate the one-side ceramic-incorporated PCCE (CI-PCCE) film, a mixed precursor solution comprising plastic-crystal-based polymer (succinonitrile, SN) with garnet-structured ceramic (Li7La3Zr2O12, LLZO) particles was infused into a thin cellulose membrane, which was used as a mechanical framework, and subsequently solidified by using UV-irradiation. The CI-PCCE exhibited good flexibility and a high room-temperature ionic conductivity of over 10-3 S cm-1. The Li symmetric cell assembled with CI-PCCE provided enhanced durability against Li dendrite penetration through the solid electrolyte (SE) layer than those with LLZO-free PCCEs and exhibited long-term cycling stability (over 200 h) for Li plating/stripping. The enhanced Li+ transference number and lower interfacial resistance of CI-PCCE indicate that the ceramic-polymer composite layer in contact with the Li anode enabled the uniform distribution of Li+ flux at the interface between the Li metal and CI-PCCE, thereby promoting uniform Li plating/stripping. Consequently, the Li//LiFePO4 (LFP) full cell constructed with CI-PCCE demonstrated superior rate capability (~120 mAh g-1 at 2 C) and stable cycle performance (80% after 100 cycles) than those with ceramic-free PCCE.

Thermal Characteristics of Samarium-based Composite Cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/ Sm_{0.2}Ce_{0.8}O_{1.9}$) for Intermediate Temperature-operating Solid Oxide Fuel Cell (고체산화물 연료전지의 Samarium Oxide 혼합 공기극에 대한 열특성 분석)

  • Baek, Seung-Wook;Bae, Joong-Myeon
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2021-2025
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    • 2007
  • Performance of single cell at solid oxide fuel cell (SOFC) system is largely affected by electrocatalytic and thermal properties of cathode. Samarium-based perovskite oxide material is recently recognized as promising cathode material for intermediate temperature-operating SOFC due to its high electrocatalytic property. Perovskite structured $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$ and its composite material, $Sm_{0.5}Sr_{0.5}CoO_{3-\delta}/Sm_{0.2}Ce_{0.8}O_{1.9}$ were investigated in terms of area specific resistance (ASR), thermal expansion coefficient (TEC), thermal cycling and long term performance. $Sm_{0.2}Ce_{0.8}O_{1.9}$ was used as electrolyte material. Electrochemical ac impedance spectroscopy (EIS) and dilatometer were used to measure the cathodic properties. Composite cathode ($Sm_{0.5}Sr_{0.5}CoO_{3-\delta}$: $Sm_{0.2}Ce_{0.8}O_{1.9}$ = 6:4) showed a good ASR of 0.13${\Omega}$ $cm^2$ at 650$^{\circ}C$ and its TEC value was 12.3${\times}$10-6/K at 600$^{\circ}C$ which is similar to the value of ceria-based electrolyte of 11.9${\times}$10-6/K. Performance of composite cathode was maintained with no degradation even after 13 times thermal cycle test.

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Neutronic design and evaluation of the solid microencapsulated fuel in LWR

  • Deng, Qianliang;Li, Songyang;Wang, Dingqu;Liu, Zhihong;Xie, Fei;Zhao, Jing;Liang, Jingang;Jiang, Yueyuan
    • Nuclear Engineering and Technology
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    • v.54 no.8
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    • pp.3095-3105
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    • 2022
  • Solid Microencapsulated Fuel (SMF) is a type of solid fuel rod design that disperses TRISO coated fuel particles directly into a kind of matrix. SMF is expected to provide improved performance because of the elimination of cladding tube and associated failure mechanisms. This study focused on the neutronics and some of the fuel cycle characteristics of SMF by using OpenMC. Two kinds of SMFs have been designed and evaluated - fuel particles dispersed into a silicon carbide matrix and fuel particles dispersed into a zirconium matrix. A 7×7 fuel assembly with increased rod diameter transformed from the standard NHR200-II 9×9 array was also introduced to increase the heavy metal inventory. A preliminary study of two kinds of burnable poisons (Erbia & Gadolinia) in two forms (BISO and QUADRISO particles) was also included. This study found that SMF requires about 12% enriched UN TRISO particles to match the cycle length of standard fuel when loaded in NHR200-II, which is about 7% for SMF with increased rod diameter. Feedback coefficients are less negative through the life of SMF than the reference. And it is estimated that the average center temperature of fuel kernel at fuel rod centerline is about 60 K below that of reference in this paper.

The Relationship between circulation of precipitation and urbanization (생태학적 측면에서 고찰한 빗물 순환체계와 도시화와의 관계)

  • 이은희
    • Journal of the Korean Institute of Landscape Architecture
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    • v.24 no.4
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    • pp.123-131
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    • 1997
  • Since the industrial revolution. the growth of cities has been especially apid and the rate of ulbanization has been high. This urban development is encroaching on the natural environment because the cities are developed with not only residential estates, industrial area and buildings but also with infrastructure. The surface area of the city is sealed ,with pavement whereas nature is disturbed and modified. The hydrological cycle in the city is inf1uenced by the change of land use I. e., from forest to agricultural land, talc draining of wetlands and above all the increase of built-up areas. The surface retention and interception of precipitation in the city is reduced. because the surface area is now smooth and solid. The characteristics of the hydrological cycle in the city are increased runoff, reduced evapotranspiration and infiltraction . We have too much faith in technology although it may cause more unforseen problems. We build more river banks and 'emulation dams and straighten rivers and streams in order to protect ourselves from disasters.. However. the results of hose developments are often higher$.$ water levels, the disturbance of aquatic ecosystems and the reduction of biodiversity. Therefore, we should examine problems from the hydrological cycle in cities and study a natural system as close cities to nature as possible. This paper shows the problems caused by the hydrological cycle in the city. The ecology-oriented method and design must be used in order to protect our environment from dicturbance.

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Design of Scroll Expander for Electric Power Generation System using Organic Rankine Cycle with Biomass Energy Source (바이오매스를 에너지원으로 하는 유기냉매 사이클 스크롤 팽창기 발전 장치 설계)

  • Moon, J.H.;Yu, J.S.;Kim, H.J.;Cho, N.J.
    • Journal of Power System Engineering
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    • v.16 no.4
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    • pp.30-36
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    • 2012
  • A scroll expander has been designed to produce a shaft power from a R134a Rankine cycle for electricity generation. Heat was supplied to the Rankine cycle through a heat exchanger, which received heat from another cycle of water. In the water cycle, water was heated up in a boiler using biogenic solid fuel. The designed scroll expander was a horizontal type, and a trochoidal oil pump was employed for oil supply to bearings and Oldham-ring keys. For axial compliance, a back pressure chamber was created on the backside of the orbiting scroll base plate. Numerical study has been carried out to estimate the performance of the designed scroll expander. The expander was estimated to produce the shaft power of about 2.9 kW from a heat supply of 36 kW, when the temperature of R134a was $80^{\circ}C$ and $35^{\circ}C$ at the evaporator and condenser of the Rankine cycle, respectively. The expander efficiency was about 70.5%. When the amount of heat supply varied in the ranges of 7.5~55 kW, the expander efficiency changed in the range of 45.6~70.5%, showing a peak efficiency of 70.5% at the design shaft speed.