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Preparation and Characteristics of Li4Ti5O12 Anode Material for Hybrid Supercapacitor

  • Lee, Byung-Gwan;Yoon, Jung-Rag
    • Journal of Electrical Engineering and Technology
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    • v.7 no.2
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    • pp.207-211
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    • 2012
  • Spinel-$Li_4Ti_5O_{12}$ was successfully synthesized by a solid-phase method at 800, 850, and $900^{\circ}C$ according to the $Li_4Ti_5O_{12}$ cubic spinel phase structure. To achieve higher EDLC energy density with the $Li_4Ti_5O_{12}$, the negative electrode of the hybrid supercapacitor was studied in this work. The electrochemical performances of the hybrid supercapacitor and EDLC were characterized by constant current discharge curves, c-rate, and cycle performance testing. The capacitance (1st cycle) of the hybrid supercapacitor and EDLC was 209 and 109 F, respectively, which is higher than EDLC. The capacitance of the hybrid supercapacitor decreases from 209 F to 101 F after 20 cycles when discharged at several specific current densities ranging from 1 to 10 A. In contrast, capacitance of the EDLC hardly decreases after 20 cycles. Results show that hybrid supercapacitor benefits from the high rate capability of supercapacitor and high capacity of the battery. Findings also prove that the hybrid supercapacitor is an energy storage device where the supercapacitor and the Li ion secondary battery coexist in one cell system.

Reprocessing of fluorination ash surrogate in the CARBOFLUOREX process

  • Boyarintsev, Alexander V.;Stepanov, Sergei I.;Chekmarev, Alexander M.;Tsivadze, Aslan Yu.
    • Nuclear Engineering and Technology
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    • v.52 no.1
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    • pp.109-114
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    • 2020
  • This work presents the results of laboratory scale tests of the CARBOFLUOREX (CARBOnate FLUORide EXtraction) process - a novel technology for the recovery of U and Pu from the solid fluorides residue (fluorination ash) of Fluoride Volatility Method (FVM) reprocessing of spent nuclear fuel (SNF). To study the oxidative leaching of U from the fluorination ash (FA) by Na2CO3 or Na2CO3-H2O2 solutions followed by solvent extraction by methyltrioctylammonium carbonate in toluene and purification of U from the fission products (FPs) impurities we used a surrogate of FA consisting of UF4 or UO2F2, and FPs fluorides with stable isotopes of Ce, Zr, Sr, Ba, Cs, Fe, Cr, Ni, La, Nd, Pr, Sm. Purification factors of U from impurities at the solvent extraction refining stage reached the values of 104-105, and up to 106 upon the completion of the processing cycle. Obtained results showed a high efficiency of the CARBOFLUOREX process for recovery and separating of U from FPs contained in FA, which allows completing of the FVM cycle with recovery of U and Pu from hardly processed FA.

Development of Numerical Model for Igniter and Study on Initial Ignition of Interior Ballistics (강내탄도의 점화기 해석 모델 개발 및 초기 점화 연구)

  • Sung, Hyung-Gun;Jang, Jin-Sung;Lee, Sang-Bok;Choi, Dong-Whan;Roh, Tae-Seong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.2
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    • pp.105-113
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    • 2013
  • A numerical model of the igniter for the interior ballistics has been developed by combining lumped parameter model with the theoretical equation of orifice. With the developed model of the igniter, the numerical study on characteristics of the interior ballistics has been conducted according to the igniter configuration in terms of igniter length, side hole diameter, and distribution of side holes. As results of the calculation of the pressure difference between the breech and shot base, the low-cycle oscillations have been influenced by the igniter length, while the high-cycle oscillations have been affected by the side hole diameter and the distribution of side holes.

Simulation Analysis of Flexible Track Drilling Machines Based on ADAMS (ADAMS 기반의 플렉시블 트랙 드릴링 머신의 시뮬레이션 분석)

  • Zhu, Zhong-gang;Zhang, Qi;Lv, Jian-Hua;Qin, Zhen;Lyu, Sung-Ki
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.17 no.5
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    • pp.1-7
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    • 2018
  • Flexible track drilling machines are credited with important applications in the area of aircraft manufacturing because of their portability, quick installation capabilities, and high efficiency. However, their structures are special and the constitution principles and motion characteristics are difficult to control, increasing the development costs and research cycle in the context of the technology blockade of foreign companies. The simulation analysis of flexible track drilling machines can be conducted by applying virtual prototypes, shortening the development cycle and reducing the cost. In this paper, a model of a machine is established by using the SolidWorks software and imported into ADAMS to conduct kinematic and dynamic simulation analysis. During the analysis, the feasibility of the configuration is checked, a reasonable driving motion is chosen, potential deficiencies are found, and improvement actions are raised.

Evaluation of Leachate Replacement Effect on Solid State Anaerobic Digestion of Dairy Manure and Sawdust Bedding Mixtures

  • Jo, Hyeonsoo;Lee, Seunghun;Kim, Eunjong;Ahn, Heekwon
    • Korean Journal of Soil Science and Fertilizer
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    • v.50 no.4
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    • pp.293-305
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    • 2017
  • This experiment was conducted to evaluate the effect of leachate replacement frequency on solid state anaerobic digestion (SSAD) of dairy manure using 22 L volume lab-scale digesters at mesophilic temperature ($37^{\circ}C$) in batch mode. Three different leachate replacement strategies (no replacement, once every three days, and once every nine days) were applied and three digesters per each treatment were operated for 45 days. Results showed that leachate replacement test unit every nine days resulted in 1.6 times more methane production ($53.8N{\cdot}mL\;g^{-1}{\cdot}VS$) from SSAD compared to test unit every three days ($34.0N{\cdot}mL\;g^{-1}{\cdot}VS$). No leachate replacement strategy applied group showed slightly higher methane production ($56.3N{\cdot}mL\;g^{-1}{\cdot}VS$) than every nine days replaced one. When added the methane production potential of replaced leachate itself to the methane produced from digester, leachate replacement every nine days resulted in quite similar methane production ($56.5N{\cdot}mL\;g^{-1}{\cdot}VS$) to no leachate replacement group. Even though methane production potential of replaced leachate itself added to the methane produced from digester, every three days replacement showed only $34N{\cdot}mL$ methane production per gram of volatile solids. These results suggest that farmers do not need to replace leachate during SSAD of dairy manure and sawdust mixture in order to maximize methane production. If there are any concerns with accumulation of inhibiting substances in the digester, the 9-day cycle leachate replacement is appropriate.

Effective Equivalent Finite Element Model for Impact Limiter of Nuclear Spent Fuel Shipping Cask made of Sandwich Composites Panels (사용후 핵연료 수송용기 샌드위치 복합재 충격완충체의 유효등가 유한요소 모델 제시)

  • Kang, Seung-Gu;Im, Jae-Moon;Shin, Kwang-Bok;Choi, Woo-Suk
    • Composites Research
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    • v.28 no.2
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    • pp.58-64
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    • 2015
  • The purpose of this paper is to suggest the effective equivalent finite element model for the impact limiter of a nuclear spent fuel shipping cask made of sandwich composite panels. The sandwich composite panels were composed of a metallic facesheet and a core material made of urethane foam, balsa wood and red wood, respectively. The effective equivalent finite element model for the impact limiter was proposed by comparing the results of low-velocity impact test of sandwich panels. An explicit finite element analysis based on LS-DYNA 3D was done in this study. The results showed that the solid elements were recommended to model the facesheet and core of sandwich panels for impact limiter compared to combination modeling method, in which the layered shell element for facesheet and solid element for core material are used. In particular, the solid element for balsa and red wood core materials should be modeled by the element elimination approach.

The Comparison on Treatment Method of Liquid Radioactive Waste in Yonggwang #3&4 and #5&6 (영광 3&4와 5&6호기에서 액체 방사성폐기물 처리방법의 비교)

  • Yeom, Yu-Seon;Kim, Soong-Pyung;Lee, Seung-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.219-230
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    • 2004
  • Most of the low-level liquid radioactive wastes generated from PWR plants are classified into high or low total suspended solid(HTDS or LTDS), and into radiochemical and radioactive laundry waste. Although the evaporation process has a high decontami- nation ability, it has several problems such as corrosion, foam, and congestion. A new liquid waste disposal process using the ion-exchange demineralizer(IED), instead of the current evaporation process, has been introduced into the Yonggwang NPP #5 and 6. These two methods have been compared to understand the differences in this study. Aspects compared here were the released radioactivity amount of the liquid radioactive wastes, the dose of off-site residents, the decontamination factor, and the amount of the solid radioactive wastes. The IED system is designed to discharge higher radioactivity about 20% than the evaporating system, and the actual radioactivity released from the evaporating and IED system were 0.473mCi and 1.098mCi, respectively. The radioactivity released from the IED was 2.32 times higher than that of the evaporating system. The dose of off-site residents was $2.97{\times}10^{-6}$mSv for the evaporating system, and $6.47{\times}10^{-6}$mSv for IED. The decontamination factor(DF) of the evaporator is, in most cases, far lower than the lower limits of detection(LLD) with the Ge-Li detector. Due to the low concentration of the liquid wastes collected from the liquid waste system, the decontamination factor of IED is very low. Since there is not enough data on the amount of solid radioactive wastes generated by the evaporation system, the comparison on these two systems has been conducted on the basis of the design, and the comparison result was that the evaporating system generated more wastes about 40% than IED.

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Development of Automatic Design Program for Solid Rocket Motors Structure (고체 추진기관 구조체의 설계 자동화 프로그램 개발)

  • Kim, Won-Hoon;Koo, Song-Hoe;Moon, Soon-Il;Hwang, Ki-Young;Lee, Kang-Soo;Seok, Jung-Ho
    • Journal of the Korean Society of Propulsion Engineers
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    • v.10 no.3
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    • pp.18-25
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    • 2006
  • In order to perform system requirements quickly and accurately, an automatic design program of solid rocket motors(SRM) structure designated as the 'ProDes software' has been developed and verified. from given system design criteria and constraints, it has the capabilities to design, analysis, simulation and drawing process to greatly reduce the over 'design cycle time' and manpower of a project. The conception of the program is modular, and calculations are performed step by step allowing parametric design studies and providing final selected design goal. Each configurations of SRM components and joint types composed of various master models is obtained from the data base module of the library. Between the design results of the ProDes software and those of the previous detail design of the established motor showed good agreements.

Immobilization of Radioactive Rare Earth oxide Waste by Solid Phase Sintering (고상소결에 의한 방사성 희토류산화물의 고화)

  • Ahn, Byung-Gil;Park, Hwan-Seo;Kim, Hwan-Young;Lee, Han-Soo;Kim, In-Tae
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.1
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    • pp.49-56
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    • 2010
  • In the pyroprocessing of spent nuclear fuels, LiCl-KCl waste salt containing radioactive rare earth chlorides are generated. The radioactive rare earth oxides are recovered by co-oxidative precipitation of rare earth elements. The powder phase of rare eath oxide waste must be immobilized to produce a monolithic wasteform suitable for storage and ultimate disposal. The immobilization of these waste developed in this study involves a solid state sintering of the waste with host borosilicate glass and zinc titanate based ceramic matrix(ZIT). And the rare-earth monazite which synthesised by reaction of ammonium di-hydrogen phosphate with the rare earth oxides waste, were immobilzed with the borosilicate glass. It is shown that the developed ZIT ceramic wasteform is highly resistant the leaching process, high density and thermal conductivity.

Review on Effective Skills to Inhibit Dendrite Growth for Stable Lithium Metal Electrode (리튬금속전극의 덴드라이트 성장 억제 방안의 연구 동향)

  • Kim, Yerang;Park, Jihye;Hwang, Yujin;Jung, Cheolsoo
    • Journal of the Korean Electrochemical Society
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    • v.25 no.2
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    • pp.51-68
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    • 2022
  • Although lithium metal batteries have a high energy density, experimental skills capable of solving lots of problems induced by dendrite such as short circuit, low coulomb efficiency, capacity loss, and cycle performance are still only in academic research stage. In this paper, research cases for dendrite growth inhibition on lithium metal electrode were classified into four types: flexible SEI (solid electrolyte interface) layer responding to volume expansion of lithium metal electrode, SEI supporting layer to inhibit dendrite growth physically, SHES (self-healing electrostatic shield) mechanism to adjust lithium growth by leading uniform diffusion of Li+ ions, and finally micro-patterning to induce uniform deposition of lithium. We hope to advance the practical use of lithium metal electrode by analyzing pros and cons of this classification.