• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.255-257
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• 2012

Epoxy resin without any hardener can harden in the presence of hydroxide ions in cement mortars and concretes at ambient temperature. The purpose of present study is to examine the hardening properties of hardener-free epoxy-modified mortars by curing conditions. The hardener-free epoxy-modified mortars using diglycidyl ether of A epoxy resin are prepared with various polymer-cement ratios, and subjected to initial moist/dry curing, initial steam(90℃) curing, initial steam/heat(80℃, 100℃) curing.As a result, degree of hardening of epoxy resin in initial moist/dry cured, initial steam cured and initial steam/heat(80℃) cured hardener-free epoxy-modified mortars is decreased with increasing polymer-cement ratio. However, it is markedly improved with additional dry-curing periods. On the other hand, regardless of the polymer-cement ratio and dry curing periods, degree of hardening of hardener-free epoxy-modified mortars with initial steam/heat(100℃) cure is over 95%.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.43 no.1
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• pp.1-7
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• 2015

This paper predicts the spring-in effect of curved laminated composite structure for various stacking sequence using finite element analysis(ABAQUS). In composite manufacturing process, large temperature difference, different coefficient of thermal expansion and chemical shrinkage effect cause distortion of composite parts such as spring-in and warpage. Distortion of composite structure is important issue on quality of product, and it should be considered in manufacturing process. In finite element analysis, a CHILE(Cure Hardening Instantaneously Linear Elastic) model and chemical shrinkage effects are considered developing user subroutine in ABAQUS and some cases are simulated.

• Macromolecular Research
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• v.16 no.2
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• pp.128-133
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• 2008

Several dual-curable acrylic pressure-sensitive adhesives (PSA) were synthesized by the radical polymerization of acrylic monomers containing benzophenone, hydroxyl, and alkyl groups. The optimum extent of UV-induced cure was determined by varying the content of the benzophenone groups (the photoinitiator) from 0.5 to 1.5 wt%. The weight average molecular weight of the polymers obtained ranged from 300,000 to 700,000 amu. The coated pressure-sensitive adhesives were cured either by short UV exposure to induce the grafting of acrylic polymers, or by heating for 6 hat $60^{\circ}C$ to promote the reactions between the polyisocyanates and hydroxyl groups. The dual-curing behavior was determined by monitoring both processes quantitatively by infrared spectroscopy. The developed dual-curable acrylic pressure-sensitive adhesives were found to compensate for the limitations in UV-induced curing of thick coatings.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2009.11a
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• pp.55-59
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• 2009

The epoxy resin without hardener can harden by a ring-opening reaction in the presence of the alkalies produced by the hydration of cement in epoxy-modified mortars and concretes. This paper investigates the effect of curing conditions on the strength improvement of polymer-modified mortars using bisphenol A-type epoxy resin without hardener. The polymer-modified mortars using epoxy resin are prepared with various polymer-cement ratios, and subjected to ideal, water, dry and heat cures. In the heat cure, the epoxy-modified mortars are sealed or unsealed with a PVDC (polyvinylidene chloride) film. The epoxy-modified mortars are tested for flexural and compressive strengths at desired curing methods. The microstructures of the epoxy-modified mortars are also observed by scanning electron microscope. The effects of curing conditions on the strength development of the epoxy-modified mortars are examined. From the test results, the marked effectiveness of the heat cure under the PVDC film sealing against the development of the strength of the epoxy-modified mortar without the hardener is recognized. The flexural and compressive strengths of 7-day-90℃ heat-cured, PVDC film-sealed epoxy-modified mortars without hardener reach 7 to 17MPa and 24 to 44MPa respectively, and are two to three times of Unmodified mortar. Such high strength development of the epoxy-modified mortars may be achieved by the dense microstructure formation by cement hydrates and the hardening of the epoxy resin in the mortars.

• Journal of the Korean GEO-environmental Society
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• v.20 no.5
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• pp.31-38
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• 2019

Recently, there has been an increasing number of ground subsidence (sink-hole) in the downtown areas, and in such a case, it is important to minimize accidents and passages through prompt recovery. With respect to the present recovery method for ground subsidence, the methods of applying the back filling after excavating the ground subsidence or using the grouting injected materials to restore the ground are mostly used, but there has been few studies on materials used for recovering the ground subsidence. Therefore, in order to clarify the characteristics of back filling materials used in the ground subsidence, this study uses the environment-friendly hardening agent to improve the dredged clay, and then, the mixture ratio of hardening agent and mixture ratio of decomposed granite soil is changed to cure for 3, 7, 14 and 28 days to analyze the intensity characteristics of the unconfined compression, and it was compared with the unconfined compression intensity for the previously used cement, a hardening agent. In order to evaluate the characteristics of intensity on the back filling materials, the C.B.R test was carried out, and for the review on whether the back filling materials influence on corrosion of water and sewer pipes and others, the soil non-resistance test was carried out. As a result of the test, for the case of the recovery work of the ground subsidence that requires urgency, it is considered as prudent if the hardening agents of 12% are integrated to cure for 3 days or longer, and for not having the influence on the corrosion of the gas tube or water pipes, it is proposed to mix for 30% or more of the decomposed granite soil. Door model test were conducted To confirm the bearing capacity characteristics of the solidified layer.

• 제어로봇시스템학회:학술대회논문집
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• 2005.06a
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• pp.2160-2163
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• 2005

Solid freeform fabrication (SFF) technology plays a major role in industry and represents a reasonable percentage of industrial rapid prototyping/tooling/manufacturing (RP/RT/RM) development applications. However, SFF technology still has long way to progress to achieve satisfactory process speed, surface finish and overall quality improvement of its application. Today, three dimensional printing (3DP) technique that is one of SFF technology is receiving many interests, and is applied by various fields. It can fabricate three dimensional objects of solid freeform with high speed and low cost using ink jet printing technology. However, need long curing time after manufacture completion. And it must do post-processing process necessarily to heighten strength of objects because strength of fabricated objects is very weak. Therefore, in this study, we proposed an improved 3DP process that can solve problems of conventional 3DP process. The general 3DP process is method to spout binder simply through printer head on powder, but proposed process is method to cure jetted UV resin by UV lamp after jet UV resin using printhead on powder. The hardening of resin is achieved strongly at early time by UV lamp in proposed method. So, the proposed process can fabricate three dimensional objects with high speed without any post-processing.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.9
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• pp.5460-5466
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• 2014

In this study, mainly for kitchen knives and small swords, cutlery, etc. STS420J2 used material used for the experiments. In order to cure the surface of the test piece after the rough grinding and fine grinding was performed in order polishing. Perform the surface hardening of STS420J2 local area by using a diode laser. The output of the laser diode and the feed rate to the process variable. Micro-hardness testing, microstructure testing, scanning electron microscope testing(SEM), the heat input to the analysis. After analyzing the experiment to compare the mechanical properties of the material. When using a diode laser to assess the soundness of the surface hardening. Accordingly, the process for deriving the optimum demonstrate the feasibility.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.3
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• pp.1620-1625
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• 2015

In this study, a variety of industrial gears, shafts, chains, rollers, mold, etc. are widely used inautomotive steel carbon steel for machine structural SM45C typical material used for the experiments. In order to cure the surface of the test piece after the rough grinding and fine grinding was performed in order polishing. Perform the surface hardening of SM45C lacal area by using a diode laser. The output of the laser diode and the feed rate to the process variable. Micro-hardness testing, microstructure testing, scanning electron microscope testing(SEM), the heat input to the analysis. After analyzing the experiment to compare the mechanical properties of the material. When using a diode laser to assess the soundness of the surface hardening. Accordingly, the process for deriving the optimum demonstrate the feasibility.

• Composites Research
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• v.33 no.4
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• pp.220-227
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• 2020

When curing the composite, the fibers have little thermal deformation, but the resin changes its properties with time and temperature, which leads to residual stress in the product. Residual stress is caused by the difference in the coefficient of thermal expansion of the fibers and resin during the curing process and the chemical shrinkage of the resin. This difference causes thermal deformation such as spring-in and warpage. Thermal deformation of composite structure is important issue on quality of product, and it should be considered in manufacturing process. In this study, a subroutine was developed to predict thermal deformation by applying 3-D viscoelastic model. The finite element analysis was verified by comparing the results of the plate analysis of the 2-D viscoelastic model. Spring-in of L-shaped structure was predicted and analyzed by applying the 3-D viscoelastic model.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05b
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• pp.336-343
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• 1998

An iteration method has been developed for determining crack growth and fracture resistance cure (J-R curve) from the load versus load-line displacement record only. In this method, the hardening curve, the load versus displacement curve at a given crack length, is assumed to be a power-law function, where the exponent varies with the crack length. The exponent is determined by an iterative calculation method with the assumption that the exponent varies linearly with the load-line displacement. The proposed method was applied to the static J-R tests using compact tension(CT) specimens, a three-point bend (TPB) specimen, and a cracked round bar (CRB) specimen as well as it was applied to the quasi-dynamic J-R tests using CT specimens. The J-R curves determined by the proposed method were compared with those obtained by the conventional testing methodologies. The results showed that the J-R curves could be determined directly by the proposed iteration method with sufficient accuracy in the specimens from SA508, SA533, and SA516 pressure vessel steels and SA312 Type 347 stainless steel.