• Title/Summary/Keyword: corrosivity

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Influences of Coatings and Solution Corrosivity on Cathodic Protection of Metallic Materials

  • Yoo, Y.R.;Chang, H.Y.;Jin, T.E.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.5 no.3
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    • pp.106-111
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    • 2006
  • Painting has protected metallic stack but the paint films may be degraded and corrosion problem can be arisen. To protect the painted metal stack, cathodic protection can be applied. If cathodic protection is applied to bare metal, only small area may be protected. However, if cathodic protection is applied to painted metal surface, large area can be protected and the lifetime of paint films can be extended. High corrosion resistant alloys were corroded at a Flue Gas Desulfurization (FGD) facility of power plant within a short period and thus cathodic protection can be used to protect these metals. On the base of computer simulation, if cathodic protection is applied to bare metal in a FGD environment, it was estimated that applied current could almost be spent to protect area near the anode. However, if cathodic protection is applied to high resistant-coated metal, the much larger area from the anode could be effectively protected.

High-temperature Corrosion by Chlorides in Biomass-fired Plants (바이오매스 발전시 염소가스에 의한 고온부식)

  • Lee, Dong Bok
    • Journal of the Korean institute of surface engineering
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    • v.49 no.1
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    • pp.14-19
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    • 2016
  • Biomass is a renewable and sustainable source of energy used to create electricity or pressurized steam. In biomass-fueled power plants, wood waste or other waste is burned to produce steam that runs a turbine to make electricity, or that provides heat to industries and homes. Biomass power plants, apart from producing energy, help to reduce the $CO_2$ emission. However, the main problem is the high-temperature corrosion due to fuel corrosivity, especially of the straw. This limits both the temperature of the steam and also the effectiveness of the power plant. The corrosion in biomass-fueled plant was described.

Cause Analysis for a Lining Damage in Sea Water System Piping Installed in a Korean Industrial Plant

  • Hwang, K.M.;Park, S.K.
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.1-6
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    • 2021
  • Many Korean industrial plants including nuclear and fossil power plants use seawater as the ultimate heat sink to cool the heat generated by various facilities. Owing to the high corrosivity of seawater, facilities and piping made of metal material in contact with seawater are coated or lined with polymeric materials to avoid direct contact with seawater. However, polymeric materials used as coating and lining have some level of permeability to water and are degraded over time. Korean industrial plants have also experienced a gradual increase in the frequency of damage to pipes in seawater systems due to prolonged operating periods. In the event of a cavitation-like phenomenon, coating or lining inside the piping is likely to be damaged faster than expected. In this paper, the cause of water leakage due to base metal damage caused by the failure of the polyester lining in seawater system piping was assessed and the experience with establishing countermeasures to prevent such damage was described.

Assessment of external corrosion deterioration of large diameter metallic water pipes buried in reclaimed land (간척지대에 매설된 대구경 금속관의 외면 부식손상 평가)

  • Lee, Ho-Min;Choi, Tae-Ho;Kim, Jung-Hyun;Bae, Cheol-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.5
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    • pp.373-383
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    • 2020
  • The purpose of this study was to evaluate the corrosion damage of large diameter metallic pipes buried in reclaimed land due to the corrosion effect by soil, and to propose a method of installing metal pipes in the reclaimed land. The results are as follow. First, the soil of the reclaimed land was gray clay, the soil specific resistance indicating soil corrosiveness was at least 120 Ω-cm, the pH was weakly acidic(5.04 to 5.60), the redox potential was at least 62 mV, the moisture content was at most 48.8%, and chlorine ions and sulfate ions were up to 4,706.1 mg/kg and 420 mg/kg. Therefore, the overall soil corrosivity score was up to 19, and the external corrosion effect seems to be very large. Second, the condition of straight part of pipes was in good condition, but most of KP joints were affected by corrosion at a severe level. The reason for this seems to be that KP joints accelerated corrosion due to stress and crevice corrosion in addition to galvanic corrosion in the same environment. Third, as a result of evaluating correlations of each item that affects the corrosion on the external part, the lower the soil resistivity and redox potential, the greater the effect on the KP joints corrosion, and the moisture content, chloride ion, and sulfate ion, the higher the value, the greater the effect on the corrosion of KP joints. In addition, among soil corrosion items, the coefficient of determination of soil resistivity with corrosion of KP joints was the highest with 0.6439~0.7672. Fourth, when installing metal pipes or other accessories because the soil of the reclaimed land is highly corrosive, it is necessary to apply a corrosion preventive method to extend the life of pipes and prevent leakage accidents caused by corrosion damage to the joint.

Corrosion of Metals in Waterborne Preservative-Treated Wood (수용성(水溶性) 방부처리재(防腐處理材)에서 금속류(金屬類)의 부식(腐蝕))

  • Kim, Gyu-Hyeok;Kim, Jae-Jin
    • Journal of the Korean Wood Science and Technology
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    • v.20 no.1
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    • pp.15-22
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    • 1992
  • This study was performed to investigate the corrosion of metal fasteners in waterborne preservative-treated wood. Of all the metal tested, steel exhibited the greatest amount of corrosion across all preservatives and exposure conditions whereas stainless steel was totally inert. Galvanized steel corroded at a much lower rate compared to steel and the corrosion of brass was negligible. Among the preservatives, CCA-Type B was the most corrosive system tested. The sequence for the average corrosivity across all metals was: CCA-type B>CCA-Type C${\geq}$ACC${\geq}$CCA-Type A. Across all metals and retentions the salt formulations were more corrosive than the oxide and the corrosion was increased with the increse in the amount of preservative loadings. The amount of corrosion was also increased with the increase in exposure relative humidity (RH) across all metals and presevatives However, at the 60% RH exposure condition, the corrosion of metals was very negligible. Consequently, it can be concluded that across all metals oxide-type preservatives should be used to prevent the corrosion problem of metal fasteners in contact with treated wood and the use of steel nail preservative-treated wood should be avoided without distinction of end-use location, i.e., exterior or interior, and the use of stainless steel or at least brass nail in damp exterior condition was strongly recommended.

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The Monitoring of Corrosive Water Quality in Water Distribution System by Corrosion Characteristics of Raw and Tap water (원·정수의 부식특성에 따른 상수관망에서의 부식성 수질 모니터링)

  • Bae, Seog-Moon;Kim, Do-Hwan;Son, Hee-Jong;Choi, Dong-Hoon;Kim, Ik-Sung;Kim, Kyung-A
    • Journal of Environmental Science International
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    • v.24 no.7
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    • pp.907-915
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    • 2015
  • The tap water is generally known to be corrosive in the pH range at 6.5 ~ 7.5. And the degree of corrosion varies depending on the types of raw water such as river surface water or lake water of the dam. Although several corrosion index represents the corrosivity of tap water, the typical corrosion indexes such as Langelier saturation index (LI) and calcium carbonate precipitation potential (CCPP) were calculated to monitoring the corrosive water quality about raw and tap water in water distribution system. To control the corrosive water quality, the correlation between corrosion index and water quality factors were examined. In this study, corrosion index (LI, CCPP) and the pH was found to be most highly correlated.

Application of Neural Networks in Aluminum Corrosion

  • Powers, John;Ali, M. Masoom
    • Journal of the Korean Data and Information Science Society
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    • v.11 no.2
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    • pp.157-172
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    • 2000
  • Metal containers represent a situation where a specific metal is exposed to a wide variety of electrolytes of varying degrees of corrosivity. For example, hundreds, if not thousands of different products are packaged in an aluminum beverage can. These products vary in pH, chloride concentration and other natural or artificial ingredients which can effect the type and severity of potential corrosion. Both localized (perforation) and uniform corrosion (metal dissolution without the onset of pitting) may occur in the can. A quick test or series of tests which could predict the propensity towards both types of corrosion would be useful to the manufacturer. Electrochemical noise data is used to detect the onset and continuation of pitting corrosion. Specific noise parameters such as the noise resistance (the potential noise divided by the current noise) have been used to both detect pitting corrosion and also to estimate the pitting severity. The utility of noise resistance and other electrochemical parameters has been explored through the application of artificial neural networks. The versatility of artificial neural networks is further demonstrated by combing electrochemical data with electrolyte properties such as pH and chloride concentration to predict both the severity of both localized and uniform corrosion.

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Assessment of Atmospheric Corrosivity at Jeju Island (제주도 대기환경의 부식성 평가)

  • KIM GUI-SHIK;YANG KYEONG-CHO;HU CHUL-GOO;SONG JEONG-HWA
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.11a
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    • pp.253-259
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    • 2004
  • The Jeju Island in Korea is the clean area which the tradition culture is preserved locally well with the nature environment of Heaven's blessing. An air pollution is becoming recently serious problem as the industrial development is proceeded with the urbanization. This study investigates that the atmosphere environment at Jeju area influences on the metal corrosion. A study of the atmosphere corrosion for carbon steel, copper, zinc ana aluminium exposed on five test sites indoors and outdoors. Corrosion results are treated statistically and adjusted to a model previously proposed for carbon steel, copper, zinc and aluminium based on the influence of environmental parameters and main pollutants($SO_2$ and chlorides) on tire atmosphere corrosion of metals. Through this study, we try to set the standards atmosphere corrosion at Jeju Island.

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Characteristics and Corrosion Behaviors of Quaternary (Co/Ni/P/Mn) Electroless Plating (4성분 무전해도금(Co/Ni/P/Mn)의 특성 및 부식거동)

  • Hur, Ho
    • Clean Technology
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    • v.20 no.2
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    • pp.136-140
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    • 2014
  • The quaternary alloy (Co/Ni/P/Mn) coatings were prepared using electroless plating on the polypropylene. Compositions of the quaternary alloys (Co/Ni/P/Mn) were controlled by the amount of agents. The composition by EDS, morphology with SEM, film thickness, and surface electrical resistance of the samples were measured. Higher phosphorous content samples give larger electric resistance, thus a relationship is admitted between P content and electric resistance. The corrosivity of the coatings were evaluated by electrochemical methods in the 3.5 wt% NaCl and 5.0 wt% $H_2SO_4$ solutions, respectively. It was concluded that phosphorous addition enhances resistivity in the corrosion.

Effect of Area Ratio on Galvanic Corrosion Between Metallic Materials and GECM in 3.5% NaCl Solution (3.5% NaCl 수용액 중에서의 금속과 GECM의 갈바닉 부식에 미치는 면적비의 영향)

  • Kim, Y.S.;Lim, H.K.;Sohn, Y.I.;Yoo, Y.R.;Chang, H.Y.
    • Corrosion Science and Technology
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    • v.9 no.1
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    • pp.39-47
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    • 2010
  • Galvanic coupling between GECM(graphite epoxy composite material) and metallic materials can facilitate corrosion of metals and alloys because GECM is noble and electrically conductive. Galvanic corrosion is affected by many factors including metallic materials, area ratio, surface condition, and corrosivity. This work aims to evaluate the effect of area ratio on galvanic corrosion between GECM and several metals. In the case of glavanic coupling of carbon steel and Al to GECM, corrosion rate increased with increasing area ratio. Corrosion rate of sensitized STS 316S stainless steel decreased a little at an area ratio 1:1 but increased at an area ratio 30:1. It is considered to be due to that area ratio affects galvanic corrosion more in less corrosion resistant alloys. However, in case of STS 316 and Ti, galvanic coupling reduces corrosion rate by the formation of passive film.