• Journal of Powder Materials
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• v.23 no.6
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• pp.414-419
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• 2016

Much attention has been paid to thermally conductive materials for efficient heat dissipation of electronic devices to maintain their functionality and to support lifetime span. Hexagonal boron nitride (h-BN), which has a high thermal conductivity, is one of the most suitable materials for thermally conductive composites. In this study, we synthesize h-BN nanocrystals by pyrolysis of cost-effective precursors, boric acid, and melamine. Through pyrolysis at $900^{\circ}C$ and subsequent annealing at $1500^{\circ}C$, h-BN nanoparticles with diameters of ~80 nm are synthesized. We demonstrate that the addition of small amounts of Eu-containing salts during the preparation of melamine borate precursors significantly enhanced the crystallinity of h-BN. In particular, addition of Eu assists the growth of h-BN nanoplatelets with diameters up to ~200 nm. Polymer composites containing both spherical $Al_2O_3$ (70 vol%) and Eu-doped h-BN nanoparticles (4 vol%) show an enhanced thermal conductivity (${\lambda}{\sim}1.72W/mK$), which is larger than the thermal conductivity of polymer composites containing spherical $Al_2O_3$ (70 vol%) as the sole fillers (${\lambda}{\sim}1.48W/mK$).

• Journal of Adhesion and Interface
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• v.10 no.1
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• pp.30-34
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• 2009

The effect of pressure on the thermal conductivity in two-phase composite system was studied. Thermally conductive polypropylene (PP)/silicon carbide (SiC) composites were prepared by applying various pressures from 0 to 20 MPa. The thermal conductivity of the composite was 1.86 W/mK at 20 MPa, increased by 40% compared to the value of at 0 MPa. It was 9 times higher than that of unfilled polypropylene. It implies the pressure induces the easy path for phonon transport. Also, the experimental values were compared with Maxwell's prediction and Agari's prediction. Agari's prediction gave a better agreement compared to that of Maxwell's prediction due to the consideration of interactions between filler-filler and filler-polymer.

• Polymer(Korea)
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• v.26 no.5
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• pp.644-652
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• 2002

This study aims at developing the conductive pastes consisting of room temperature vulcanizing (RTV) silicone and metal powder as matrix and filler, respectively. Electrical and rheological properties of metal - filled polymer composites are in general strongly affected by particle shape, side and dispersion state of the filler. In highly filled systems, particles tend to form very complex agglomerated structure which is easily changed when subjected to shear deformation. And the breakdown of agglomerated particles due to shear usually leads to the change of electrical conductivity of the composite. In this study, the effect of particle size and dispersion state of filler on the electrical conductivity of the composites are investigated to offer the selection criteria of conductive filler by measuring the rheological properties of uncured composites and the electrical conductivity of the cured composites. It was found that the type of metal filler systematically affected the rheological property, the susceptibility to shear and the degree of change of electrical conductivity of the composite. The effect of shear on the properties is more conspicuous in the composites containing large particle, indicating that both rheological and electrical properties can be improved by controlling the dispersion state at a given filler content.

• Elastomers and Composites
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• v.52 no.2
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• pp.136-142
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• 2017

Using various compositions of thermally conductive inorganic fillers with boron nitride (BN) and aluminum oxide ($Al_2O_3$), solventless UV-curable thermally conductive acrylic pressure sensitive adhesives (PSAs) were prepared. The base of the PSAs consists of 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate, and isobornyl acrylate.The compositions of the thermally conductive inorganic fillers were 10, 15, 20, and 25 phr in case of BN, and 20:0, 15:5, 10:10, 5:15, and 0:20 phr in case of $BN/Al_2O_3$. The adhesion properties like peel strength, shear strength, and probe tack, and the thermal conductivity of the prepared PSAs were investigated with different thermally conductive inorganic filler contents. There were no significant changes in photo-polymerization behavior with increasing BN or $BN/Al_2O_3$ content. Meanwhile, the conversion rate and transmittance of the PSAs decreased and their thermal stabilities increased with increasing BN content. Their adhesion properties were also independent of the BN or $BN/Al_2O_3$ content. The dispersibility of BN in the acrylic PSAs was better than that of $Al_2O_3$ and it ranked the thermal conductivity in the following order: BN > $BN/Al_2O_3$ > $Al_2O_3$.

• Applied Chemistry for Engineering
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• v.31 no.1
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• pp.73-83
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• 2020

As electronic devices become more advanced and smaller, one of the biggest problems to solve is the heat affecting the efficiency and lifetime of instruments. High thermal conductivity materials, in particular, metal or ceramic ones, have been used to reduce the heat generated from devices. However, due to their low mechanical properties and high weight, thermally conductive composites composed with polymers having a light-weight and good mechanical properties as a matrix and carbon materials having high thermal conductivity as a thermally conductive filler have been attracting great attention. To improve the thermal conductivity of the composites, a phonon scattering must be suppressed to move phonon effectively. In this review, we classified researches related to phonon migration and scattering inhibition of carbon/polymer composites, and discussed various methods to improve thermal conductivity.

• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.210-215
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• 2022

Two types of lignin materials with a different surface ionic character were used and polypyrrole layer was introduced on the lignin surface to obtain polypyrrole@lignin and polypyrrole@lignosulfonate composites using a simple chemical oxidation polymerization, reported in a previous article. Polypyrrole was effectively prepared regardless of the lignin type and the resulting composites were investigated using scanning electron microscope (SEM), cyclic voltammetry (CV), and impedance analysis. SEM and CV results showed that the obtained composites retained stable electrochemical properties after introduction of polypyrrole on the lignin surface. Impedance analyses showed that the surface properties of composites were dependent on lignin characteristics. In addition, the composites were embedded in agarose, an gelifying agent, to obtain conductive gels. It was found that the conductive gels possessed an electrical conductivity and also retained stable electrochemical properties, which indicated that the conductive gels might be useful for some applications.

• Polymer Science and Technology
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• v.24 no.1
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• pp.30-37
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• 2013

• Journal of Powder Materials
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• v.9 no.6
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• pp.409-415
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• 2002

In this review the methods for production and processing of isolated or agglomerated nanoscale metal particles embedded in organic liquids (nanosuspensions) and polymer matrix composites are elucidated. Emphasis is laid on the techniques of inert gas condensation (IGC) and high pressure sputtering for obtaining highly porous metal powders ("nanopowder") as well as on vacuum evaporation on running liquids for obtaining nanosuspensions. Functional properties and post-processing are outlined in view of applications in the fields of electrically conductive adhesives and anti-microbially active materials for medical articles and consumer goods.mer goods.

• Korean Journal of Materials Research
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• v.30 no.10
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• pp.522-532
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• 2020

Conductive polymer composites with high electrical and mechanical properties are in demand for bipolar plates of phosphoric acid fuel cells (PAFC). In this study, composites based on natural graphite/fluorinated ethylene propylene (FEP) and different ratios of carbon black are mixed and hot formed into bars. The overall content of natural graphite is replaced by carbon black (0.2 wt% to 3.0 wt%). It is found that the addition of carbon black reduces electrical resistivity and density. The density of composite materials added with carbon black 3.0 wt% is 2.168 g/㎤, which is 0.017 g/㎤ less than that of non-additive composites. In-plane electrical resistivity is 7.68 μΩm and through-plane electrical resistivity is 27.66 μΩm. Compared with non-additive composites, in-plane electrical resistivity decreases by 95.7 % and through-plane decreases by 95.9 %. Also, the bending strength is about 30 % improved when carbon black is added at 2.0 wt% compared to non-additive cases. The decrease of electrical resistivity of composites is estimated to stem from the carbon black, which is a conductive material located between melted FEP and acts a path for electrons; the increasing mechanical properties are estimated to result from carbon black filling up pores in the composites.

• Elastomers and Composites
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• v.48 no.1
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• pp.76-84
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• 2013

The term 'Piezoresistive effect' describes a change in the electrical resistance of the material from deformed to its original shape by the external pressure, e.g., elongation, compression, etc. This phenomenon has various applications of sensors for monitoring pressure, vibration, and acceleration. Although there are many materials which have the piezoresistive effect, rubber (nano)composites with conductive fillers have attracted a great deal of attention because the piezoresistive effect appears at the various range of pressure by controlling the type of filler, particle size, particle shape, aspect ratio of particles, and filler content. Especially one can obtain the composites with elasticity and flexibility by using the rubber as a matrix. This paper aims to review the piezoresistive effect itself, their basic principles, and the various conductive rubber-composites with piezoresistive effect.