• Bulletin of the Korean Chemical Society
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• 제23권3호
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• pp.399-403
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• 2002

The complex of iron(II) tris(3-Br-phen) (3-Br-phen; 3-bromo-1,10-phenanthroline) was prepared as a precursor of electropolymerization and the crystal structure of [Fe(3-Br-phen)3]($PF_6$)2${\cdot}$CH3CN with a distorted octahedral geometry has been investigated. The reductive electropolymerization of $>[Fe(3-Br-phen)3]^{2+}$ complex onto the surface of a glassy carbon electrode and indium tin oxide (ITO) optically transparent electrode were performed in acetonitrile at room temperature. Thin film of poly-$>[Fe(3-Br-phen)3]^{2+}$ formed was adherent, electroactive and stably deposited on a glassy carbon disk electrode. The thin metallopolymeric film formed was also confirmed by absorption spectroscopy.

• Bulletin of the Korean Chemical Society
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• 제33권6호
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• pp.2028-2030
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• 2012

The single-crystal structure of $CaCl_2{\cdot}2C_6H_{12}O_6{\cdot}3H_2O$ was determined with Mr=525.34, a=16.054(7) ${\AA}$, b=7.864(4) ${\AA}$, c=10.909(5) ${\AA}$, ${\beta}=127.894(8)^{\circ}$, V=1086.9(9) ${\AA}^3$, C2, Z=2 and $R$=0.0227 for 1727 observed reflections. The fructose moiety of the complex exists as a ${\beta}$-D-pyranose. The calcium ion is surrounded by eight oxygen atoms, These are arranged in symmetry-related pairs derived from four sugar and two water molecules. Three nonvicinal hydroxyl groups of fructose are involved in calcium binding. All the hydroxyl groups and water molecules are involved in forming an extensive hydrogen-bond network.

• Bulletin of the Korean Chemical Society
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• 제20권4호
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• pp.417-421
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• 1999

The complex, K3[La(TTHA)]5H,O, was prepared and its crystal structure was analyzed by single crystal X-ray diffraction method. In the complex, the La(Ⅲ) ion adopts a ten-coordinate geometry with four nitrogen atoms and six carboxyl oxygen atoms from the same TTHA ligand molecule. Its coordination polyhedron can be described as a distorted bicapped square antiprism. Each [La(TTHA)]3- anion is linked by K+ cations via carboxyl groups of TTHA ligand to form a three dimensional crystal structure. The thermal properties were investigated by TG and DTA techniques in argon atmosphere. The materials resulting from thermal treatment were La(OH)3 and K2O which were identified by powder X-ray diffraction technique.

• Applied Microscopy
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• 제48권4호
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• pp.81-86
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• 2018

The respiratory chain complex forms a supercomplex (SC) in the inner mitochondrial membrane. This complex facilitates the process of electron transfer to produce the proton gradient used to synthesize ATP. Understanding the precise structure of the SC is considered an important challenge. However, it has not yet been reported. The development of a Cryo-electron microscopy (EM) technique provides an effective way to obtain high-resolution micrographs to determine the high-resolution three-dimensional structure of biomolecules. In this brief review, the currently reported Cryo-EM structures of the mammalian respirasome have been described in order to establish a direction for further research in the respiratory system.

• 대한수학회논문집
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• 제26권1호
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• pp.125-133
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• 2011

A new kind of structure is introduced in an even dimensional differentiable Riemannian manifold and some basic properties of this structure is discussed. Also the existence of such structure is shown with an example.

• The Plant Pathology Journal
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• 제28권4호
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• pp.357-363
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• 2012

Several species belonging to the Gibberella fujikuroi species (Gf ) complex are commonly associated with rice and corn, not only causing serious diseases, but also producing fumonisins, a group of mycotoxins harmful to animals and humans. To characterize the population structure of the putative fumonisin-producing Gf complex in Korea, we obtained 276 candidate isolates from rice and corn harvested in 2009 and 2010 by diagnostic polymerase chain reaction with several specific primer sets. Phylogenetic trees were constructed using multilocus sequences (combined RPB2 and EF1A, totaling 1.6 kb) from these isolates. Among the 135 isolates from rice, F. fujikuroi (teleomorph: G. fujikuroi; 59.3%) and F. proliferatum (G. intermedia; 13.3%) were predominant, followed by F. concentricum (5.9%). Additionally, twenty-five (18.5%) rice isolates belonged in a distinct subclade of F. commune, a non-member of the Gf complex. In contrast, F. verticillioides was the most predominant species (38.3%) among the 141 corn isolates, and followed by F. fujikuroi (27.7%), F. proliferatum (14.9%), F. subglutinans (7.1%), and F. concentricum (2.8%). A single mating type (MAT1-1) was found predominantly among the Gf complex isolates examined. Possible distinct subclades were detected within the populations of F. fujikuroi and F. proliferatum; however, this needs further confirmation. This is the first reported population-level characterization of putative fumonisin-producing Gf complex associated with rice and corn in Korea.

• 한국농공학회논문집
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• 제58권3호
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• pp.13-19
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• 2016

Element-focused network analysis method for truss structure is proposed. The propagation process of loads from external loads to connected other elements is similar to that of connections between nodes in accordance with attachment rule in a network. Here nodes indicate elements in a truss structure and edges represent propagated loads. Therefore, the flows of loads in a truss structure can be calculated using the network analysis method, and consequently the structure can also be analyzed. As a first step to analyze a truss structure as a network, we propose a local load transfer rule in accordance with the topology of elements, and then analyze the loads of the truss elements. Application of this method reveal that the internal loads and reactions caused by external loads can be accurately estimated. Consequently, truss structures can be considered as networks and network analysis method can be applied to further complex truss structures.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2005년도 추계학술대회 논문집
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• pp.1159-1164
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• 2005

Seismic analysis methods in use on ground structure are equivalentstatic analysis, response-displacement method and dynamic analysis etc. Equivalentstatic analysis does not considerdynamic effect, and dynamic analysis process is very complex. then 'Urbanrail transit earthquake-resistance design standard (2005.06)' is persuading that analyze by response displacement method that consider enough dynamic effect of ground structure statically. But, It is very complex and difficult to apply response-displacement method in the field. So, modified equivalentstatic analysis or pseudo static analysis that is easy to apply in the field and have rationality of design is practically used. In this study, I try to prescribe the applicable scale of structure and static analysis that have calculative effectiveness about response-displacement method by comparing and analyzing the result of each analysis method according to the scale of urban rail transit' box type concrete structure and by performing seismic analysis that apply modified equivalentstatic analysis, pseudo static analysis and response-displacement method changing the kind of ground, depth of bedrock, size of structure.

• 대한수학회논문집
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• 제37권1호
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• pp.229-257
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• 2022

Let M be a semi-invariant submanifold of codimension 3 with almost contact metric structure (𝜙, 𝜉, 𝜂, g) in a complex space form M_n+1(c), c ≠ 0. We denote by A and R_𝜉 the shape operator in the direction of distinguished normal vector field and the structure Jacobi operator with respect to the structure vector 𝜉, respectively. Suppose that the third fundamental form t satisfies dt(X, Y) = 2𝜃g(𝜙X, Y) for a scalar 𝜃(< 2c) and any vector fields X and Y on M. In this paper, we prove that if it satisfies R_𝜉A = AR_𝜉 and at the same time ∇_𝜉R_𝜉 = 0 on M, then M is a Hopf hypersurface of type (A) provided that the scalar curvature s of M holds s - 2(n - 1)c ≤ 0.

• East Asian mathematical journal
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• 제38권1호
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• pp.43-63
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• 2022

Let M be a semi-invariant submanifold of codimension 3 with almost contact metric structure (φ, ξ, η, g) in a complex space form M_n+1(c). We denote by R_ξ the structure Jacobi operator with respect to the structure vector field ξ and by ${\bar{r}}$ the scalar curvature of M. Suppose that R_ξ is φ∇_ξξ-parallel and at the same time the third fundamental form t satisfies dt(X, Y) = 2θg(φX, Y) for a scalar θ(≠ 2c) and any vector fields X and Y on M. In this paper, we prove that if it satisfies R_ξφ = φR_ξ, then M is a Hopf hypersurface of type (A) in M_n+1(c) provided that ${\bar{r}-2(n-1)c}$ ≤ 0.