• Title/Summary/Keyword: coefficient of $CO_2$

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Influence of High Temperature Deformation Process Variables on the Microstructure and Thermo-physical Properties of a Ni-Fe-Co Alloy (Fe-Ni-Co 합금의 고온 변형 공정 변수와 미세조직 및 열물리적 특성의 상관 관계)

  • Yoon, D.H.;Jung, J.E.;Chang, Y.W.;Lee, J.H.;Lee, K.S.
    • Transactions of Materials Processing
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    • v.21 no.3
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    • pp.207-214
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    • 2012
  • High temperature deformation behavior of a $Ni_{30}Fe_{53}Co_{17}$ alloy, with its extraordinary low coefficient of thermal expansion less than $10{\times}10^{-6}K^{-1}$ at temperatures ranging from room temperature to 673K, was investigated by conducting a series of compression tests. From an empirical processing map, the appropriate working temperature-strain rate combination for optimum forming was deduced to be in the ~1373K, $10^{-2}s^{-1}$ region. This region has a relatively high power dissipation efficiency, greater than 0.36. Furthermore, open die forging of a 100mm diameter billets was performed to confirm the variation of thermo-physical properties in relation to microstructure. The coefficient of thermal expansion was found to increase considerably with increasing the open die forging temperature and decreasing the cooling rate, which in turn provides a drastic increase in the average grain size.

Flow and Heat Transfer Characteristics of $CO_2$/Oil Mixtures in a Circular Tube

  • Kang, Byung-Ha;Lim, Dong-Seop
    • International Journal of Air-Conditioning and Refrigeration
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    • v.16 no.4
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    • pp.117-123
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    • 2008
  • The present study is directed at flow and heat transfer of $CO_2$ and oil mixtures in a circular tube. PAG and POE oils are considered in this study. Flow characteristics of $CO_2$ and oil mixtures have been investigated by flow visualization. Pressure drop has been measured in the range of operating mass flow rate from 0.1 to 0.4 kg/min in a circular tube. Heat transfer characteristics of $CO_2$/oil mixtures have been investigated using a counterflow heat exchanger. In case of pure liquid $CO_2$ as well as $CO_2$ and POE mixtures, flow are seen to be uniform so that $CO_2$ and POE oil are still miscible even at flowing state. However, it is found that $CO_2$ and PAG are not miscible. Pressure drop of $CO_2$/PAG mixtures are much higher than that of $CO_2$/POE mixtures as well as pure $CO_2$ at a fixed mass flow rate. As the concentration of POE oil is increased from 0 to 5 wt%, pressure drop is increased. However, heat transfer rate and heat transfer coefficient of $CO_2$/POE mixtures are much higher than that of $CO_2$/PAG mixtures. The f-factor correlation and Nusselt number correlation for $CO_2$/POE oil mixtures are suggested in this paper.

Experimental Study on Characteristics of Evaporation Heat Transfer and Oil Effect of $CO_2$ in Mini-channels (미세채널 내 이산화탄소의 증발 열전달 특성 및 오일의 영향에 관한 실험적 연구)

  • Lee, Sang-Jae;Kim, Dae-Hoon;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.1
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    • pp.16-22
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    • 2009
  • In order to investigate $CO_2$ heat transfer coefficient and pressure drop by PAG oil concentration during $CO_2$ evaporation, the experiment on evaporation heat transfer characteristics in a mini-channels were performed. The experimental apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiment was conducted for various mass fluxes($300{\sim}800kg/m^{2}s$), heat fluxes($10{\sim}40kW/m^2$) saturation temperatures($-5{\sim}5^{\circ}C$), and PAG oil concentration(0, 3, 5wt%). The variation of the heat transfer coefficient was different according to the oil concentration. With the increase of the oil concentration, the evaporation heat transfer coefficient decreased and the delay of dryout by oil addition was found. Pressure drop increased with the increase of the oil concentration and heat flux, and the decrease of saturation temperature.

Development of Greenhouse Gas Emission Factors from Sewage Sludge Incinerator (하수슬러지 소각장의 온실가스 배출계수 개발)

  • Kim, Seungjin;Kang, Seongmin;Kang, Soyoung;Lee, Jeongwoo;Sa, Jae-Hwan;Park, Seong-Jin;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.5 no.3
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    • pp.209-218
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    • 2014
  • In this study, the researchers have developed the greenhouse gas emission coefficients targeted at sewage sludge incineration plants that treat sewage sludge by incineration. Among the gases emitted from the sewage sludge incineration plants, the greenhouse gases showed concentrations of 6.84% for $CO_2$, 4.51 ppm for $CH_4$, and 86.34 ppm for $N_2O$; calculated into greenhouse gas emission coefficients, these gave $276.06kg\;CO_2/ton$, $0.0066kg\;CH_4/ton$, and $0.35kg\;N_2O/ton$. As the result of calculating the greenhouse gas emission quantity in sewage sludge incineration plants using the greenhouse gas emission coefficients, the gross greenhouse gas emission was $84.63ton\;CO_2\;eq./day$, and the net emission was $23.90ton\;CO_2\;eq./day$; this was $37.52ton\;CO_2\;eq./day$ less than the net greenhouse gas emission that was calculated using the standard values of IPCC, which was $61.42ton\;CO_2\;eq./day$. This difference is probably because unlike the standard values of IPCC, the greenhouse gas emission coefficients of this study reflected the special properties of subject facilities. Thus, it is thought that emission coefficient research on the facilities that deviated from the standard values of IPCC should continue to achieve the development of national greenhouse gas coefficient that reflects the special properties of Korea.

Comparative Molecular Field Analysis of Pyrrolopyrimidines as LRRK2 Kinase Inhibitors

  • Balupuri, Anand;Balasubramanian, Pavithra K.;Cho, Seung Joo
    • Journal of Integrative Natural Science
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    • v.9 no.1
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    • pp.1-9
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    • 2016
  • Leucine rich repeat kinase 2 (LRRK2) is a highly promising target for Parkinson's disease (PD) that affects millions of people worldwide. A three-dimensional quantitative structure-activity relationship (3D-QSAR) analysis was performed on a series of pyrrolopyrimidine-based selective LRRK2 kinase inhibitors. This study was performed to rationalize the structural requirements responsible for the inhibitory activity of these compounds. A reliable 3D-QSAR model was developed using comparative molecular field analysis (CoMFA) technique. The model produced statistically acceptable results with a cross-validated correlation coefficient ($q^2$) of 0.539 and a non-cross-validated correlation coefficient ($r^2$) of 0.871. Robustness of the model was further evaluated by bootstrapping and progressive scrambling analysis. This work could assist in designing more potent LRRK2 inhibitors.

The heat transfer and pressure drop characteristics of $CO_2$ during supercritical region in a horizontal tube (초임계 영역에서 수평관내 $CO_2$ 열전달과 압력강하)

  • 이동건;오후규;김영률;손창효
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.500-508
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    • 2004
  • The heat transfer coefficients during gas cooling process of carbon dioxide in a horizontal tube were investigated. The experiments are conducted without oil in the refrigerant loop. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater, and a gas cooler(test section). The water loop consists of a variable-speed pump, an isothermal tank, and a flow meter. The gas cooler is a counterflow heat exchanger by cooled water flowing in the annulus. The $CO_2$ flows in the horizontal stainless steel tube. which is 9.53mm in O.D. and 7.75mm in I.D. The gas cooler is 6 [m] in length. which is divided into 12 subsections, respectively. The experimental conditions considered in the study are following range of variables : refrigerant temperature is between 20 and $100^{\circ}C$. mass fluxes ranged from 200 to 400kg/($m^2$.s), average pressure varied from 7.5 to 10.0MPa. The main results were summarized as follows : The friction factors of $CO_2$ in the gas cooler show a relatively good agreement with those predicted by Blasius' correlation. The local heat transfer coefficient in the gas cooler has compared with most of correlations, which are the famous ones for forced convection heat transfer of turbulent flow. The results show that the local heat transfer coefficient of gas cooler agrees well with the correlation by Bringer-Smith except that at the region near pseudo critical temperature. while that at the near pseudo critical temperature is higher than the correlation.

A Study on the Prediction Method of Carbonation Process for Concrete Structures of Nuclear Power Plant (원전 콘크리트 구조물의 중성화 진행 예측 기법에 관한 연구)

  • Koh, Kyoung-Tack;Kim, Do-Gyeum;Kim, Sung-Wook;Cho, Myung-Sung;Son, Young-Chul
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.6 no.1
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    • pp.149-158
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    • 2002
  • The carbonation process is affected by both the concrete material properties such as W/C ratio, types of cement and aggregates, admixture characteristics and the environmental factors such as $CO_2$ concentration, temperature, humidity. Based on results of preliminary study on carbonation, this study is to develop a carbonation prediction model by taking account of $CO_2$ concentration, temperature, humidity ad W/C ratio among major factor affecting the carbonation process. And to constitute a model formula which correspond to the mix design of the nuclear power plant, test coefficient that correspond to the design of the nuclear power plant is obtained based on the results of accelerated carbonation test. Also a field coefficient which is obtained based on results of the field examination is included to improve the conformity of the actual structures of nuclear power plant.

Improvement of Reliance on Zinc oxide (ZnO Varistor의 신뢰성 향상)

  • Cho, Hyun-Moo;Lee, Sung-Gap
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.110-113
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    • 2004
  • ZnO varistor ceramics which were fabricated with variation of added of $0.5{\sim}1.0mol%\;Co_3O_4$ sintered at $1150^{\circ}C$. In the specimen added $0.7mol%\;Co_3O_4$, sintered density was $6.03g/cm^3$ and electrical peoperties were superior to any other components. The nonlinear coefficient a was 83, and clamping voltage ratio was 1.35. But, endurence surge current in the specimen added $0.5mol%\;Co_3O_4$ was $7000A/cm^2$, and deviation of varistor voltage was ${\Delta}-3.23%$. As P.C.T and T.C.T environment test were succeed in all specimens, and deviation of varistor voltage in the specimen added $0.6mol%\;Co_3O_4$ was ${\Delta}-0.81%$. All specimens showed a good leakage current property in the High Temperature Continuous Load Test for 1000hr, at $85^{\circ}C$, and variation rate of the varistor voltage was ${\Delta}-2%$.

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Magnetoelectric Characteristics on Layered Ni-PZT-Ni, Co, Fe Composites for Magnetic Field Sensor (자기센서용 Ni-PZT-Ni, Co, Fe 적층구조 소자의 ME 특성)

  • Ryu, Ji-Goo;Jeon, Seong-Jeub
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.2
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    • pp.92-98
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    • 2015
  • The magnetoelectric characteristics on layered Ni-PZT-Ni, Co, Fe composites by epoxy bonding for magnetic field sensor were investigated in the low-frequency range. The ME coefficient of Ni-PZT-Ni, Ni-PZT-Co and Ni-PZT-Fe composites reaches a maximum of $200mV/cm{\cdot}Oe$ at $H_{dc}=110$ Oe, $106mV/cm{\cdot}Oe$ at $H_{dc}=90$ Oe and $87mV/cm{\cdot}Oe$ at $H_{dc}=160$ Oe, respectively. A trend of ME charateristics on Ni-PZT-Co, Ni-PZT-Fe composites was similar to that of Ni-PZT-Ni composites. The ME output voltage shows linearly proportional to ac field $H_{ac}$ and is about 0~150 mV at $H_{ac}$=0~7 Oe and f=110 Hz in the typical Ni-PZT-Ni sample. The frequency shift effect due to the load resistance $R_L$ shows that the frequency range for magnetic field sensor application can be modulated with appropriate load resistance $R_L$. This sample will allow for a low-magnetic ac field sensor in the low-frequency (near f=110 Hz).

Optimization of Extended UNIQUAC Parameter for Activity Coefficients of Ions of an Electrolyte System using Genetic Algorithms

  • Hashemi, Seyed Hossein;Dehghani, Seyed Ali Mousavi;Khodadadi, Abdolhamid;Dinmohammad, Mahmood;Hosseini, Seyed Mohsen;Hashemi, Seyed Abdolrasoul
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.652-659
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    • 2017
  • In the present research, in order to predict activity coefficient of inorganic ions in electrolyte solution of a petroleum system, we studied 13 components in the electrolyte solution, including $H_2O$, $CO_2$ (aq), $H^+$, $Na^+$, $Ba^{2+}$, $Ca^{2+}$, $Sr^{2+}$, $Mg^{2+}$, $SO_4$, $CO_3$, $OH^-$, $Cl^-$, and $HCO_3$. To predict the activity coefficient of the components of the petroleum system (a solid/liquid equilibrium system), activity coefficient model of Extended UNIQUAC was studied, along with its adjustable parameters optimized based on a genetic algorithm. The total calculated error associated with optimizing the adjustable parameters of Extended UNIQUAC model considering the 13 components under study at three temperature levels (298.15, 323.15, and 373.15 K) using the genetic algorithm is found to be 0.07.