• Title/Summary/Keyword: chlorite

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Efficacy of Sodium Hypochlorite and Acidified Sodium Chlorite in Preventing Browning and Microbial Growth on Fresh-Cut Produce

  • Sun, Shih-Hui;Kim, Su-Jin;Kwak, Soo-Jin;Yoon, Ki-Sun
    • Preventive Nutrition and Food Science
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    • v.17 no.3
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    • pp.210-216
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    • 2012
  • The use of suitable sanitizers can increase the quality of fresh-cut produce and reduce the risk of foodborne illnesses. The objective of this study was to compare the washing effects of 100 mg/L sodium hypochlorite (SH) and 500 mg/L acidified sodium chlorite (ASC) on the prevention of enzymatic browning and the growth of microbial populations, including aerobic plate counts, E. coli, and coliforms, throughout storage at $4^{\circ}C$ and $10^{\circ}C$. Fresh-cut zucchini, cucumbers, green bell peppers, and root vegetables such as potatoes, sweet potatoes, carrots, and radishes were used. Compared to SH washing, ASC washing significantly (p<0.05) reduced microbial contamination on the fresh-cut produce and prevented browning of fresh-cut potatoes and sweet potatoes during storage. More effective inhibition of aerobic plate counts and coliforms growth was observed on fresh-cut produce treated with ASC during storage at $10^{\circ}C$. Polyphenol oxidase (PPO) activity of fresh-cut potatoes and sweet potatoes was more effectively inhibited after washing with ASC. The use of 500 mg/L ASC can provide effective antimicrobial and anti-browning treatments of fresh-cut produce, including processed root vegetables.

Antimicrobial Effect of Acidified Sodium Chlorite (ASC) on Whole Croaker

  • Lee, Byung-Doo;Koo, Ja-Heon;Jahncke, Michael L.;Kim, Du-Woon;Chung, Dong-Ok;Eun, Jong-Bang
    • Preventive Nutrition and Food Science
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    • v.13 no.4
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    • pp.266-268
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    • 2008
  • The antimicrobial effect of acidified sodium chlorite (ASC) solution on whole croaker skin was evaluated. Whole croaker skin was treated with ASC (50, 100, 200, 400, and 600 ppm) and distilled water. After 10-minute exposure to 600 ppm ASC, 8% of Gram-negative bacteria survived on the whole croaker sample. Treatment with 50 ppm ASC eliminated all coliforms in the initial load. Immersion treatment with 600 ppm ASC resulted in $1.3\;log\;CFU/cm^2$ greater kill of the initial mesophile loads of control ($2.8\;log\;CFU/cm^2$) than distilled water. Fifty ppm ASC solution produced a 1.6-log reduction of psychrotrophic bacteria. ASC treatment was an effective method for reducing naturally occurring microflora on whole croaker skin.

Utilization of Ligno-cellulosic Biomass(III)-Acid Hydrolysis of Exploded Wood after Delignification (목질계 바이오매스의 이용(제3보)-탈리그닌 처리한 폭쇄재의 산가수분해-)

  • 양재경;장준복;임부국;이종윤
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.29 no.4
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    • pp.18-27
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    • 1997
  • This study was performed to obtained the optimal delignified condition of exploded wood on the acid hydrolysis with sulfuric acid. Wood chips of pine wood(Pinus desiflora), oak wood(Quercus serrata) and birch wood (Betula platyphylla var. japonica) were treated with a high pressure steam (20-30kgf/$\textrm{cm}^2$, 2-6 minutes). The exploded wood was delignified with sodium hydroxide and sodium chlorite, and then hydrolyzed with sulfuric acid. The result can be summerized as follows ; In the exploded wood treated with sodium hydroxide, the optimal concentration of sodium hydroxide was 1% as content of lignin in the exploded wood. Lignin content of exploded wood treated with sodium chlorite was lower then that sodium hydroxide. The maximum reducing sugar yield of exploded wood treated with 1% sodium hydroxide was lower than non-treated exploded wood. In the case of sodium chlorite treated, the maximum reducing sugar yield was hgher than non-treated exploded wood. Sugar composition of acid hydrolysis solution was composed of xylose and glucose residue, and the rate of glucose residue was increased in high pressure condition.

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Controls on Diagenetic Mineralogy of Sandstones and Mudrocks from the Lower Hayang Group (Cretaceous) in the Daegu Area, Korea (대구 부근 하부 하양층군(백악기) 사암과 이암의 속성 광물과 속성 작용의 규제 요인)

  • Shin, Young-Sik;Choo, Chang-Oh;Lee, Yoon-Jong;Lee, Yong-Tae;Koh, In-Seok
    • Journal of the Korean earth science society
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    • v.23 no.7
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    • pp.575-586
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    • 2002
  • Authigenic minerals found in sandstones and mudrocks of the Lower Hayang Group (Cretaceous) in the central part of the Kyungsang Basin are carbonate minerals (calcite, dolomite), clay minerals (illite, chlorite, C/S, I/S and kaolinite), albite, quartz and hematite. Characteristic diagenetic mineral assemblages are as follows: albite-chlorite (including C/S)-hematite in the Chilgog Formation, albite-illite-calcite in the Silla Conglomerate, illite-chlorite-hematite in the Haman Formation and albite-chlorite-dolomite in the Panyawol Formation, respectively. Among clay minerals reflecting the physical and chemical change of the diagenetic process, illite, the dominant clay mineral, occurs in every formation in the study area. Chlorite occurs mainly in green or gray sandstones and mudrocks, or in sandstones and mudrocks of the Chilogok Formation which contains a high content of volcanic materials. Based on the mineral assemblage, diagenetic minerals are strongly related with source rocks. Judging from the illite crystallinity, diagenesis of sandstones and mudrocks in the study area reached the late diagenetic stage or low grade metamorphisim. The diagenetic process was much influenced by intrusion of the Bulguksa granite, content of organic materials, grain size, and depositional environment rather than burial depth.

Alteration Textures and Mineral Chemistry of Margarite from Miwon Area, Chungcheongbukdo (충북미원지역에서 산출하는 마카라이트의 변질양상 및 광물화학)

  • 이승준;안중호;김현철;조문섭
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.1
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    • pp.69-77
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    • 2002
  • Margarite, which occurs in the Unkyori Formation of Miwon area, Chungcheongbukdo, South Korea, was investigated using the petrographic microscope, back-scattered electron images (BSEI), and electron probe microanalyzer (EPMA) to characterize the alteration textures and mineral chemistries. Most margarite crystals are inhomogeneous, and chlorite was commonly observed to occur at the boundaries parallel to the rim of margarite. Cracks occur across the basal plane of the margarite, and margarite is partly replaced by chlorite along the cracks. In additon, muscovite and biotite are intergrown in margarite and chlorite crystals, suggesting that margarite was partially altered to chlorite as well as to muscovite and biotite. Chemical analysis data show that paragonite solid solution in the margarite is approximately 19.6 mol%, but clintonite solid solution is negligible. Margarite crystals in the Unkyori Formation cut or penetrate other metamorphic minerals In the same thin sections and are oriented randomly without any relationship with the foliation of host rocks, indicating that formed as a secondary mineral after peak metamorphism. Furthermore, it seems that hydrothermal fluids associated with the Mesozoic intrusions developed near the sample are closely related to the margarite formation.

Effect of an Aqueous Chlorine Dioxide Generator and Effect on Disinfection of Fresh Fruits and Vegetables by Immersion Washing (이산화염소수 생성기의 생성효율 및 과.채류에 대한 침지 세정 살균효과)

  • Park, Kee-Jai;Jeong, Jin-Woong;Lim, Jeong-Ho;Jang, Jae-Hee;Park, Hee-Joo
    • Food Science and Preservation
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    • v.15 no.2
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    • pp.236-242
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    • 2008
  • We investigated the optimum concentration of a $NaClO_2$ solution and the amount of gaseous $Cl_2$ for production of high yield and purity of aqueous $ClO_2$ by use of a gaseous chlorine-chlorite $ClO_2$ generator. This system produced lower concentrations of chlorine dioxide and is applicable for direct-use in food processing as a cleaner and sanitizer. The concentration of $NaClO_2$ solution and the amount of gaseous $Cl_2$ was varied from 0.01-0.1% and 100-1,000 g/hr, respectively. The concentrations of chlorite, chlorate, FAC (free available chlorine), and chlorine dioxide that were produced increased with increasing concentration of $NaClO_2$ solution and with the amount of gaseous $Cl_2$. The optimum concentration of $NaClO_2$ solution and amount of gaseous $Cl_2$ were 0.1% and 900 g/hr respectively. $ClO_2$ and FAC produced at these concentrations were 882.0 ppm and 8.0 ppm, with no detection of chlorite and chlorate. The yield and purity of $ClO_2$ were 97.0% and 96.0% respectively. Immersion-cleaning experiments showed that this protocol decreased the level of CFU/g by $10^3$- to $10^4$-fold, with a similar effect on fruit.

Spectroscopy of Skarn Minerals in Dangdu Pb-Zn Deposit and Assessment of Skarn Exploration Approaches Employing Portable Spectrometer (당두 연-아연 광상의 스카른 광물의 분광학적 특성과 휴대용 분광계의 스카른 탐사 가능성에 대한 고찰)

  • Jeong, Yong Sik;Yu, Jaehyung;Koh, Sang-Mo;Heo, Chul-Ho
    • Journal of the Mineralogical Society of Korea
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    • v.27 no.3
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    • pp.135-147
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    • 2014
  • This study analyzed spectroscopic methods for characterization of skarn minerals and sphalerite occurring in Dangdu ore deposit, and effectiveness of portable spectrometer in skarn mineral resources exploration is discussed. The spectroscopic analyses identified clinopyroxene, garnet, epidote, calcite, chlorite and sphalerite where spectral curves of clinopyroxene, garnet, epidote, and sphalerite show single mineral spectral characteristics and those of chlorite are in a mixed form with calcite and clinopyroxene. The assessment of spectroscopic analyses based on XRD analysis and microscopic observation reveals that clinopyroxene, garnet, epidote correspond well with more than 80% of detection, but sphalerite, chlorite, and calcite showed below 50% of detection rate. It is expected that skarn deposit exploration using a portable spectrometer is more effective in detection of clinopyroxene, garnet, and epidote whereas spectroscopic data of sphalerite, chlorite, and calcite needs to be utilized as a supplementary data. For the effective detection of chlorite and calcite, their content in the samples needs to be sufficient.

Development of System on the Sustained Production of Chlorine Dioxide Using Polymer Hydrogels (고분자 수화젤을 이용한 이산화염소의 지속적 생성 시스템의 개발)

  • Jeon, Younghyun;Kim, Bumsang
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.173-176
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    • 2012
  • Chlorine dioxide has an excellent ability to sterilize and deodorize and is harmless to humans. However, it is very unstable and explosive as it is highly concentrated, thus its use in the air clean filed has been limited. Therefore, there is a demand to develop the system to produce a low concentration of chlorine dioxide sustainedly. Here, for a first step in the development of the system on the sustained production of chlorine dioxide, the use of polymer hydrogels was investigated. P(MMA-co-HEMA) hydrogel particles were prepared via dispersion photopolymerization and sodium chlorite and citric acid were loaded respectively in the hydrogel particles. When sodium chlorite and citric acid were reacted with not loaded in the hydrogels, rapid production of chlorine dioxide occurred and the concentration of chlorine dioxide decreased over time. However, when sodium chlorite and citric acid were loaded respectively in the hydrogel particles and reacted, chlorine dioxide was produced slowly and sustainedly because the release of sodium chlorite and citric acid from the hydrogels delayed the reaction between them. The result shows that the use of P(MMA-co HEMA) hydrogels has the potential to develop the system on the sustained production of chlorine dioxide.

Studies on the Bleaching of Rice-Straw Chemical Pulp (II) -Two-Stages Bleaching- (볏짚화학펄프의 표백에 관한 연구(제2보) -2단 표백-)

  • 강진하;박성종;박성철
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.3
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    • pp.84-99
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    • 2001
  • This study was carried out to acquire basic data necessary for the use of rice-straw chemical pulp. It investigated the proper bleaching conditions when rice-straw chemical pulp(alkaline sulfite-${Na_2}{S_2}{O_4}$) was bleached using the various kinds of bleaching agents by the two-stages bleaching methods. And, physical properties of pulps bleached with eight kinds of two-stages bleaching methods were tested. The results of this study were as follow; 1. The first-stage bleaching was conducted under the proper conditions with chlorine(C). And then, the proper conditions related to the calcium chlorite(H), hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of CH stage were determined to be 0.3% concentration of calcium chlorite, $30^{\circ}C$ of reaction temperature and 20min. of reaction time. For CP stage, the proper conditions of concentration of hydrogen peroxide, reaction temperature and reaction time were 1.5%, $60^{\circ}C$ and 90min., respectively. And for CY stage, the proper conditions were 0.5% concentration of sodium hydrosulfite, $40^{\circ}C$ of reaction temperature and 90min. of reaction time. 2. The first-stage bleaching was conducted under the proper conditions with chlorine dioxide(D). And then, the proper conditions related to the calcium chlorite(H), hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of DH stage were determined to be 0.5% concentration of calcium chlorite, $25^{\circ}C$ of reaction temperature and 5min. of reaction time. For DP stage, the proper conditions of concentration of hydrogen peroxide, reaction temperature and reaction time were 1.0%, $70^{\circ}C$ and 90min., respectively. And for DY stage, the proper conditions were 0.3% concentration of sodium hydrosulfite, $50^{\circ}C$ of reaction temperature and 20min. of reaction time. 3. The first-stage bleaching was conducted under the proper conditions with calcium chlorite(H). kAnd then, the proper conditions related to the hydrogen peroxide(P) and sodium hydrosulfite(Y) bleaching as the second-stage bleaching were investigated. The proper conditions of HP stage were determined to be 0.3% concentration of hydrogen peroxide, $30^{\circ}C$ of reaction temperature and 60min. of reaction time. For HY stage, the proper conditions of concentration of sodium hydrosulfite, reaction temperature and reaction time were 2.5%, $60^{\circ}C$ and 30min., respectively. 4. When the rice-straw chemical pulps were bleached with eight kinds of two-stages bleaching methods in the proper conditions mentioned above, respectively, the final brightnesses after CH, CP, CY, DH, DP, DY, HP, and HY bleachings were 62.0, 74.3, 61.4, 58.9, 66.9, 62.9, 50.4 and 60.1, respectively. And strengthes of pulps bleached with DP and DH methods were comparatively higher than those of pulps bleached with other bleaching methods.

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Clay Mineral Composition of the Soils Derived from Residuum and Colluvium (잔적 및 붕적모재 토양의 점토광물 특성구명)

  • Zhang, Yong-Seon;Sonn, Yeon-Kyu;Jung, Sug-Jae;Lee, Gye-Jun;Kim, Myung-Sook;Kim, Sun-Kwan;Lee, Ju-Young;Pyun, In-Hwan
    • Korean Journal of Soil Science and Fertilizer
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    • v.39 no.5
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    • pp.245-252
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    • 2006
  • This experiment was conducted to investigate the distribution and compositions of clay mineral and to replenish the soil classification system in Korea. Soil layer samples were collected from 26 residuum and colluvium soil series out of 390 soil series in Korea, and then analyzed for soil physical and chemical characteristics, mineral and chemical compositions of clay in B horizon soils. Major clay minerals of residuum and colluvium were illite and chlorite in soils originated from the sedimentary rock such as limestone, shale, sandstone and conglomerate; quartz and kaolin in soils originated from rhyolite, neogene deposits, porphyry and tuff; and kaolin and quartz in the soils originated from granite, granite gneiss and anorthosite. Clay minerals in Korean soils were divided into 4 groups: mixed mineral group(MIX) mainly contained with illite, kaolin and vemiculite; kaolin group(KA) with kaolin and illite; chlorite group(CH) with chlorite and illite; and smectite group(SM) with kaolin, illite and smectite. The most predominant clay mineral group was kaolin group(KA) with kaolin and illite; an mixed mineral group(MIX) with illite, kaolin and vemiculite. Cation exchange capacity (CEC) of clay was low in the soils mainly composed with MIX and KA groups and silica-alumina molar ratio of clay was high in the soils composed with SM group