• Title/Summary/Keyword: chlorine content

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Corrosion Control in Water Pipes by Adjusting the Corrosivity of Drinking Water : Effect and impact of the Corrosion Inhibitor (수돗물 부식성 제어를 통한 수도관 부식방지 : 부식억제제별 효과와 영향에 대한 분석)

  • Park, Young-Bog;Park, Ju-Hyun;Park, Eun-Hee;Lee, Jin-Suk;Kim, Hyen-Ton;Choi, Young-June;Chung, Hyen-Mi;Huh, Yu-jeong;Choi, In-cheol
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.303-310
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    • 2016
  • The tap water used in Seoul was found to be corrosive. Its corrosivity was effectively reduced by that the additions of alkali agent such as NaOH, $Ca(OH)_2$ and corrosion inhibitor such as $H_3PO_4$. For the corrosion test, carbon steel pipe 50 m long was exposed to the drinking water produced by a pilot plant at $36.5^{\circ}C$, similar to the existing process where it takes about 20 minutes to reduce the initial chlorine content of 0.5 mg/L to 0.05 mg/L. $CO_2$ and $Ca(OH)_2$ was added not only to control the Langelier index (LI) above -1.0 and but also, to increase the duration time of residual chlorine by about 6 times. The persistence effect of residual chlorine was in the order of $H_3PO_4$ > $Ca(OH)_2$ > NaOH. Measurements of weight loss showed that corrosion inhibition was effective in order of $Ca(OH)_2$ > $H_3PO_4$ > NaOH > no addition, where the concentrations of $Ca(OH)_2$ and phosphate were 5 ~ 10 mg/L (as $Ca^{2+}$) and 1 mg/L (as $PO{_4}^{3-}$), respectively.

Quantitative structure activity relationship (QSAR) between chlorinated alkene ELUMO and their chlorine

  • Tang, Walter Z.;Wang, Fang
    • Advances in environmental research
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    • v.1 no.4
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    • pp.257-276
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    • 2012
  • QSAR models for chlorinated alkenes were developed between $E_{HOMO}$ and their chlorine and carbon content. The aim is to provide valid QSAR model which is statistically validated for $E_{LUMO}$ prediction. Different molecular descriptors, $N_{Cl}$, $N_C$ and $E_{HOMO}$ have been used to take into account relevant information provided by molecular features and physicochemical properties. The best model were selected using Partial Least Square (PLS) and Multiple Linear Regression (MLR) led to models with satisfactory predictive ability for a data set of 15 chlorinated alkene compounds.

A study for the Quality Depending on Sanitization and Storage Method of Raw Vegetables in Foodservice Operation (단체급식소에서 이용되는 일부 생채소의 소독방법 및 저장에 따른 품질연구)

  • Kim Heh-Young
    • Korean journal of food and cookery science
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    • v.20 no.6 s.84
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    • pp.684-694
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    • 2004
  • The purpose of this study was to estimate the microbial and physicochemical quality of some raw vegetables and suggest safer methods of sanitization and storage for foodservice operations. Three sanitization methods were utilized during pre-preparation (tap water, chlorine water and electrolyzed water). Leek and Chicory were monitored as ingredient, with different storage temperatures $(3,\;10^{\circ}C)$ and periods (1, 2, 3, 4 and 7 days). The largest reduction in the microbial counts was shown with the electrolyzed water and for the case before immersion in chlorine water, performing a first washing was more effective in reducing the microbial counts than with no washing. The results showed that the storage temperature, pH, moisture content and microbial loads were important factors affecting the quality of vegetables.

Bleaching of Hardwood Kraft Pulp by Xylanase Pretreatment

  • Cho, Nam-Seok
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.4
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    • pp.65-71
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    • 1999
  • This study was carried out to investigate the effect of xylanase pretreatment of the unbleached hardwood kraft pulp during the conventional Chlorine-Extraction- Hypochlorite (CEH) bleaching on pulp property. Optimum bleaching condition was evaluated by using Novozym produced from the fungus Humicola insolens. Also the effect of chelating agent prior to enzyme treatment was analyzed. The kappa number of enzymatic bleached pulp at the enzyme charge 10 IU/ml was slightly similar to that of bleached pulp without enzyme. By enzyme treatment, the chlorine charge in conventional CEH bleaching process of hardwood KP could be reduced by 17%, while no adverse effect on pulp yield and strength was. The optimum condition for enzyme pretreatment was 10 IU/ml xylanase charge, 3 to 4 hrs treatment, and 2% pulp consistency. In sugar composition in the enzyme pretreated pulp, arabinose and mannose were not much different, but more xylose was retained. This high content of hemicellulose in pulp seems to play an important role in pulp properties. The pulp pretreatment by chelating agent prior to enzyme treatment could improve the enzyme activity and enhance the bleaching effect at 0.2% diethylenetriamine pentaacetic acid (DTPA) charges.

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Mechanical Properties of Concrete Containing Blast Furnace Slag according to CBS Dust Replacement Ratio (CBS Dust 치환율에 따른 고로슬래그 다량치환 콘크리트의 역학적 특성)

  • Sin, Se-Jun;Han, Jun-Hui;Lee, Young-Jun;Lee, Dong-Joo;Lee, Jun-Seok;Han, Min-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2019.05a
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    • pp.38-39
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    • 2019
  • Mechanical properties of concrete containing furnace slag according to the CBS Dust Replacement Ratio were analyzed. The experimental study found that the compressive strength was excellent in the early age when the CBS Dust was replaced, and the drying shrinkage was excellent, and the replacement of CBS Dust 5% on the concrete containing the furnace slag would have a positive effect.

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Solution-based fabrication of germanium sulphide doped with or without Li ions for solid electrolyte applications

  • Jin, Byeong Kyou;Cho, Yun Gu;Shin, Dong Wook;Choi, Yong Gyu
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.110-113
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    • 2012
  • Ge-S and Li-Ge-S powders were synthesized via solution-based process in order to employ chalcogenide-based solid electrolyte for use in Li secondary batteries. GeCl4 and thioacetamide in combination result in Ge-S powders of which major crystalline phase becomes GeS2 where the tetragonal and orthorhombic phases coexist after heat treatment. A chemical treatment using NaOH brings about the reduction of chlorine in the powders obtained. However, the heat treatment at 300 ℃ is more effective in minimizing the chlorine content. When lithium chloride is used as the precursor of Li ions, the LiCl powders are agglomerated with an inhomogeneous distribution. When Li2S is used, the Li-Ge-S powders are distributed more uniformly and the orthorhombic GeS2 phase dominates in the powders.

Electrochemical Generation of Chlorine Dioxide Using Polymer Ion Exchange Resin (고분자 이온교환수지를 이용한 의료.식품용 멸균제 이산화염소의 전기화학분해 발생)

  • Rho, Seung Baik;Kim, Sang Seob
    • Applied Chemistry for Engineering
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    • v.23 no.1
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    • pp.86-92
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    • 2012
  • A characteristic study of chlorine dioxide generation by the electrolysis system was performed after chlorite ($ClO_2^-$) is adsorbed from sodium chlorite by a polymer ion exchange resin. A strongly basic anion exchange resin was used and a Ti plate coated with Ru and Ir was used as an electrode. Various parameters such as reaction stirring velocity, reaction temperature, chlorine dioxide product concentration, ion exchange resin content and product maker type for the adsorption quantity in the chlorite adsorption of ion exchange resin were investigated and found the ion exchange resin with the maximum adsorption quantity. A generation trend of chlorine dioxide was observed by the electrolysis system and optimum conditions on the desired value were found using response surface design of DOE (Design of Experiments). The strongly basic anion exchange resin with the maximum adsorption quantity was SAR-20 (TRILITE Gel type II) and the adsorption quantity was around 110 mg/IER (g). Observed generation optimum conditions of chlorine dioxide were constant-current (electrode area base; $A/dm^2$) and flow rate of $N_2$ gas (4.7 L/min) at the desired value of sterilization (900~1000 ppm, 1 h).

Study on Sodium, Patassium Content in Diet and of Blood Serum of Toxemic Pregnant Women (임신중독증(姙娠中毒症)의 식이(食餌)와 혈청중(血淸中)의 나트륨, 칼륨함량(含量)에 관(關)한 연구(硏究))

  • Kim, Mi-Kyung;Woo, Soon-Im;Chun, Sae-Youl
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.11 no.4
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    • pp.25-30
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    • 1982
  • The present study was carried out to investigate the relationship between the patients with toxemia of pregnancy and sodium, potassium and chlorine content in their blood serum and the intake diet. The author analyzed or titrated the concentration of serum and diet electrolytes for the antenatal and gynecologic inpatients (19 normal and 17 toxemic pregnant women ranged 23 to 32 years old) of the Han gang sacred Heart Hospital in Seoul and also determined their daily salt intake. The results obtained can be summarized as follows. 1. In the patients with toxemia of pregnancy mean sodium concentration in serum $(147.2{\pm}11.0mEq/L\;(338.5mg/dl)$ was greater than that of normal pregnant women (140 mEq/L corresponding to 322mg/dl) 2. In the toxemic pregnant women serum chlorine level (mean $113.4{\pm}5.6 mEq/L$ corresponding to 402.5mg/dl) showed the increase of 9.9 mEq /L(36.9 mg/dl) when compared to mean value of normal pregnant women(103.5mEq/L corresponding to 365.6mg/dl). 3. Mean potassium content in pregnant women with toxemia($4.59{\pm}0.7mEq/L$ corresponding to 17.9mg/dl) was similar to that of normal pregnant women(4.2mEq/L corresponding to 16.3mg/dl). 4. It was found that the salt content detected in the diet of toxemic pregnant women (mean $20.84{\pm}2.1g/day$) was greater than daily mean salt intake of normal pregnant women (19g).

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Reinforcing Performance of Networked Silicas in Silica-filled Chloroprene Rubber Compounds

  • Ryu, Changseok;Yang, Jae-Kyoung;Park, Wonhyeong;Kim, Sun Jung;Kim, Doil;Seo, Gon;Kim, Wook-Soo;Ahn, Ki Woong;Kim, Beak Hwan
    • Elastomers and Composites
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    • v.54 no.1
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    • pp.40-53
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    • 2019
  • The physical properties of chloroprene rubber (CR) compounds reinforced with networked silicas were investigated by comparing them to those reinforced with conventional silica to observe the effect of the organic connection bonds combining silica particles on their cure, tensile, and aging performance. The introduction of networked silica to CR increase in silica content to 80 phr in rubber, while the content of conventional silica was limited to 60 phr. The CR compounds reinforced with networked silica showed higher resistance to combustion. The gradual increases in delta torque, Mooney viscosity, and modulus of silica-filled CR compounds with silica content were mainly attributed to the specific interaction between the chlorine atoms of CR and the hydroxyl groups of silica. The CR compounds reinforced with networked silica showed low compression set and heat build-up and maintained their high modulus even after thermal, oil, and ozone aging.

STUDIES ON THE FRAGILITY OF TOBACCO RAW MATERIAL (잎담배의 부스러짐 특성에 관한 연구)

  • 김기환;유광근;주영석;최영현;김병구
    • Journal of the Korean Society of Tobacco Science
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    • v.8 no.1
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    • pp.13-21
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    • 1986
  • The fragility, which express the fineness index, increased linearly with the moisture content for various tobacco shreds and showed a high correlation to the moisture content. Then, fineness index (FIs) at reference moisture content(l2.5%) was obtained by following equation. FIs=FIm+A(12.5-Mm) A" denote the gradient of simple linear regression equation between the fineness index and moisture content. FIm; the fineness index measured at the standard moisture content(12.5%). The characteristics of fragility concerning with some kinds of tobacco raw materials, stalk position, moisture content and storaged time were investigated. The following results were obtained. 1. The moisture content range of less fragile of tobacco raw material was from 16% to 20%. whereas the rolled process sheet tobacco was from 12% to 16%. 2. The Bright yellow and the paper process sheet tobacco were less fragile than that of the other tobacco raw materials. 3. The leaves were more distant from middle stalk position, and its become more fragile. 4. Physical properties of the storaged tobacco leaves were determined as a function of each storageunction of each storage time. The long-term storaged leaves(more than 3 years) were slightly lighter weight, more fragility and lower equilbrium moisture content than thos of the mid-term storaged leaves.(less than 3 years). 5. Contents of chemical component of the storaged leaves were determined every storage time. The long-term storaged leaves were slightly lower content of nicotine and chlorine than those of mid-term storaged leaves, but contents of crude fiber, total ash and calcium were increased significantly.

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