• Title/Summary/Keyword: chemical profile

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Chloride Penetration Properties of Portland Cement Mortar Substituted with Anion Exchange Resin Powder (음이온교환수지 분말이 치환된 포틀랜드 시멘트 모르타르의 염소이온 침투 특성)

  • Lee, Yun-Su;Lim, Seung-Min;Park, Jang-Hyun;Jung, Do-Hyun;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.20 no.1
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    • pp.1-9
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    • 2020
  • Chloride ion, which penetrates into the cement composites from the outside, generally diffuses by the concentration gradient. Chloride ions are adsorbed by the chemical reaction with cement hydrates. Recent studies have shown that anion exchange resin (AER) powder can effectively adsorb the chloride ion in the cement composites, and thus, the cement composites containing AER have a high chloride adsorption capacity and a good resistance for chloride penetration. In this study, the chloride adsorption ability of the AER powder was investigated under the conditions of distilled water and calcium hydroxide saturated solution to determine if the AER powder is less effective to increase the chloride adsorption ability after grinding process. The chloride adsorption ability of AER powder was compared with the previous research about the chloride adsorption of AER bead. In addition, the compressive strength, chloride diffusion coefficient (using NT Build 492 method), and the chloride profile of cement mortar substituted with AER powder were investigated. There was no decrease in the chloride adsorption capacity of AER powder but increase in the kinetic property for chloride adsorption after the grinding process. The AER powder could absorb the chloride ion in the mortar quickly, and showed better chloride ion adsorption ability than the cement hydrates.

Essential Oil Isolated from Iranian Yarrow as a Bio-rational Agent to the Management of Saw-toothed Grain Beetle, Oryzaephilus surinamensis (L.) (머리대장가는납작벌레의 합리적 방제 물질로 이란 서양가새풀 정유의 살충효과 평가)

  • Ebadollahi, Asgar
    • Korean journal of applied entomology
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    • v.56 no.4
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    • pp.395-402
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    • 2017
  • Overuse of synthetic pesticides caused negative side-effects such as environmental contamination, development of insect pests' resistance, and effects on non-target organisms. Plant origin substances without/or with low mammalian toxicity have been considered as promising alternatives to the synthetic pesticides. Fumigant toxicity of the essential oil of Iranian Yarrow, Achillea millefolium L., was investigated against a cosmopolitan stored-product insect pest: saw-toothed grain beetle (Oryzaephilus surinamensis L.). Chemical profile of this essential oil was studied by Gas Chromatography-Mass Spectrometry. Tested concentrations were significantly effective to the mortality of insect pest. A positive correlation between essential oil concentrations and pest mortality were realized. LC50 value (lethal concentration needed to 50% mortality) was achieved as $17.977(16.195{\pm}20.433){\mu}l/l$ air. The main components were 1,8-Cineole (13.17%), nerolidol (12.87%), ${\alpha}$-cubebene (12.35%), artemisia ketone (6.69%), ${\alpha}$-terpineol (5.27%), alloaromadendrene oxide (4.71%) and borneol (3.99%). Terpenic compounds including monoterpene hydrocarbons (8.19%), monoterpenoids (44.23%), sesquiterpene hydrocarbons (21.69%) and sesquiterpenoids (22.24%) were 96.35% of the total identified compounds. Results indicated that the terpene-rich A. millefolium essential oil may be considered as a safe bio-agent in the O. surinamensis management.

Sustained Release of Proteins Using Small Intestinal Submucosa Modified PLGA Scaffold (SIS로 개질된 PLGA 담체에서의 단백질의 서방화)

  • Ko, Youn-Kyung;Choi, Myung-Kyu;Kim, Soon-Hee;Kim, Geun-Ah;Lee, Hai-Bang;Rhee, John-M.;Khang, Gil-Son
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.199-205
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    • 2008
  • In this study, we fabricated poly (lactide-co-glycolide) (PLGA) scaffold modified with small intestinal submucosa (SIS) as a drug delivery matrix of bioactive molecules. SIS derived from the submucosa layer of porcine intestine has been widely used as biomaterial because of low immune response. PLGA scaffold was prepared by the method of solvent casting/salt leaching. Novel composite scaffolds of SIS/PLGA were manufactured by simple immersion method of PLGA scaffold in SIS solution under vacuum. SEM observation shows that PLGA and SIS/PLGA scaffolds have interconnective and open pores. Especially, SIS/PLGA scaffold showed that micro-sponge of SIS with interconnected pore structures were formed in the pores of PLGA scaffold. In order to assay release profile of proteins, we manufactured FITC conjugated BSA loaded PLGA and SIS/PLGA scaffold. And the release amount was identified by fluorescence intensity using the fluorescence spectrophotometer. The initial burst of BSA containing SIS/PLGA scaffolds was lower than that of PLGA scaffolds resulting in constant release. And release of BSA in SIS/PLGA scaffold was fast and incremental because of the increased content of BSA. In conclusion, we confirmed that penetrated SIS solution prevented the initial burst of BSA and PLGA modified with SIS scaffold is useful as protein carriers with controlled release pattern.

Characterization of the Germinated Rices to Examine an Application Potentials as Functional Rice Processed Foods (기능성 쌀가공식품 원료료의 활용가능성 검토를 위한 발아미의 특성조사)

  • Kang, Mi-Young;Lee, Yeon-Ri;Nam, Seok-Hyun
    • Korean Journal of Food Science and Technology
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    • v.35 no.4
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    • pp.696-701
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    • 2003
  • Rice seeds of 4 cultivars including Whachung and Nampung, of the non-waxy rice cultivars, and Shinsunchalbyeo and Whachungchabyeo, of the waxy rice cultivars, were germinated at $27^{\circ}C$ for 3 days to compare the changes in some physico-chemical properties of the starch granules and the starch-hydrolysing enzyme activities during germination, respectively. With the starch granules, the amount of long glucose chains from amylose molecules were reduced in the non-waxy rices, while the chain length increased in the waxy rices. In the distribution profile of the glucose chain length from amylose molecules, we could observed that the chain length with DP (degree of polymerization) ranged 33 to 66 increased with the decreasing rate of the chain length with that above 130, regardless of the waxiness of rices. In addition, we observed that in contrast to a increase in chain length with DP ranged 14 to 33, the amount of short chains from A chain fraction decreased. Germination induced slight reduction in the polymerization rate of starch granules, and decrease in both initiation and termination temperatures for the gelatinization. ${\alpha}-Amylase$ activity of rices germinated for 3 days found to he higher than that of malt. Especially, the activity of Shinsunchalbyeo was revealed to be highest, about two fold higher than that of malt. In contrast, ${\beta}-amylase$ of the waxy rice found to be considerably less active than malt, although the waxy showed prevalent activity as compared to the non-waxy rices.

Development of an electron source using carbon nanotube field emittes for a high-brightness X-ray tube (탄소나노튜브를 이용한 고휘도 X-선원용 전자빔원 개발)

  • Kim, Seon-Kyu;Heo, Sung-Hwan;Cho, Sung-Oh
    • Journal of the Korean Vacuum Society
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    • v.14 no.4
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    • pp.252-257
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    • 2005
  • A high-brightness electron beam source for a microfocus X-ray tube has been fabricated using a carbon-nanotube (CNT) field emitter. The electron source consists of cathode that includes a CNT field emitter, a beam-extracting grid, and an anode that accelerates that electron beam. The microfocus X-ray tube requires an electron beam with the diameter of less than 5 $\mu$m and beam current of higher than 30 $\mu$A at the position of the X-ray target. To satisfy the requirements, the geometries of the field emitter tips and the electrodes of the gun was optimized by calculating the electron trajectories and beam spatial profile with EGUN code. The CNT tips were fabricated with successive steps: a tungsten wire with the diameter of 200 $\mu$m was chemically etched and was subsequently coated with CNTs by chemical vapor deposition. The experiments of electron emission at the fabricated CNT tips were performed. The design characteristics and basic experimental results of the electron source are reported.

Isolation and Identification of Low Molecular Phenolic Antioxidants from Ethylacetate Layer of Korean Black Raspberry (Rubus coreanus Miquel) Wine (복분자(Rubus coreanus Miquel) 와인의 에틸아세테이트층으로부터 저분자 페놀성 항산화 화합물의 단리·동정)

  • Kim, Seong-Ja;Lee, Hyoung-Jae;Park, Keun-Hyung;Rhee, Chong-Ouk;Lim, Ik-Jae;Chung, Hee-Jong;Moon, Jae-Hak
    • Korean Journal of Food Science and Technology
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    • v.40 no.2
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    • pp.129-134
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    • 2008
  • Five antioxidative active substances were isolated from the EtOAc layer (20 g/56.2 g) of Korean black raspberry (Rubus coreanus Miquel) wine (11 L, black raspberry 15.7 kg fresh wt. eq.) by various column chromatography and high performance liquid chromatography (HPLC). Proton nuclear magnetic resonance ($^1H$-NMR) spectroscopy and gas chromatography Electro Ionization-Mass Spectrometry (GC-EI-MS) identified these as 4-hydroxybenzoic acid (1, 0.1 mg), 3,4-dihydroxybenzoic acid (2, 0.3 mg), 4-(2-hydroxyethyl)-phenol (3, 0.6 mg; tyrosol), pyrocatechol (4, 0.3 mg), 3,4,5-trihydroxybenzoic acid ethyl ester (5, 0.6 mg; ethyl gallate). The presence of 1 and 2 in Korean black raspberry has previously been reported. However, the presence of 3-5 in Korean black raspberry, and the identification of 1-5 from the Korean black raspberry wine have never before been reported.

A Study on the Characteristics of Fluvio Marine Soils developed in the West South Coastal area (서남해안(西南海岸) 간석지토양(干潟地土壤)의 특성(特性)에 관(關)한 조사연구(調査硏究))

  • Shim, Jae-Hwan;Jung, Jung-Hwa;An, Yeul
    • Korean Journal of Soil Science and Fertilizer
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    • v.22 no.4
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    • pp.280-284
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    • 1989
  • The soil texture and the physico-chemical characteristics of 442,000ha reclaimable tide land in the south-western of korean peninsular were analysed. The subsidence which may occur as the soil ripened was studied. The results were as follows : 1. Among the 257,000ha of existing reclaimed tidal land 53.0% was tine silty soil and 36.0% coarse silty, 6.0% coarse loamy and 5.0% sandy soils, respectively. 2. Out of the total 442,000ha of reclaimable tidal land, 51.0% was coarse silty soil, and 20% sandy, 15.0% coarse loamy and 14.0% fine silty textural family, respectively. The coarse silty deposits were mainly distributed in the Gyeong gi and Jeonnam coast, while the coarse deposits(Coarse Loamy-sandy) exist in the Jeonbuk coastal area, but in the Chungnam areas there were various textural grades. 3. Reclaimable tidal Land in the south-western part of the peninsular was Classified into saline and alkaline soil. Electric Conductivity in saturation extract was extremely high that was 46~51 mmhos/cm, E.S.P was more than 25% and pH was ranged around 7.5~8.0 4. Reclaimed to cultivated field the subsidence reclaimable tide land to be expected when was about 18% in Soil and 21% in Sicl soils calculated down to 1.25m of the profile.

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Characterization of Isoflavones from Seed of Selected Soybean (Glycine max L.) Resources Using High-Resolution Mass Spectrometry (고해상도 질량 분석을 이용한 대두(Glycine max L.) 우수자원 종자의 이소플라본 특성 평가)

  • Lee, So-Jeong;Kim, Heon-Woong;Lee, Suji;Na, Hyemin;Kwon, Ryeong Ha;Kim, Ju Hyung;Yoon, Hyemyeong;Choi, Yu-Mi;Wee, Chi-Do;Yoo, Seon Mi;Lee, Sang Hoon
    • The Korean Journal of Food And Nutrition
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    • v.33 no.6
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    • pp.655-665
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    • 2020
  • In this study, chemical information on a total of 20 individual compounds was constructed to identify isoflavones from the previous reports related with used parts(seeds, leaves, stems, pods) and products of soybean(Glycine max L.). Through constructed library and UPLC-DAD-QToF/MS analysis, a total of 19 individual isoflavones including aglycones, glucosides, acetylglucosides and malonylglucosides as major compounds was identified and quantified from 14 selected soybean seeds. Among them, genistein 7-O-(2"-O-apiosyl)glucoside and genistein 7-O-(6"-O-apiosyl)glucoside(ambocin) were identified tentatively as novel compounds in soybean seeds. Besides, among malonylglucosides, glycitein 4'-O-(6"-O-malonyl)glucoside was estimated for the first time. Total isoflavone contents were distributed from 240.21 to 445.21(mg/100 g, dry matter) and 7-O-6"-O-malonylglucosides were composed of 77.8% on total isoflavone as well as genistein derivatives were confirmed as major class. It was considered importantly that the development of isoflavone-rich varieties was necessary to strengthen their effects such as anti-inflammation, anti-cancer and menopause mitigation. The qualitative and quantitative data presented precisely in this study could be help to select and breed isoflavone-rich varieties. Furthermore, their basic isoflavone profile is expected to be applied to estimate the change of isoflavone conjugates on bioavailability after soy food supplements.

Initial Operating Condition of Membrane Bioreactor with PVDF Hollow Fiber and Permeate Reuse (PVDF 중공사막을 이용한 막생물반응기의 초기 운전조건 설정 및 여과수 재활용)

  • Shin, Choon-Hwan;Kang, Dong-Hyo;Park, Hae-Sik;Cho, Hyun-Kil
    • Clean Technology
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    • v.16 no.1
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    • pp.39-45
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    • 2010
  • In this paper, 4 bundle modules of PVDF hollow fiber membrane from Woori Tech company (Korea) were manufactured in a treatment capacity of 10 ton/day. A membrane bioreactor (MBR) pilot plant was installed at Sooyoung Wastewater Treatment Plant in Busan. An alternating aeration process was selected to avoid the concentration profile of suspended solid (SS) in the MBR. For stable operation, raw wastewater with mixed liquor suspended solid (MLSS) of about 1,000 ppm, which was in-flowed from the aeration tank of the wastewater treatment plant, was fed and filtered through the pilot plant. Subsequently the pilot plant were washed three times with washing water: once with ethanol solution, once with a solution of 5% NaOCl, and finally with washing water. After the chemical washing, the remaining water in the MBR was fed into the pilot plant. As a result, the SS removal efficiency was found to be more than 99.9%. The amount of filtrate with the aeration tank influent decreased by 16%, compared with that from the initial conditions, giving rise to 30% increase in the suction pressure. These results were used to set up continuous operation conditions. The results from the continuous operation with influent MLSS of 1,900 mg/L showed that the SS removal efficiency was about 99.99% and that the amount of filtrate and the suction pressure were $42{\sim}52L/m^2$ and 16~20 cmHg, respectively, indicating stable operation of the pilot plant. However, for the reuse of wastewater, methods need to be sought to avoid growth of algae which affects the SS removal efficiency at inlet and outlet of the permeate tank.

Ziziphus spina christifor Sustainable Agroforestry Farming in Arid Land of Khartoum State of Sudan

  • Mustafa Abdalla Nasre Aldin;Hussein Alawad Seid Ahmed;Mohamed El Mukhtar Ballal;Adil Mahgoub Farah
    • Journal of Forest and Environmental Science
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    • v.39 no.1
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    • pp.20-26
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    • 2023
  • Cow pea (Vigna unguiculata) was intercropped with Ziziphus spina-christi as summer forage in two consecutive seasons of 2017 and 2018. The aims to find out suitable agroforestry practice for saline soils of Khartoum State. And to investigate effect of tree spacing on forage biomass yield under semi -irrigated systems. Completely randomized block design with 3 replicates was conducted for this trial. Thus Z.spina-christi that fixed at 4×4 m was intercropped with cowpea at 1 m and 1.5 m spacing from trees trunk. Tree growth parameters were measured in terms of tree height, tree collar diameter, tree crown diameter and fruit yield per tree. While crop were parameters were determined in terms of plant height, number of plant, forage biomass yield per ha and land equivalent ratio. Soil profile of 1×1 m and 1.5 m depth was excavated and its features were described beside its chemical and physical properties were analyzed for 0-10 cm, 0-30 cm, and 30-60 cm and 60-100 cm layers. The results revealed that soil pH, CaCO3, SAR, ESP, and EC ds/m were increased by increasing soil depths. Meanwhile tree growth in terms of tree height was significant in the first season 2017 when compared with tree collar diameter and tree crown diameter. Also significant differences were recorded for tree growth when compared with sole trees in the second season in 2018. Tree fruit showed marked variations between the two seasons, but it was higher under intercropping particularly at ZS2. Crop plant height was highly significant under sole cropping than intercropping in first season in 2017. In contrast forage biomass yield was significant under intercropping in ZS1 and ZS2 treatments. Land equivalent ratio was advantageous under this agroforestry system particularly under ZS2. Thus it recorded 5 and 9 for ZS2 in the two consecutive seasons respectively. Therefore, it is feasible to introduce this agroforestry system under such arid lands to provide summer forage yield of highly nutritive value and low cost for animals feed as well as to increase farmers' income and to halt desertification and to sequester carbon.