• 대한조선학회논문집
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• 제58권4호
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• pp.225-233
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• 2021

Conventional submarine propulsion batteries have mainly used lead acid batteries, which have proved relatively safe, but in recent years, research on mounting lithium-ion batteries to improve the underwater operation capability of submarines is underway in advanced countries such as Japan. Korea has world-class technology in the development of electric vehicles and lithium-ion batteries for energy storage, but fire safety accidents continue to occur in electric vehicles and energy storage lithium-ion batteries. In order to mount the lithium-ion battery in a submarine, it is necessary to check the safety as well as whether the performance is improved compared to the lead acid battery. Through the charge/discharge experiment of this lithium-ion battery module unit, it was possible to measure how much performance was improved compared to the lead acid battery. Safety tests were conducted on the lithium-ion battery module assuming that it was mounted on a submarine, and it was confirmed that safety was secured when applied to a submarine. Since many modules are mounted on actual submarines, it has been confirmed that it can be applied to submarine systems by simulating charge/discharge characteristics through Hardware-in-the Loop(HILS). Through the results of this study, the application of lithium-ion batteries to submarines is expected to significantly improve the sustainability of underwater operations.

• 전기전자학회논문지
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• 제24권4호
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• pp.1058-1063
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• 2020

본 논문은 생체 신호 및 센서 신호 처리를 위하여 저전력으로 동작하는 12비트 SAR A/D 변환기를 제안한다. 기존의 SAR A/D 변환기의 전력소모를 줄이고자, 동적 전류를 감소시켜 전체 전력 소모를 감소시켰다. 동적 전류를 감소시키기 위해서 C-DAC 비트 스위치를 동작시키는 샘플링 시간을 클럭 생성기의 샘플링 시간과 다르게 인가하였다. 추가적으로 SAR A/D 변환기의 전체 전력소모 중 70%를 차지하는 디지털 블록의 공급전압을 0.6V로 낮춰 설계하였다. 제안하는 SAR A/D 변환기는 CMOS 65nm 공정 1-poly 6-metal을 사용하여 설계하였으며, 1.2V의 공급전압으로 동작하며, ENOB는 10.1 비트, INL/DNL은 ±0.5LSB/±1.2LSB이며, 전체 전력소모는 31.2uW이고 FoM은 2.8fJ/step 이다.

• 한국정보통신학회논문지
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• 제24권9호
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• pp.1202-1208
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• 2020

현재 4차 산업혁명 시대에 발맞춰서 선박 분야에서는 인공지능 요소를 접목하여 미래를 대비하여야 한다. 그리고 자율운항 선박 등장에 대한 전력관리 분야에서도 이에 대한 대응이 필요하다. 본 연구에서는 머신러닝의 DNN(Deep Neural Network)을 이용한 배터리 연동형 전력관리시스템(BLPMS, Battery Linked Power Management System) 알고리즘을 제안한다. 실험을 위하여 LabView를 통한 선박 데이터를 바탕으로 운항모드별 선박 전력소비량의 패턴을 학습하고 Python을 통해 배터리의 상태를 도출하여 발전기와 배터리의 연동의 유연성을 확인하였다. 실험의 결과 배터리의 충·방전을 통해 발전기의 저부하 운전이 감소되고, LNG의 1%의 연료소모량 감소를 통하여 경제성 및 신뢰성을 확인하였다.

• 전기전자학회논문지
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• 제26권2호
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• pp.313-318
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• 2022

피드백 전압 감지 구조는 기존 외부 출력 캐패시터의 제거로 인한 오버슈트 및 언더슈트 현상을 완화하기 위해 제안된다. 기존의 LDO 레귤레이터는 전원 공급 전압의 불균형으로 인해 발생하는 오버슈트 및 언더슈트를 겪는다. 따라서 제안된 LDO는 기존 LDO의 피드백 경로만 유지하면서 새로운 제어 경로를 형성하기 위해 보다 개선된 과도 응답을 갖도록 설계되었다. 새로운 제어 경로는 출력 단계에서 발생하는 오버슈트 및 언더슈트 현상을 감지한다. 이에, 패스 소자의 게이트 노드의 전류를 충방전함으로써 패스 소자의 동작 속도가 향상된다. 피드백 전압 감지 구조가 있는 LDO 레귤레이터는 3.3~4.5V의 입력 전압 범위에서 작동하며 3V의 출력 전압에서 최대 200mA의 부하 전류를 가집니다. 시뮬레이션 결과에 따르면 부하전류가 200mA일 때 언더슈트 조건에서는 73mV, 오버슈트 조건에서는 61mV이다.

• 한국정보통신학회논문지
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• 제25권11호
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• pp.1603-1611
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• 2021

본 연구에서는 에너지 저장장치인 배터리를 기존의 발전기 전력계통에 연계하기 위하여 양방향 전력의 흐름이 가능한 BDC(Bi-Directional Converter) 적용을 위해 모델링을 통하여 제어 프로세스를 설계하고, 해상 상황에 따라 변화하는 부하에 최적화된 전력 공급이 가능한 배터리의 충전 혹은 방전 메커니즘에 대하여 제안한다. 본 연구는 MATLAB/Simulink를 이용하여 BDC를 모델링 하였으며 부하 시나리오에 따라 배터리 충전 및 방전 시의 전류 제어 및 SOC(State Of Charge) 최적화를 시뮬레이션 하였다. 이를 통해 선내 운전되는 발전기가 최적운전 범위에 운전될 수 있도록 배터리와 전력 및 부하를 연동할 수 있도록 하였으며, 발전기가 높은 연료효율 범위에서 운전될 수 있도록 전력제어관리를 수행하였다.

• 한국재료학회지
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• 제32권4호
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• pp.216-222
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• 2022

The capacity of high nickel Li(Ni_xCo_yMn_1-x-y)O₂ (NCM, x ≥ 0.8) cathodes is known to rapidly decline, a serious problem that needs to be solved in a timely manner. It was reported that cathode materials with the {010} plane exposed toward the outside, i.e., a radial structure, can provide facile Li⁺ diffusion paths and stress buffer during repeated cycles. In addition, cathodes with a core-shell composition gradient are of great interest. For example, a stable surface structure can be achieved using relatively low nickel content on the surface. In this study, precursors of the high-nickel NCM were synthesized by coprecipitation in ambient atmosphere. Then, a transition metal solution for coprecipitation was replaced with a low nickel content and the coprecipitation reaction proceeded for the desired time. The electrochemical analysis of the core-shell cathode showed a capacity retention of 94 % after 100 cycles, compared to the initial discharge capacity of 184.74 mA h/g. The rate capability test also confirmed that the core-shell cathode had enhanced kinetics during charging and discharging at 1 A/g.

• Journal of Electrochemical Science and Technology
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• 제13권3호
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• pp.362-368
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• 2022

The application of polymer composite electrolyte in all-solid-state lithium-sulfur battery (ASSLSBs) can guarantee high energy density and improve the interface contact between electrolyte and electrode, which has a broader application prospect. However, the inherent insulation of the sulfur-cathode leads to a low electron/ion transfer rate. Carbon materials with high electronic conductivity and electrolyte materials with high ionic conductivity are usually selected to improve the electron/ion conduction of the composite cathode. In this work, PEO-LiTFSI-LLZO composite polymer electrolyte (CPE) with high ionic conductivity was prepared. The ionic conductivity was 1.16×10^-4 and 7.26×10^-4 S cm^-1 at 20 and 60℃, respectively. Meanwhile, the composite sulfur cathode was prepared with Sulfur, reduced graphene oxide and composite polymer electrolyte slurry (S-rGO-CPEs). In addition to improving the ion conductivity in the cathode, CPEs also replaces the role of binder. The influence of different contents of CPEs in the cathode material on the performance of the constructed battery was investigated. The results show that the electrochemical performance of the all-solid-state lithium-sulfur battery is the best when the content of the composite electrolyte in the cathode is 40%. Under the condition of 0.2C and 45℃, the charging and discharging capacity of the first cycle is 923 mAh g^-1, and the retention capacity is 653 mAh g^-1 after 50 cycles.

• 전기화학회지
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• 제24권4호
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• pp.113-119
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• 2021

본 연구에서는 유기환원제로 포름산과 촉매로 PtD/C를 사용하여 불순물이 없는 고품질 V^3.5+ 전해질을 생산하였고 이를 VRFB에 적용하였다. PtD/C 촉매의 잘 배향된 3D 수상 돌기 구조는 포름산 산화 반응과 바나듐 환원 반응에 높은 활성을 보여 주었다. 그 결과 PtD/C의 촉매 전환율은 2.73 mol g^-1 h^-1로 polyol방법을 제조된 Pt/C의 전환율 1.67 mol g^-1 h^-1보다 더 높았다. 또한 VRFB 충방전 실험에서 촉매 반응으로 생성된 V^3.5+ 전해질은 전해 방법으로 제조 된 표준V^3.5+전해질과 동일한 성능을 보여 줌으로서 VRFB의 전해질로 사용 가능함을 증명하였다.

• 한국수소및신에너지학회논문집
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• 제34권2호
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• pp.91-99
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• 2023

Participation in power trading using surplus power is considered a business model active in the domestic energy trade market, but it is limited only if the legal requirements according to the type, capacity, and use of the facilities to be applied for are satisfied. The hydrogen residential demonstration model presented in this paper includes solar power, energy storage system (ESS), fuel cell, and water electrolysis facilities in electrical facilities for private use with low-voltage power receiving system. The concept of operations strategy for this model focuses on securing the energy self-sufficiency ratio of the entire system, securing economic feasibility through the optimal operation module installed in the energy management system (EMS), and securing the stability of the internal power balancing issue during the stand-alone mode. An electric facility configuration method of a hydrogen residential complex demonstrated to achieve this operational goal has a structure in which individual energy sources are electrically connected to the main bus, and ESS is also directly connected to the main bus instead of a renewable connection type to perform charging/discharging operation for energy balancing management in the complex. If surplus power exists after scheduling, participation in power trading through reverse transmission parallel operation can be considered to solve the energy balancing problem and ensure profitability. Consequentially, this paper reviews the legal regulations on participation in electric power trading using surplus power from hydrogen residential models that can produce and consume power, gas, and thermal energy including hybrid distributed power sources, and suggests action plans.

• 한국재료학회지
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• 제33권6호
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• pp.257-264
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• 2023

To develop a high capacity lithium secondary battery, a new approach to anode material synthesis is required, capable of producing an anode that exceeds the energy density limit of a carbon-based anode. This research synthesized carbon nano silicon composites as an anode material for a secondary battery using the RF thermal plasma method, which is an ecofriendly dry synthesis method. Prior to material synthesis, a silicon raw material was mixed at 10, 20, 30, 40, and 50 wt% based on the carbon raw material in a powder form, and the temperature change inside the reaction field depending on the applied plasma power was calculated. Information about the materials in the synthesized carbon nano silicon composites were confirmed through XRD analysis, showing carbon (86.7~52.6 %), silicon (7.2~36.2 %), and silicon carbide (6.1~11.2 %). Through FE-SEM analysis, it was confirmed that the silicon bonded to carbon was distributed at sizes of 100 nm or less. The bonding shape of the silicon nano particles bonded to carbon was observed through TEM analysis. The initial electrochemical charging/discharging test for the 40 wt% silicon mixture showed excellent electrical characteristics of 1,517 mAh/g (91.9 %) and an irreversible capacity of 133 mAh/g (8.1 %).