• 제목/요약/키워드: bond characteristics

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Characteristics of porous silicon for detection of ethanol and methanol (에탄올과 메탄올에 대한 다공질 실리콘의 감지 특성)

  • Kim, Hyung-Il;Kang, Chul-Goo;Kang, Moon-Sik;Jin, Joon-Hyung;Min, Nam-Ki
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1905-1907
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    • 2001
  • 본 논문에서는 다공질 실리콘에 대한 에탄올과 메탄을 가스 감지 특성을 측정하고 전기 전도도의 변화를 고찰하였다. 우선 HF와 에탄올의 혼합 용액내에서 n-type의 웨이퍼에 일정 전압을 인가하여 다공질 실리콘을 형성한다. 다공질 실리콘은 수직한 방향으로 $55{\sim}60{\mu}m$ 두께로 균일하게 형성되었다. 다공질 실리콘을 이용하여 소자를 제작하고 에탄올과 메탄올 가스를 주입하여 전류-전압 특성을 측정하였다. 기존의 다공질 실리콘 에탄올 센서와는 달리 turn-on 시 센서에 흐르는 전류가 빠른 시간내에 일정한 값으로 도달하였고 turn-off시에도 같은 결과를 보였다. 다공질 실리콘 표면에 흡착된 에탄올과 메탄올 가스는 전류의 흐름을 방해하는 surface charge를 스크린하여 전기 전도도를 증가시킨다. 또한 흡착된 가스가 dangling bonds를 passivation하여 전류를 증가시키는 것으로 생각된다.

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The Trial Construction of Optimum In-Process Electrolytic Dressing System and the Control Characteristics (최적 연속전해드레싱 시스템의 개발과 제어특성)

  • 김정두;이은상
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.3
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    • pp.680-687
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    • 1995
  • In recent years, grinding techniques for precision machining of brittle materials used in electric, optical and magnetic parts have been improved by using superabrasive wheel and precision grinding machine. The completion of optimum dressing of superabrasive wheel makes possible the effective precision grinding of brittle materials. But the present dressing system cannot have control of optimum dressing of the superabrasive wheel. This study has proposed a new optimum in-process electrolytic dressing system. This system can carry out optimum in-process dressing of superabrasive wheel, and give very effective control according to gap increase.

A Study on the Characteristics of Zerodur Grinding using Ultra-Precision Machine (초정밀가공기를 이용한 Zerodur의 연삭 특성에 관한 연구)

  • 김주환;김건희;한정열;김석환;원종호
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2003.04a
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    • pp.405-409
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    • 2003
  • We explored a new rough grinding technique on optics materials such as Zerodur. The facility used is a NANOFORM-600 diamond turning machine with a custom grinding module and range of diamond resin bond wheel. The grinding parameters such as workpiece rotation speed depth of cut and feed rate were altered while grinding the workpiece surfaces of 20m in diameter. Surface roughness is measured by Form Talysurf series2. Our target is to define grinding conditions producing the surface roughness better than 0.02${\mu}{\textrm}{m}$ Ra and the form accuracy of around 0.2${\mu}{\textrm}{m}$ PV.

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Selective Reduction of Organic Compounds with Non-Free Hydride Reducing Agents

  • Cha, Jin Soon
    • Journal of Integrative Natural Science
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    • v.1 no.3
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    • pp.192-194
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    • 2008
  • A series of non-free hydride reducing systems containing boron or aluminum atom, which possess no metal-hydride bond but an available hydrogen at a branched ${\beta}$-position, has been applied to the selective reduction (chemo--, regio-, and stereoselective reduction) of organic compounds. The systems, comprised of diisopinocampheylborane and diisobutylalane derivatives, exhibited almost perfect selectivities in the reduction of aldehydes and ketones. The characteristics features of this systems leading to a perfect transformation have been depicted in this report, especially in the 1) Reduction of ${\alpha}$,${\beta}$-Unsaturated Carbonyl Compounds to Allylic Alcohols via 1,2-Reduction, 2) Chemoselective Reduction between Structurally Different Carbonyl Compounds, and 3) Stereoselective Reduction of Cyclic Ketones.

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General Fragmentations of Alkaloids in Electrospray Ionization Tandem Mass Spectrometry

  • Shim, Hee Jung;Lee, Ji Ye;Kim, Byungjoo;Hong, Jongki
    • Mass Spectrometry Letters
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    • v.4 no.4
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    • pp.79-82
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    • 2013
  • Various types of alkaloids observed in several herbal medicines were analyzed by electrospray ionization tandem mass spectrometry in positive ion mode. In the present study, MS/MS spectralpatterns were investigated for eight-types of alkaloids (aporpine, protoberberine, tetrahydroprotoberberine, benzylisoquinoline, protopine, phthalide, morpine, and bisbenzylisoquinoline). For aporpine- and protoberberine-type alkaloids, main fragmentations occurred at substituted groups on rigid ring structures, not showing ring fusion. Interesting fragmentations due to iminolization and retro-Diels-Alder (RDA) reaction were observed in MS/MS spectra of protopine- and tetrahydroprotobereberine-type alkaloids. Also, several types of fragmentations such as inductive cleavage and ${\alpha}$-cleavage, or bond cleavage between two ring structures were observed depending on their structural characteristics. These fragmentation patterns are expected to allow instant classification of the specific alkaloid type in various MS/MS spectra of alkaloids.

Numerical Simulation of Ozone Concentration using the Local Wind Model in Pusan Coastal Area, Korea (부산연안역에서 국지풍모델을 이용한 오존농도의 수치모의)

  • Jeon, Byung-Il;kim, Yoo-Keun;Lee, Hwa-Woon
    • Journal of Environmental Science International
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    • v.6 no.4
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    • pp.335-350
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    • 1997
  • Numerical simulations of photochemical air pollution (CBM: Carbon-Bond Mechanisms under a theoretical three-dimensional local wind system are carried to clarify the fundamental characteristics of the effects of local wind on photochemical air pollution. According to the AWS data of Pusan coastal area and KMA, the surface wind of Pusan during summertime showed a very remarkable land and sea breeze circulation. The ozone concentration distribution using local wind model showed that high ozone concentration zone near coastal area moved toward inland In the afternoon. This change implies a sea breeze Increases the ozone concentration, but a land breeze decreases it in Pusan coastal area.

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Stress Analysis and Degradation Mechanism of the Drive Control system for a Railway carriage (철도차량 추진제어장치의 스트레스 분석 및 열화 메커니즘)

  • Kim, Ki-Joon;Wang, Jong-Bae;Choi, Young-Chan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.10a
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    • pp.21-24
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    • 2000
  • Traction motors driven by several type inverters have been subjected to increasing demands for higher operating temperature, more demands for duty cycles, higher starting current, frequent voltage transients and finally severe environmental exposure. For applications to inverter duty, traction motors needs a special insulation system, which has characteristics of increased bond strength, lower operating temperature and higher turn-to-tum insulation. Also it needs major contributors to insulation life and reliability of motors, which more considered by temperature, voltage, frequency, rise time, pulse configuration, wire thickness and insulation materials. In this paper, to evaluate of reliability and expected life, it is analyzed the several stresses and their degradation mechanism on insulation system of AC traction motor.

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Characterization of Silicon-Zinc-Oxide films by thermal annealing methods (열처리 방식에 따른 실리콘 산화아연 박막의 물성 분석)

  • Lee, Sang-Hyuk;Jun, Hyun-Sik;Park, Jin-Seok
    • Proceedings of the KIEE Conference
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    • 2015.07a
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    • pp.1151-1152
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    • 2015
  • Silicon zinc oxide (SZO) thin films were deposited via co-sputtering. Two kinds of post-treatment, furnace annealing and hot pressing, were carried out on the deposited SZO films. The effects of the post-treatment on the chemical bond and surface roughness of the deposited SZO films were analyzed as functions of the post-treatment conditions that were used. It was observed from the X-ray photoelectron spectroscopy (XPS) results that the amount of Si-O bonds in the SZO film drastically increased after the low-temperature furnace annealing. The experiment results showed that the hot pressing method would be favorable as it could improve the electrical characteristics of the SZO-TFTs.

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A Study on the Development of Diamond Grinding Wheel with Multi-Porous Structure (다기공 다이아몬드 연삭숫돌의 개발에 관한 연구)

    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.7 no.2
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    • pp.100-107
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    • 1998
  • Diamond wheels with fine grains and multi-porous structures are newely trial developed for smoothing and mirror finishing materials. Grinding wheel must have performed both to remove tool marks efficienitly and to contact elastically with curved surfaces, that are employed for ultra precision and high performance grinding of difficult-to materials such as tungsten carbide alloy using tool and die materials, Diamond grains are bonded by a melamine resin to prevent the decrease of machining efficiency due to grain sinking within the bond materials. Also, highly foamed structures are developed to increase the flexibility of the grinding wheel, and to induce self-sharpening by increasing contact pressure between the grinding wheel and workpiece surfaces. In this paper, melamine-bonded diamond wheels try to manufacture, then the forming method of grinding wheel are suggested, and the grinding characteristics of melamine-bonded diamond grinding wheel are also illustrated.

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Development of diamond wheel for ultra precision and high performance grinding of difficult-to-materials (난삭재의 초정밀.고능률 연삭가공을 위한 다이아몬드숫돌의 개발)

  • Heo, Seong-Jung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.12
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    • pp.2172-2178
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    • 1997
  • Development of diamond wheel with fine grains and multi-pore structures were newely attempted. Wheels, that are employed for ultra precision and high performance grinding of difficult-to materials such as tungsten carbide alloy using tool and die materials, must have both performances to remove tool marks efficiently and to contact elastically with curved surfaces. Diamond grains were bonded firmly by a melamine resin to prevent the decrease of machining efficiency due to grain sinking within the bond materials. Also, highly foamed structures were developed to increase the flexibility of the wheel, and to induce active self-sharpening by increasing contact pressure between the wheel and work surfaces. In this paper, melamine-bonded diamond wheels are trial manufactured, then the forming method of wheels are suggested, and the grinding characteristics of wheels are also illustrated.