• 제목/요약/키워드: binding material

검색결과 380건 처리시간 0.028초

산소 분압에 따른 산화주석 박막의 전계효과 이동도 변화 분석 (Analysis on the Field Effect Mobility Variation of Tin Oxide Thin Films with Oxygen Partial Pressure)

  • 마대영
    • 한국전기전자재료학회논문지
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    • 제27권6호
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    • pp.350-355
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    • 2014
  • Bottom-gate tin oxide ($SnO_2$) thin film transistors (TFTs) were fabricated on $N^+$ Si wafers used as gate electrodes. 60-nm-thick $SnO_2$ thin films acting as active layers were sputtered on $SiO_2/Al_2O_3$ films. The $SiO_2/Al_2O_3$ films deposited on the Si wafers were employed for gate dielectrics. In order to increase the resistivity of the $SnO_2$ thin films, oxygen mixed with argon was introduced into the chamber during the sputtering. The mobility of $SnO_2$ TFTs was measured as a function of the flow ratio of oxygen to argon ($O_2/Ar$). The mobility variation with $O_2/Ar$ was analyzed through studies on crystallinity, oxygen binding state, optical properties. X-ray diffraction (XRD) and XPS (X-ray photoelectron spectroscopy) were carried out to observe the crystallinity and oxygen binding state of $SnO_2$ films. The mobility decreased with increasing $O_2/Ar$. It was found that the decrease of the mobility is mainly due to the decrease in the polarizability of $SnO_2$ films.

대마섬유의 정련 방법에 관한 비교 연구 (Comparative Study on the Degumming Methods of Hemp Fiber)

  • 임형규;김희숙
    • 한국의류산업학회지
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    • 제22권4호
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    • pp.523-533
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    • 2020
  • Previous studies are used to examine cellulose content, degumming period, fiber quality, production yield, production cost, development limit of fiber according to physical, chemical, and microbial degumming methods. Three types of degumming methods are used to measure surface condition after degumming, necessity of additional degumming and degree of impurity removal. First, previous studies confirmed that the microbial degumming method is superior in terms of cellulose content, fiber quality, production yield, production cost, and fiber development possibility. Second, surface condition and the necessity of additional degumming were analyzed by SEM. The black skin binding material was removed in the case of the Sangnangyi and chemical degumming; however, it was insufficient and further degumming was required. Skin fiber binding material was removed in the case of microbial degumming and the surface was cleanest after degumming; in addition, most showed the form of yarn decomposition. The FT-IR spectrum determined the degree of removal of impurities and showed that it can utilize inherent physical properties as the best degumming method. The degree of removal of pectin and lignin by microbial degumming was cleanest with hemicellulose also reduced by microbial degumming.

Microstructural behavior and mechanics of nano-modified cementitious materials

  • Archontas, Nikolaos D.;Pantazopoulou, S.J.
    • Advances in concrete construction
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    • 제3권1호
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    • pp.15-37
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    • 2015
  • Ongoing efforts for improved fracture toughness of engineered cementitious materials address the inherent brittleness of the binding matrix at several different levels of the material's geometric scale through the addition of various types of reinforcing fibers. Crack control is required for crack widths that cover the entire range of the grain size spectrum of the material, and this dictates the requirement of hybrid mixes combining fibers of different size (nano, micro, macro). Use of Carbon Nano-Tubes (CNT) and Carbon Nano-Fibers (CNFs) as additives is meant to extend the crack-control function down to the nanoscale where cracking is believed to initiate. In this paper the implications of enhanced toughness thus attained at the material nanostructure are explored, with reference to the global smeared constitutive properties of the material, through consistent interpretation of the reported experimental evidence regarding the behavior of engineered cementitious products to direct and indirect tension.

Evaluation of Acceptor Binding Energy of Nitrogen-Doped Zinc Oxide Thin Films Grown by Dielectric Barrier Discharge in Pulsed Laser Deposition

  • Lee, Deuk-Hee;Chun, Yoon-Soo;Lee, Sang-Yeol;Kim, Sang-Sig
    • Transactions on Electrical and Electronic Materials
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    • 제12권5호
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    • pp.200-203
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    • 2011
  • In this research, nitrogen (N)-doped zinc oxide (ZnO) thin films have been grown on a sapphire substrate by dielectric barrier discharge (DBD) in pulsed laser deposition (PLD). DBD has been used as an effective way for massive in-situ generation of N-plasma under conventional PLD process conditions. Low-temperature photoluminescence spectra of N-doped ZnO thin films provided near-band-edge emission after a thermal annealing process. The emission peak was resolved by Gaussian fitting and showed a dominant acceptor-bound excitation peak ($A^{\circ}X$) that indicated acceptor doping of ZnO with N. The acceptor binding energy of the N acceptor was estimated to be approximately 145 MeV based on the results of temperature-dependent photoluminescence (PL) measurements.

천연 결합재를 사용한 황토경화체의 물성에 대한 연구 (Physical Properties of the Hardened Loess Using Natural Binding Materials)

  • 김진석;오영훈
    • 한국구조물진단유지관리공학회 논문집
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    • 제16권4호
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    • pp.44-51
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    • 2012
  • 본 연구에서는 황토에 시멘트나 유기계 접착제를 첨가하지 않은 천연재료 황토결합재를 사용하여 황토경화체를 제작하고, 배합조건에 따른 강도성상을 평가하였다. 황토와 석회의 결합재에 천연재료를 첨가할 경우 사용한 천연재료는 모두 물리적 성능을 개선하는 효과가 있었다. 천연재료 중에서 석회는 황토경화체의 물성을 증가시키는데 가장 큰 영향을 미치고 있다. 황토경화체의 물리적 특성은 적용한 배합비 중에서 W/B 45%, 단위수량 $285kg/m^3$, 석회첨가율 60%일 때 가장 우수하게 나타나고 있다.

Addition of Various Cellulosic Components to Bacterial Nanocellulose: A Comparison of Surface Qualities and Crystalline Properties

  • Bang, Won Yeong;Kim, Dong Hyun;Kang, Mi Dan;Yang, Jungwoo;Huh, Taelin;Lim, Young Woon;Jung, Young Hoon
    • Journal of Microbiology and Biotechnology
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    • 제31권10호
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    • pp.1366-1372
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    • 2021
  • Bacterial nanocellulose (BNC) is a biocompatible material with a lot of potential. To make BNC commercially feasible, improvements in its production and surface qualities must be made. Here, we investigated the in situ fermentation and generation of BNC by addition of different cellulosic substrates such as Avicel and carboxymethylcellulose (CMC) and using Komagataeibacter sp. SFCB22-18. The addition of cellulosic substrates improved BNC production by a maximum of about 5 times and slightly modified its structural properties. The morphological and structural properties of BNC were investigated by using Fourier transform-infrared spectroscopy (FT-IR), scanning electron microscopy and X-ray diffraction. Furthermore, a type-A cellulose-binding protein derived from Clostridium thermocellum, CtCBD3, was used in a novel biological analytic approach to measure the surface crystallinity of the BNC. Because Avicel and CMC may adhere to microfibrils during BNC synthesis or crystallization, cellulose-binding protein could be a useful tool for identifying the crystalline properties of BNC with high sensitivity.

고농도 염화물을 함유하는 혼합시멘트 계에서 철근부식에 따른 미세구조의 변화와 전기화학적 특성 (Microstructure modification and electrochemical properties of steel corrosion in the blended cement systems containing internal chlorides)

  • 나종윤;이승헌;김창은
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1999년도 학회창립 10주년 기념 1999년도 가을 학술발표회 논문집
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    • pp.131-134
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    • 1999
  • Microstructure modification and electrochemical properties are investigate to estimate the effects of internal chlorides on the steel corrosion in the blended cement systems. According to the test results, slag cement system showed high chloride binding capacity and low corrosion rate. The impedance data showed three distince arcs from lowest(mHz) frequency to highest (MHz) frequency due to product layer, interfacial reaction and bulk matrix. Through the microstructural investigation, fine steel-matrix interface of slag cement system was observed but rough steel-matrix interface of OPC system was observed. Friedel's salt was thought that the substantial material contributed to the chloride binding of slag cement system.

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KPFM을 통한 수은이온 검출 방법 (Mercury ion detection technique using KPFM)

  • 박찬호;장규환;이상명;유준석;나성수
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2014년도 추계학술대회 논문집
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    • pp.358-360
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    • 2014
  • For the several decades, various nanomaterials are broadly used in industry and research. With the growth of nanotechnology, the study of nanotoxicity is being accelerated. Particularly, mercury ion is widely used in real life. Because the mercury is representative high toxic material, it is highly recommended to detect the mercury ion. In previous reported work, thymine-thymine mismatches (T-T) capture mercury ion and create very stable base pair ($T-Hg^{2+}-T$). Here, we performed the high sensitive sensing method for direct label free detection of mercury ions and DNA binding using Kelvin Probe Force Microscope (KPFM). In this method, 30 base pairs of thymine (T-30) is used for mercury specific DNA binding ($T-Hg^{2+}-T$). KPFM is able to detect the mercury ion because there is difference between bare T-30 DNA and mercury mediated DNA ($T-Hg^{2+}-T$).

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Synthesis of Chemosensor Based on Pyrene and Study for Its Sensing Properties Toward Fluoride Ion

  • Kim, Hyungjoo;Li, Xiaochuan;Son, Young-A
    • 한국염색가공학회지
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    • 제25권3호
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    • pp.153-158
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    • 2013
  • In this study, pyrene based chemosensor was synthesized by two step reaction. The chemosensor showed that high selectivity toward fluoride in DMSO. The fluorescence intensity was drastically increased by binding between chemosensor and fluoride ion. Absorption and fluorescence spectra were obtained by UV-Vis spectrometer and fluorescence spectrophotometer. The binding ratio between chemosensor and fluoride ion was also investigated by job's plot method and Benesi-Hildebrand plot. The HOMO/LUMO energy levels and electron distribution were calculated and simulated by Material studio 6.0 Package.

전기화학 바이오센서의 전극물질로 응용을 위한 열분해 탄소의 제작 및 특성 연구 (Fabrication and Characterization of Pyrolyzed Carbon for Use as an Electrode Material in Electrochemical Biosensor)

  • 이정아;황성필;곽주현;박세일;이승섭;이광철
    • 대한기계학회논문집A
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    • 제31권10호
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    • pp.986-992
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    • 2007
  • This paper presents the fabrication and characterization of carbon films pyrolyzed with various photoresists for bioMEMS applications. To verify the usefulness of pyrolyzed carbon films as an electrode material in an electrochemical biosensor developed by the authors, interactions between avidin and biotin on the pyrolyzed carbon film were studied via electrochemical impedance spectroscopy based on electrostatic interactions between avidin and negatively-charged ferricyanide. The pyrolyzed carbon films were characterized using a surface profiler, a precision semiconductor parameter analyzer, a nanoindentor, scanning electron microscopy, and atomic force microscopy. Amine conjugated biotin was immobilized on the electrode using EDC/NHS as crosslinkers after $O_2$ plasma treatment to enhance functional groups on the carbon electrode pyrolyzed at $1000^{\circ}C$ with AZ9260. The detection of avidin binding with different concentrations in a range of 0.75 nM to $7.5\;{\mu}M$ to the pyrolyzed carbon electrode modified with biotin was carried out by measuring the electrochemical impedance change. The results show that avidin binds to the biotin on the electrode not by non-specific interaction but by specific interaction, and that EIS successfully detects this binding event. Pyrolyzed carbon films are a promising material for miniaturization, integration, and low-cost fabrication in electrochemical biosensors.