• Title/Summary/Keyword: barrier performance

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Investigation of LiO2 Adsorption on LaB1-xB'xO3(001) for Li-Air Battery Applications: A Density Functional Theory Study

  • Kwon, Hyunguk;Han, Jeong Woo
    • Journal of the Korean Ceramic Society
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    • v.53 no.3
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    • pp.306-311
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    • 2016
  • Li-air batteries have received much attention due to their superior theoretical energy density. However, their sluggish kinetics on the cathode side is considered the main barrier to high performance. The rational design of electrode catalysts with high activity is therefore an important challenge. To solve this issue, we performed density functional theory (DFT) calculations to analyze the adsorption behavior of the $LiO_2$ molecule, which is considered to be a key intermediate in both the Li-oxygen reduction reaction (ORR) and the evolution reaction (OER). Specifically, to use the activity descriptor approach, the $LiO_2$ adsorption energy, which has previously been demonstrated to be a reliable descriptor of the cathode reaction in Li-air batteries, was calculated on $LaB_{1-x}B^{\prime}_xO_3$(001) (B, B' = Mn, Fe, Co, and Ni, x = 0.0, 0.5). Our fast screening results showed that $LaMnO_3$, $LaMn_{0.5}Fe_{0.5}O_3$, or $LaFeO_3$ would be good candidate catalysts. We believe that our results will provide a way to more efficiently develop new cathode materials for Li-air batteries.

Temperature Dependence of Electrical Parameters of Silicon-on-Insulator Triple Gate n-Channel Fin Field Effect Transistor

  • Boukortt, Nour El Islam;Hadri, Baghdad;Caddemi, Alina;Crupi, Giovanni;Patane, Salvatore
    • Transactions on Electrical and Electronic Materials
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    • v.17 no.6
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    • pp.329-334
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    • 2016
  • In this work, the temperature dependence of electrical parameters of nanoscale SOI (silicon-on-insulator) TG (triple gate) n-FinFET (n-channel Fin field effect transistor) was investigated. Numerical device simulator $ATLAS^{TM}$ was used to construct, examine, and simulate the structure in three dimensions with different models. The drain current, transconductance, threshold voltage, subthreshold swing, leakage current, drain induced barrier lowering, and on/off current ratio were studied in various biasing configurations. The temperature dependence of the main electrical parameters of a SOI TG n-FinFET was analyzed and discussed. Increased temperature led to degraded performance of some basic parameters such as subthreshold swing, transconductance, on-current, and leakage current. These results might be useful for further development of devises to strongly down-scale the manufacturing process.

The Effect of Thermal Annealing Process on Fermi-level Pinning Phenomenon in Metal-Pentacene Junctions

  • Cho, Hang-Il;Park, Jin-Hong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.290.2-290.2
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    • 2016
  • Recently, organic thin-film transistors have been widely researched for organic light-emitting diode panels, memory devices, logic circuits for flexible display because of its virtue of mechanical flexibility, low fabrication cost, low process temperature, and large area production. In order to achieve high performance OTFTs, increase in accumulation carrier mobility is a critical factor. Post-fabrication thermal annealing process has been known as one of the methods to achieve this by improving the crystal quality of organic semiconductor materials In this paper, we researched the properties of pentacene films with X-Ray Diffraction (XRD) and Atomic Force Microscope (AFM) analyses as different annealing temperature in N2 ambient. Electrical characterization of the pentacene based thin film transistor was also conducted by transfer length method (TLM) with different annealing temperature in Al- and Ti-pentacene junctions to confirm the Fermi level pinning phenomenon. For Al- and Ti-pentacene junctions, is was found that as the surface quality of the pentacene films changed as annealing temperature increased, the hole-barrier height (h-BH) that were controlled by Fermi level pinning were effectively reduced.

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Thermal, Hydraulic and Mechanical Analysis for Disposal of Spent Nuclear Fuel in Saturated Rock Mass in the KBS-3 Concept. (KBS-3 개념에 따른 포화된 암반내 사용후핵연료 처분을 위한 열, 수리, 역학적 특성 해석)

  • 장근무;황용수;김선훈
    • Tunnel and Underground Space
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    • v.7 no.1
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    • pp.39-50
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    • 1997
  • Reference concepts for the disposal of spent nuclear fuel and the current status of underground rock laboratory were studied. An analysis to simulate the deep disposal of spent nuclear fuel in saturated rock mass was conducted. Main input parameters for numerical study were determined based on the KBS-3 concept. A series of results showed that the temperature distribution around a cavern reached the maximum value at about 10 years after the emplacement of spent fuel. The maximum temperature at the surface of canister was more than about 12$0^{\circ}C$ at about 4 years. This temperature was not much higher than the temperature criteria to meet the performance criteria of an artificial barrier in the KBS-3 concept. The maximum upward displacement due to the heat generation of spent fuel was about 0.9cm at about 10 years after the emplacement of spent fuel. It turned out that the vertical displacement became smaller with the decrease in heat generation of a canister. The quantity of groundwater inflow into a disposal tunnel increased by about 1.6 times at 20 years after the emplacement of spent fuel with the increase of pore pressure around a cavern.

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Probabilistic Safety Assessment for High Level Nuclear Waste Repository System

  • Kim, Taw-Woon;Woo, Kab-Koo;Lee, Kun-Jai
    • Journal of Radiation Protection and Research
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    • v.16 no.1
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    • pp.53-72
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    • 1991
  • An integrated model is developed in this paper for the performance assessment of high level radioactive waste repository. This integrated model consists of two simple mathematical models. One is a multiple-barrier failure model of the repository system based on constant failure rates which provides source terms to biosphere. The other is a biosphere model which has multiple pathways for radionuclides to reach to human. For the parametric uncertainty and sensitivity analysis for the risk assessment of high level radioactive waste repository, Latin hypercube sampling and rank correlation techniques are applied to this model. The former is cost-effective for large computer programs because it gives smaller error in estimating output distribution even with smaller number of runs compared to crude Monte Carlo technique. The latter is good for generating dependence structure among samples of input parameters. It is also used to find out the most sensitive, or important, parameter groups among given input parameters. The methodology of the mathematical modelling with statistical analysis will provide useful insights to the decision-making of radioactive waste repository selection and future researches related to uncertain and sensitive input parameters.

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A study on the topology optimization of structures (구조물의 토폴로지 최적화에 관한 연구)

  • Park, Sang-Hun;Yun, Seong-Gi
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.8
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    • pp.1241-1249
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    • 1997
  • The problem of structural topology optimization can be relaxed and converted into the optimal density distribution problem. The optimal density distribution must be post-processed to get the real shape of the structure. The extracted shape can then be used for the next process, which is usually shape optmization based on the boundary movement method. In the practical point of view, it is very important to get the optimal density distribution from which the corresponding shape can easily be extracted. Among many other factors, the presence of checker-board patterns is a powerful barrier for the shape extraction job. The nature of checker-board patterns seems to be a numerical locking. In this paper, an efficient algorithm is presented to suppress the checker-board patterns. At each iteration, density is re-distributed after it is updated according to the optimization rule. The algorithm also results in the optimal density distribution whose corresponding shape has smooth boundary. Some examples are presented to show the performance of the density re-distribution algorithm. Checker-board patterns are successfully suppressed and the resulting shapes are considered very satisfactory.

Real-Time Augmented Reality on 3-D Mobile Display using Stereo Camera Tracking (스테레오 카메라 추적을 이용한 모바일 3차원 디스플레이 상의 실시간 증강현실)

  • Park, Jungsik;Seo, Byung-Kuk;Park, Jong-Il
    • Journal of Broadcast Engineering
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    • v.18 no.3
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    • pp.362-371
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    • 2013
  • This paper presents a framework of real-time augmented reality on 3-D mobile display with stereo camera tracking. In the framework, camera poses are jointly estimated with the geometric relationship between stereoscopic images, which is based on model-based tracking. With the estimated camera poses, the virtual contents are correctly augmented on stereoscopic images through image rectification. For real-time performance, stereo camera tracking and image rectification are efficiently performed using multiple threads. Image rectification and color conversion are accelerated with a GPU processing. The proposed framework is tested and demonstrated on a commercial smartphone, which is equipped with a stereoscopic camera and a parallax barrier 3-D display.

Improved performance of PEDOT:PSS/pentacene Schottky diode on EAPap (셀룰로우스 기반의 EAPap 작동기의 PEDOT_PSS/Pentacene를 이용한 Schottky diode 성능 개선)

  • Lim, Hyun-Kyu;Cho, Ki-Youn;Kang, Kwang-Sun;Kim, Jae-Hwan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2007.11a
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    • pp.77-81
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    • 2007
  • Pentacene was dissolved in N-methyspyrrolidone (NMP) and mixed with poly(3,4-ethylenedioxythiophene), poly(styrenesulfonate) (PEDOT:PSS). The solution color changed from deep purple to intense yellow. As the dissolution time increased, visible absorption decreased and ultraviolet (UV) absorption increased. PEDOT:PSS or Pentacene-PEDOT:PSS was spin-coated to control the layer thickness. Three-layered Schottky diodes consisting of Al, PEDOT:PSS or PEDOT:PSS-pentacene, and Au with thickness of 300nm, respectively, were fabricated. The current densities of $4.8{\mu}A/cm^2$ at 2.5MV/m and $660{\mu}A/cm^2$ at 1.9MV/m were obtained for the Au/PEDOT:PSS/Al and Au/Pentacene-PEDOT:PSS/Al Schottky diodes, respectively. The current density of the Schottky diode was enhanced by about two orders of magnitude by doping pentacene to PEDOT:PSS.

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BMP-2 Immoblized in BCP-Chitosan-Hyaluronic Acid Hybrid Scaffold for Bone Tissue Engineering

  • Nath, Subrata Deb;Abueva, Celine;Sarkar, Swapan Kumar;Lee, Byong Taek
    • Korean Journal of Materials Research
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    • v.24 no.12
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    • pp.704-709
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    • 2014
  • In this study, we fabricated a novel micro porous hybrid scaffold of biphasic calcium phosphate (BCP) and a polylectrolyte complex (PEC) of chitosan (CS) and hyaluronic acid (HA). The fabrication process included loading of CS-HA PEC in a bare BCP scaffold followed by lypophilization. SEM observation and porosimetry revealed that the scaffold was full of micro and macro pores with total porosity of more than 60 % and pore size in the range of $20{\sim}200{\mu}m$. The composite scaffold was mechanically stronger than the bare BCP scaffold and was significantly stronger than the CS-HA PEC polymer scaffold. Bone morphogenetic growth factor (BMP-2) was immobilized in CS-HA PEC in order to integrate the osteoinductive potentiality required for osteogenesis. The BCP frame, prepared by sponge replica, worked as a physical barrier that prolonged the BMP-2 release significantly. The preliminary biocompatibility data show improved biological performance of the BMP-2 immobilized hybrid scaffold in the presence of rabbit bone marrow stem cells (rBMSC).

Extent and persistence of dissolved oxygen enhancement using nanobubbles

  • Tekile, Andinet;Kim, Ilho;Lee, Jai-Yeop
    • Environmental Engineering Research
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    • v.21 no.4
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    • pp.427-435
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    • 2016
  • In this study, change in water-dissolved oxygen (DO) was analyzed under various synthetic water qualities and nanobubbles (NBs) application conditions, such as gas type, initial DO as well as water dissolved, suspended and organic matters contents. When oxygen, rather than air, was introduced into nitrogen-desorbed ultra-pure water, the stagnation time was significantly increased. It took ten days for DO concentration to drop back to saturation. The higher the initial DO concentration, the longer particles were observed above saturation due to particle stability improvement. The oxygen mass transfer rate of 0.0482 mg/L/min was found to reach a maximum at an electrolytic concentration of 0.75 g/L, beyond which the transfer rate decreased due to adsorption of negative ions of the electrolyte at the interface. High levels of turbidity caused by suspended solids have become a barrier to dissolution of NBs oxygen into the water solution, and thus affected the transfer performance. On the other hand, by applying NBs for just an hour, up to 7.2% degradation of glucose as representative organic matter was achieved. Thus, NBs technology would maintain a high DO extent for an extended duration, and thus can improve water quality provided that water chemistry is closely monitored during its application.