• Title/Summary/Keyword: barrier performance

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The Thioacetate-Functionalized Self-Assembled Monolayers on Au: Toward High-Performance Ion-Selective Electrode for Ag+

  • Jin, Jian;Zhou, Wei-Jie;Chen, Ying;Liu, Yi-Long;Sun, Xiao-Qiang;Xi, Hai-Tao
    • Bulletin of the Korean Chemical Society
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    • v.35 no.2
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    • pp.601-604
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    • 2014
  • Two classes of morpholino-substitued thioacetate have been successfully synthesized and their electrochemical properties of self-assembled monolayers (SAMs) on Au electrode are measured by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The barrier property of the SAMs-modified surfaces is evaluated by using potassium ferro/ferri cyanide. The results suggest that the arenethioacetate forms higher-quality close-packed blocking monolayers in comparison with alkanethioacetate. Furthermore, it has shown that the barrier properties of these monolayers can be significantly improved by mixed SAMs formation with decanethiol. From our experimental results we find that the electron transfer reaction of $[Fe(CN)_6]^{3/4-}$ redox couple occurs predominantly through the pinholes and defects present in the SAM and both SAMs show a good and fast capacity in recognition for $Ag^+$. The morphological and elementary composition have also been examined by scanning electron microscope (SEM) and energy dispersive spectrometer (EDS).

Development of Consistency Algorithm for VOD Streaming Server Data (VOD 스트리밍 서버 데이터를 위한 일치성 보장 알고리즘 개발)

  • Jang Seung-Ju
    • Journal of the Institute of Electronics Engineers of Korea CI
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    • v.43 no.5 s.311
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    • pp.8-16
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    • 2006
  • This paper proposes and implements consistency algorithm that is serviced streaming data efficiently in VOD system. The media data is loaded into each node by Round Robin method. The barrier mechanism is changed into the minimum data factor(SH, GOP) of media data in this paper. In addition in order to fast media data service, the additional features are implemented in the consistency algorithm. Additional feature of the consistency algorithm is added. First, time synchronization algorithm is added the suggested consistency algorithm. Second, the prepaging mechanism supports efficient buffering service. I experimented the suggested consistency algorithm two DSM systems. The performance is good due to the last barrier algorithm.

Efficiency enhancement of Organic Light Emitting Diodes by the Aluminum Oxynitride Buffer Layer

  • Park, Hyung-Jun;Jang, Kyung-Soo;Jung, Sung-Wook;Hwang, Sung-Hyun;Lee, Jeoung-In;Lee, Kwang-Soo;Park, Keun-Hee;Nam, Eun-Kyoung;Jung, Dong-geun;Yi, Jun-Sin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.675-678
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    • 2007
  • In organic light emitting diodes (OLEDs), the electrons and holes need to be injected efficiently to obtain the best device performance. This means that a small injection barrier height at the ITO/organic interface is required. In this study, the surface of the ITO anode was treated with an Aluminum oxynitride (AlON).

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Magnetic Resonance-Guided Focused Ultrasound in Neurosurgery: Taking Lessons from the Past to Inform the Future

  • Jung, Na Young;Chang, Jin Woo
    • Journal of Korean Medical Science
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    • v.33 no.44
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    • pp.279.1-279.16
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    • 2018
  • Magnetic resonance-guided focused ultrasound (MRgFUS) is a new emerging neurosurgical procedure applied in a wide range of clinical fields. It can generate high-intensity energy at the focal zone in deep body areas without requiring incision of soft tissues. Although the effectiveness of the focused ultrasound technique had not been recognized because of the skull being a main barrier in the transmission of acoustic energy, the development of hemispheric distribution of ultrasound transducer phased arrays has solved this issue and enabled the performance of true transcranial procedures. Advanced imaging technologies such as magnetic resonance thermometry could enhance the safety of MRgFUS. The current clinical applications of MRgFUS in neurosurgery involve stereotactic ablative treatments for patients with essential tremor, Parkinson's disease, obsessive-compulsive disorder, major depressive disorder, or neuropathic pain. Other potential treatment candidates being examined in ongoing clinical trials include brain tumors, Alzheimer's disease, and epilepsy, based on MRgFUS abilities of thermal ablation and opening the blood-brain barrier. With the development of ultrasound technology to overcome the limitations, MRgFUS is gradually expanding the therapeutic field for intractable neurological disorders and serving as a trail for a promising future in noninvasive and safe neurosurgical care.

THE EFFECT OF SI-RICH LAYER COATING ON U-MO VS. AL INTERDIFFUSION

  • Ryu, Ho-Jin;Park, Jae-Soon;Park, Jong-Man;Kim, Chang-Kyu
    • Nuclear Engineering and Technology
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    • v.43 no.2
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    • pp.159-166
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    • 2011
  • Si-rich-layer-coated U-7 wt%Mo plates were prepared in order to evaluate the diffusion barrier performance of the Si-rich layer in U-Mo vs. Al interdiffusion. Pure Si powder was used for coating the U-Mo plates by annealing at $900^{\circ}C$ for 1 h under vacuum of approximately 1 Pa. Si-rich layers containing more than 60 at% of Si were formed on U-7 wt%Mo plates. Diffusion couple tests were conducted in a muffle furnace at $560-600^{\circ}C$ under vacuum using Si-rich-layer-coated U-Mo plates and pure Al plates. Diffusion couple tests using uncoated U-Mo plates and Al-(0, 2 or 5 wt%)Si plates were also conducted for comparison. Si-rich-layer coatings were more effective in suppressing the interaction during diffusion couple tests between coated U-Mo plate and Al, when compared with U-Mo vs. Al-Si diffusion couples, since only small amounts of Al in the coating could be found after the diffusion couple tests. Si-rich-layer-coated U-7wt%Mo particles were also prepared using the same technique for U-7 wt%Mo plates to observe the microsturctures of the coated particles.

Study on Side Impact Test Procedure of Hydrogen Bus (수소버스 측면충돌 시험방법 연구)

  • Kim, Kyungjin;Shin, Jaeho;Han, Kyeonghee;In, Jeong Min;Shim, Sojung;Kim, Siwoo
    • Journal of Auto-vehicle Safety Association
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    • v.13 no.4
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    • pp.92-98
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    • 2021
  • Recently hydrogen fuel cell buses have been deployed for the public transportations. In order to introduce buses fueled by hydrogen successfully, the research results of hydrogen bus safety should be discussed and investigated significantly. Especially, Korean government drives research in terms of various applications of hydrogen energy to replace the conventional fuel energy resources and to improve the safety evaluation. Thus it is necessary to examine vehicle crashworthiness under side impact loadings. This study was focused on the simulation result evaluation of full bus model and simplified bus model with hydrogen fuel tank module and mounting system located below floor structure due to the significance of bus side impact accidents. The finite element models of hydrogen bus, fuel tank system and side impact moving barrier were set up and simulation results reported model performance and result comparison of two side impact models. Computational results and research discussion showed the conceptual side impact framework to evaluate hydrogen bus crashworthiness.

Element Analysis related to Mobility and Stability of ZTO Thin Film using the CO2 Gases (이산화탄소를 이용한 ZTO 박막의 이동도와 안정성분석)

  • Oh, Teresa
    • Korean Journal of Materials Research
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    • v.28 no.12
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    • pp.758-762
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    • 2018
  • The transfer characteristics of zinc tin oxide(ZTO) on silicon dioxide($SiO_2$) thin film transistor generally depend on the electrical properties of gate insulators. $SiO_2$ thin films are prepared with argon gas flow rates of 25 sccm and 30 sccm. The rate of ionization of $SiO_2$(25 sccm) decreases more than that of $SiO_2$(30 sccm), and then the generation of electrons decreases and the conductivity of $SiO_2$(25 sccm) is low. Relatively, the conductivity of $SiO_2$(30 sccm) increases because of the high rate of ionization of argon gases. Therefore, the insulating performance of $SiO_2$(25 sccm) is superior to that of $SiO_2$(30 sccm) because of the high potential barrier of $SiO_2$(25 sccm). The $ZTO/SiO_2$ transistors are prepared to research the $CO_2$ gas sensitivity. The stability of the transistor of $ZTO/SiO_2$(25 sccm) as a high insulator is superior owing to the high potential barrier. It is confirmed that the electrical properties of the insulator in transistor devices is an important factor to detect gases.

Study on Safety Evaluation Process for Hydrogen Storage System of Hydrogen Bus (수소버스 수소저장용기의 측면충돌 안전성 평가방법 연구)

  • Kyungjin, Kim;Jaeho, Shin;Kyeonghee, Han;Hyeon Min, Han;Jeong Min, In;Siwoo, Kim
    • Journal of Auto-vehicle Safety Association
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    • v.14 no.4
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    • pp.113-119
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    • 2022
  • The structural safety of hydrogen buses is being evaluated for the successful introduction of hydrogen buses. The crash test methodology, for example, side impact test procedure is being discussed for hydrogen bus structure safety with a compressed hydrogen storage system located under the bus floor. Thus this study describes a new experiment method for side impact test with compressed hydrogen storage system independently based on finite element analysis instead of side impact test using full hydrogen bus. A side crash procedure of conceptual compressed hydrogen storage structure was investigated and impact simulations were performed. The finite element models of hydrogen bus, simplified structures, fuel tank system and side impact moving barrier were set up and simulation results reported model performance and result comparison of three different simplified models. Computational results and research discussion proposed the fundamental test framework for safety assessment of the compressed hydrogen storage system.

Densification of matrix graphite for spherical fuel elements used in molten salt reactor via addition of green pitch coke

  • He, Zhao;Zhao, Hongchao;Song, Jinliang;Guo, Xiaohui;Liu, Zhanjun;Zhong, Yajuan;Marrow, T. James
    • Nuclear Engineering and Technology
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    • v.54 no.4
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    • pp.1161-1166
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    • 2022
  • Green pitch coke with an average particle size of 2 mm was adopted as densifier and added to the raw materials of conventional A3-3 matrix graphite (MG) to prepare modified A3-3 matrix graphite (MMG) by the quasi-isostatic molding method. The structure, mechanical and thermal properties were assessed. Compared with MG, MMG had a more compact structure, and exhibited improved properties of higher mechanical strength, higher thermal conductivity and better molten salt barrier performance. Notably, under the same infiltration pressure of 5 atm, the fluoride salt occupation of MMG was only 0.26 wt%, whereas it was 15.82 wt% for MG. The densification effect of green pitch coke endowed MMG with improved properties for potential use in the spherical fuel elements of molten salt reactor.

Metabolites of Latilactobacillus curvatus BYB3 and Indole Activate Aryl Hydrocarbon Receptor to Attenuate Lipopolysaccharide-Induced Intestinal Barrier Dysfunction

  • Wang, Xing;Yong, Cheng Chung;Oh, Sejong
    • Food Science of Animal Resources
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    • v.42 no.6
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    • pp.1046-1060
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    • 2022
  • This study aimed to investigate the effects of the metabolites of Latilactobacillus curvatus BYB3 and indole-activated aryl hydrocarbon receptor (AhR) to increase the tight junction (TJ) proteins in an in vitro model of intestinal inflammation. In a Western blot assay, the metabolites of L. curvatus BYB3 reduced the TJ demage in lipoploysaccharide (LPS) stimulated-Caco-2 cells. This reduction was a result of upregulating the expression of TJ-associated proteins and suppressing the nuclear factor-κB signaling. Immunofluorescence images consistently revealed that LPS disrupted and reduced the expression of TJ proteins, while the metabolites of L. curvatus BYB3 and indole reversed these alterations. The protective effects of L. curvatus BYB3 were observed on the intestinal barrier function when measuring transepithelial electrical resistance. Using high-performance liquid chromatography analysis the metabolites, the indole-3-latic acid and indole-3-acetamide concentrations were found to be 1.73±0.27 mg/L and 0.51±0.39 mg/L, respectively. These findings indicate that the metabolites of L. curvatus BYB3 have increasing mRNA expressions of cytochrome P450 1A1 (CYP1A1) and AhR, and may thus be applicable for therapy of various inflammatory gut diseases as postbiotics.