• Title/Summary/Keyword: band gap engineering

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Photocatalysts for Hydrogen Production from Solar Water Splitting (태양광을 활용한 물분해 수소생산용 광촉매재료)

  • Kim, Jung Hyeun
    • Clean Technology
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    • v.19 no.3
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    • pp.191-200
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    • 2013
  • Researches on developing photocatalyst materials for hydrogen production from solar water splitting attract great attentions due to the unlimited and clean characteristics of the solar energy. In this review, photocatalysts used for hydrogen production from the solar water splitting are discussed in terms of material characteristics. In addition, various modification techniques applied to the photocatalysts for improving hydrogen production efficiency are summarized. Finally, light characteristics such as intensity, illumination density and wavelength cutoff are also discussed for the importance of hydrogen production rate.

Annealing Effects of Tunneling Dielectrics Stacked $SiO_2/Si_3N_4$ Layers for Non-volatile Memory (비휘발성 메모리를 위한 $SiO_2/Si_3N_4$ 적층 구조를 갖는 터널링 절연막의 열처리 효과)

  • Kim, Min-Soo;Jung, Myung-Ho;Kim, Kwan-Su;Park, Goon-Ho;Jung, Jong-Wan;Chung, Hong-Bay;Cho, Won-Ju
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.128-129
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    • 2008
  • The annealing effects of $SiO_2/Si_3N_4$ stacked tunneling dielectrics were investigated. I-V characteristics of band gap engineered tunneling gate stacks consisted of $Si_3N_4/SiO_2/Si_3N_4$(NON), $SiO_2/Si_3N_4/SiO_2$(ONO) dielectrics were evaluated and compared with $SiO_2$ single layer using the MOS(Metal-Oxide-Semiconductor) capacitor structure. The leakage currents of engineered tunneling barriers (ONO, NON stacks) are lower than that of the conventional $SiO_2$ single layer at low electrical field. Meanwhile, the engineered tunneling barriers have larger tunneling current at high electrical field and improved electrical characteristics by annealing processes than $SiO_2$ layer.

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Growth of MnS Thin Film on c-Sapphire by Pulsed Laser Deposition (PLD 법에 의한 c-사파이어 기판위의 MnS 박막성장)

  • Song, Jeong-Hwan
    • Korean Journal of Materials Research
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    • v.17 no.9
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    • pp.475-479
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    • 2007
  • Pulsed laser deposition was utilized to grow MnS thin films on c-sapphire substrate using a KrF excimer laser at growth temperatures that ranged from room temperature to $700^{\circ}C$. The results of X-ray diffraction (XRD) and UV-visible spectroscopy were employed to investigate the structural and optical properties of the MnS films. While the growth rate decreased as $T_s$ increased, the overall quality of the film improved. The highest quality MnS film was obtained at $700^{\circ}C$. Variations in the $T_s$ resulted in the MnS films exhibiting different growth mechanisms. The oriented (200) rocksalt MnS film was grown at room temperature. In the case of higher $T_s,\;200{\sim}500^{\circ}C$, the films consisted of mixed phases of rocksalt and wurtzite. The main structure of the films was altered to (111) rocksalt when the temperature was increased to in excess of $600^{\circ}C$. This behavior may very well be the result of elements such as surface energy and atomic arrangement during the growth process. The optical band gap of the obtained ${\alpha}-MnS$ film was estimated to be 3.32 eV.

Synthesis of CuSbS2 and CuSbSe2 Nanocrystals by a Mechanochemical Method (기계화학적 방법에 의한 CuSbS2와 CuSbSe2 나노입자의 합성)

  • Park, Bo-In;Lee, Seung Yong;Lee, Doh-Kwon
    • Current Photovoltaic Research
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    • v.5 no.4
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    • pp.140-144
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    • 2017
  • $CuSbS_2$ (CAS) and $CuSbSe_2$ (CASe) nanocrystals (NCs), which consist of earth-abundant elements, were synthesized by a mechanochemical method. Elemental precursors such as copper, antimony, sulfur, and selenium were used without adding any organic solvents or additives. The NCs were synthesized by milling for a few hours. The sudden phase changes occurred by self-ignition and propagation, as previously observed in other mechanochemical synthetic processes. The XRD, Raman, and TEM analysis were carried out to determine the crystallinity and secondary phase of the as-synthesized CAS and CASe NCs, confirming the phase-pure synthesis of CAS and CASe. Optical properties were investigated by UV-Vis spectroscopy and it was observed that the band gap energies were about 1.1 and 1.5 eV, respectively for CAS and CASe, suggesting the potential for the use as solar cell materials. The NC colloids dispersed in anhydrous ethanol were prepared and coated on Mo substrates by a facile doctor-blade method. The investigation on the solar cell properties of the as-synthesized materials is underway.

A Study on a Capacitively Coupled Microstrip Array Antenna (용량성 결합 마이크로스트립 배열 안테나에 대한 연구)

  • Lee, Jong-Ig;Yeo, Junho;Baek, Woon-Seok
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2015.10a
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    • pp.63-64
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    • 2015
  • In this paper, a microstrip array antenna capacitively coupled to a microstrip line is studied. The array antenna consists of uniformly spaced rectangular microstrip patches arranged close to a feeding microstrip line on a grounded dielectric substrate. The effects of various parameters, such as strip width and length, distance between adjacent patches, gap between strip patches and microstrip feed line, on the antenna performance were examined. By properly adjusting geometrical parameters, the array suitable for a high gain antenna for use in a frequency band centered at 12.5 GHz was designed.

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5.25-GHz BiCMOS Low Noise Amplifier (5.25-GHz BiCMOS 저 잡음 증폭기)

  • Sung, Myeong-U;Rastegar, Habib;Choi, Geun-Ho;Kim, Shin-Gon;Kurbanov, Murod;Chandrasekar, Pushpa;Kil, Keun-Pil;Ryu, Jee-Youl;Noh, Seok-Ho;Yoon, Min
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2016.05a
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    • pp.691-692
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    • 2016
  • 본 논문은 802.11a 무선 랜용 5.25-GHz BiCMOS 저 잡음 증폭기를 제안한다. 이러한 회로는 1볼트 전원에서 동작하며, 저 전압 전원 공급에서도 높은 전압 이득을 가지도록 설계하였다. 제안한 회로는 $0.18{\mu}m$ SiGe HBT BiCMOS로 설계되어 있다. 저 전압 및 저 전력 동작을 위해 바이어스 회로는 밴드 갭 참조 (band-gap reference circuit) 바이어스 회로를 사용하였다. 제안한 회로는 최근 발표된 연구결과에 비해 높은 전압이득, 낮은 잡음지수 및 작은 칩 크기 특성을 보였다.

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The Synthesis of CuInS2 Nanoparticles by a Simple Sonochemical Method

  • Park, Jae-Young;Park, Jong-Pil;Hwang, Cha-Hwan;Kim, Ji-Eon;Choi, Myoung-Ho;Ok, Kang-Min;Kwak, Ho-Young;Shim, Il-Wun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.11
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    • pp.2713-2716
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    • 2009
  • $CuInS_{2}$ nanoparticles were synthesized by a simple sonochemical method; First, Cu nanoparticles were prepared from $CuInS_{2}$ in methanol solution by a one pot reaction through the sonochemistry under multibubble sonoluminescence (MBSL) conditions. Second, the resulting Cu nanoparticles were treated with $InCl_3{\cdot}4H_2O$ and $CH_3CSNH_2$ (thioacetamide) at the same MBSL conditions to synthesize $In_2S_3$-coated Cu nanoparticles in methanol solution. Then, they were transformed into $CuInS_{2}$ (CIS) nanoparticles of 20 $\sim$ 40 nm size in diameter by thermal heating at 300 ${^{\circ}C}$ for 2 hr. The prepared CIS nanoparticles, of which band gap is 1.44 eV, were investigated by X-ray diffractometer, UV-Vis spectrophotometer, inductively coupled plasma spectrometer, and high resolution-transmission electron microscope.

Study on the Relationship between the Forest Canopy Closure and Hyperspectral Signatures

  • Lin, Chinsu;Chang, Chein-I
    • Proceedings of the KSRS Conference
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    • 2003.11a
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    • pp.72-74
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    • 2003
  • Forest canopy density is an ideal representative of the forest habitat situations. It can directly or indirectly depict the canopy structure and gap size in the forestland, thus could be applied to assessment of wildlife’s diversit y. Since population survey of vegetation and wildlife diversities is a key issue for sustainable forest ecosystem management, many research efforts have been focused on forest canopy density using multispectral data in the last two decades. Unfortunately, prediction of canopy density using large scaling remote sensing data remains a challenging issue. Due to recent advances in hyperspectral image sensors hyperspectral imagery is now available for environmental monitoring. In this paper, we conduct experiments to monitor complicated environments of forestland that can be captured by using hyperspectral imagery and further be analyzed to test a prediction model of forest canopy density. The results show that 95% of canopy density could be well described by using 2 difference vegetation indices (DVIs), which are difference of blue and green reflectances rband_100-rband_150 and difference of 2 short wave infrared reflectancse rband_406-rband_410 With the wavelengths of band no. 100, 150, 406, and 410 specified by 462.39 nm, 534.40 nm, 918.22 nm and 924.41 nm respectively.

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Design of Wideband Loop Antenna for UWB Applications (UWB 응용을 위한 광대역 루프 안테나 설계)

  • Yeo, Junho;Lee, Jong-Ig
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2014.05a
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    • pp.49-50
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    • 2014
  • In this paper, a wideband loop antenna for UWB applications is studied. The proposed wideband loop antenna consists of a circular loop and circular sectors. Circular sectors with a ultra-wideband characteristic are used to connect the circular loop and the center feed points. Optimal design parameters are obtained by analyzing the effects of the gap between the circular sectors and the radius of the circular loop on the input reflection coefficient and gain characteristics. The optimized wideband loop antenna is fabricated on an FR4 substrate with a dimension of $41mm{\times}41mm$. Experimental results show that the antenna has a desired UWB characteristic with a frequency band of 3.1-11.0 GHz for a VSWR < 2.25.

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Comparative Study of Undoped and Nickel-Doped Molybdenum Oxide Photoanodes for PEC Water Splitting

  • Garcia-Garcia, Matias
    • Journal of Electrochemical Science and Technology
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    • v.13 no.3
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    • pp.377-389
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    • 2022
  • The current global energy supply depends heavily on fossil fuels. This makes technology such as direct water splitting from harvesting solar energy in photoelectrochemical (PEC) systems potentially attractive due to its a promising route for environmentally benign hydrogen production. In this study, undoped and nickel-doped molybdenum oxide photoanodes (called photoanodes S1 and S2 respectively) were synthesized through electrodeposition by applying -1.377 V vs Ag/AgCl (3 M KCl) for 3 hours on an FTO-coated glass substrate immersed in molibdatecitrate aqueous solutions at pH 9. Scanning electron microscopy (SEM), atomic force microscopy (AFM), energy-dispersive X-ray spectroscopy (EDS), and X-ray photoelectron spectroscopy (XPS) were used for microstructural and compositional characterizations of the photoanodes. In addition, the optical and photoelectrochemical characterizations of these photoanodes were performed by UV-Visible spectroscopy, and linear scanning voltammetry (LSV) respectively. The results showed that all the photoanodes produced exhibit conductivity and catalytic properties that make them attractive for water splitting application in a photoelectrochemical cell. In this context, the photoanode S2 exhibited better photocatalytic activity than the photoanode S1. In addition, photoanode S2 had the lowest optical band-gap energy value (2.58 eV), which would allow better utilization of the solar spectrum.