• Title/Summary/Keyword: back diffusion

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A Moisture Diffusivity Model of Hardening Concrete (경화하는 콘크리트의 수분확산도 모형)

  • Jeong, Jin-Hoon
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.31-38
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    • 2005
  • Concrete has higher vapor pressure than its surrounding ambient air immediately after placement. Moisture at concrete surface evaporates to the ambient air to adjust equilibrium of the vapor pressure between them. The moisture inside the concrete moves to the surface because the evaporation at the surface causes gradient of vapor pressure inside the concrete. Plastic cracking, degree of hydration, strength development, and others caused by velocity of the moisture movement significantly influences quality of concrete. In this paper, the moisture diffusivity of early-age concrete was back-calculated using governing equation of the moisture diffusion, and temperature and relative humidity of concrete measured in a laboratory. The moisture diffusivity of the concrete was modeled using the back-calculated moisture diffusivity. The relative humidity of the concrete calculated by finite element method (FEM) using the modeled moisture diffusivity as Input data coincided with the measured relative humidity well.

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Pt/Al Reaction Mechanism in the FeRAM Device Integration (FeRAM 소자 제작 중에 발생하는 Pt/Al 반응 기구)

  • Cho Kyoung-Won;Hong Tae-Whan;Kweon Soon-Yong;Choi Si-Kyong
    • Korean Journal of Materials Research
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    • v.14 no.10
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    • pp.688-695
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    • 2004
  • The capacitor contact barrier(CCB) layers have been introduced in the FeRAM integration to prevent the Pt/Al reaction during the back-end processes. Therefore, the interdiffusion and intermetallic formation in $Pt(1500{\AA})/Al(3000{\AA})$ film stacks were investigated over the annealing temperature range of $100\sim500^{\circ}C$. The interdiffusion in Pt/Al interface started at $300^{\circ}C$ and the stack was completlely intermixed after annealing over $400^{\circ}C$ in nitrogen ambient for 1 hour. Both XRD and SBM analyses revealed that the Pt/Al interdiffusion formed a single phase of $RtAl_2$ intermetallic compound. On the other hand, in the presence of TiN($1000{\AA}$) barrier layer at the Pt/Al interface, the intermetallic formation was completely suppressed even after the annealing at $500^{\circ}C$. These were in good agreement with the predicted effect of the TiN diffusion barrier layer. But the conventional TiN CCB layer could not perfectly block the Pt/Al reaction during the back-end processes of the FeRAM integration with the maximum annealing temperature of $420^{\circ}C$. The difference in the TiN barrier properties could be explained by the voids generated on the Pt electrode surface during the integration. The voids were acted as the starting point of the Pt/Al reaction in real FeRAM structure.

Validation of spent nuclear fuel decay heat calculation by a two-step method

  • Jang, Jaerim;Ebiwonjumi, Bamidele;Kim, Wonkyeong;Park, Jinsu;Choe, Jiwon;Lee, Deokjung
    • Nuclear Engineering and Technology
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    • v.53 no.1
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    • pp.44-60
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    • 2021
  • In this paper, we validate the decay heat calculation capability via a two-step method to analyze spent nuclear fuel (SNF) discharged from pressurized water reactors (PWRs). The calculation method is implemented with a lattice code STREAM and a nodal diffusion code RAST-K. One of the features of this method is the direct consideration of three-dimensional (3D) core simulation conditions with the advantage of a short simulation time. Other features include the prediction of the isotope inventory by Lagrange non-linear interpolation and the use of power history correction factors. The validation is performed with 58 decay heat measurements of 48 fuel assemblies (FAs) discharged from five PWRs operated in Sweden and the United States. These realistic benchmarks cover the discharge burnup range up to 51 GWd/MTU, 23.2 years of cooling time, and spanning an initial uranium enrichment range of 2.100-4.005 wt percent. The SNF analysis capability of STREAM is also employed in the code-to-code comparison. Compared to the measurements, the validation results of the FA calculation with RAST-K are within ±4%, and the pin-wise results are within ±4.3%. This paper successfully demonstrates that the developed decay heat calculation method can perform SNF back-end cycle analyses.

Fabrication and Operating Properties of Nb Silicide-coated Si-tip Field Emitter Arrays (니오비움 실리사이드가 코팅된 실리콘 팁 전계 방출 소자의 제조 및 동작 특성)

  • Ju, Byeong-Kwon;Park, Jae-Seok;Lee, Sangjo;Kim, Hoon;Lee, Yun-Hi;Oh, Myung-Hwan
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.7
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    • pp.521-524
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    • 1999
  • Nb silicide was formed on the Si micro-tip arrays in order to improve field emission properties of Si-tip field emitter array. After silicidization of the tips, the etch-back process, by which gate insulator, gate electrode and photoresist were deposited sequentially and gate holes were defined by removing gradually the photoresist by $O_2$ plasma from the surface, was applied. Si nitride film was used as a protective layer in order to prevent oxygen from diffusion into Nb silicide layer and it was identified that the NbSi2 was formed through annealing in $N_2$ ambient at $1100^{\circ}C$ for 1 hour. By the Nb silicide coating on Si tips, the turn-on voltage was decreased from 52.1 V to 32.3 V and average current fluctuation for 1 hour was also reduced from 5% to 2%. Also, the fabricated Nb silicide-coated Si tip FEA emitted electrons toward the phosphor and light emission was obtained at the gate voltage of 40~50 V.

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Prediction of Fuel Cell Performance and Water Content in the Membrane of a Proton Exchange Membrane Fuel Cell (고분자 전해질 연료전지의 전해질 막내의 함수율과 성능 예측)

  • Yang, Jang-Sik;Choi, Gyung-Min;Kim, Duck-Jool
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.151-159
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    • 2006
  • A one-dimensional numerical analysis is carried out to investigate the effects of inlet gas humidities, inlet gas pressures, and thicknesses of membrane on the performance of a proton exchange membrane fuel cell. It is found that the relative humidity of inlet gases at anode and cathode sides has a significant effect on the fuel cell performance. Especially, the desirable fuel cell performance occurs at low relative humidity of the cathode side and at high humidity of the anode side. In addition, an increase in the pressure ranging from 1 atm to 4 atm at the cathode side results in a significant improvement in the fuel cell performance due to the convection effect by a pressure gradient toward the anode side, and with decreasing the thickness of membrane, the fuel cell performance is enhanced reasonably.

EFFECTS OF WATERY VAPOR CONCENTRATION ON DROPLET EVAPORATION IN HOT ENVIRONMENT

  • Lee, M.J.;Kim, Y.W.;Ha, J.Y.;Chung, S.S.
    • International Journal of Automotive Technology
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    • v.2 no.3
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    • pp.109-115
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    • 2001
  • A study has been conducted to clarify the effect of watery vapor concentration in hot ambient on droplet evaporation. Droplets of water, ethanol, n-hexadecaneand n-heptane were used in this experimental study. Ambient conditions are fixed at 470 K in temperature, 0.1 MPa in pressure and 2 m/s in velocity of ambient air. Watery vapor concentration was changed 0%~40% by 10% by add water to air. To obtain the time histories of droplet diameter after exposed in ambient, a suspended droplet in hot and humid ambient stream was synchronized with a back flash light, and enlarged droplet images were taken by a CCD camera. The evaporation rate constant of water droplet decreases slightly with the vapor concentration because diffusion velocity reduction of droplet vapor occurs on the surface. The values of ethanol and n-heptane droplet actively increase by effect that water from condensation of vapor flows into the droplet. The evaporation rate constant of n-hexadecane which has higher boiling point than water increases within around 30% of the concentration.

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Evolution of Public Library from Information Commons to Learning Commons - The Cases of Japan Public Library - (도서관 정보코먼스에서 러닝코먼스로의 진화 - 일본 공공도서관의 러닝코먼스화 사례를 중심으로 -)

  • Lim, Hyung-Yeon
    • Journal of Korean Library and Information Science Society
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    • v.45 no.3
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    • pp.441-462
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    • 2014
  • The purpose of this study is to analyze the concept of information commons and learning commons that has emerged in recent years, and point out the difference between the two concepts, as well as its implications for public libraries, which get lessons learned from learning commons at Japanese public libraries. To track its evolution to learning commons, the theoretical component of learning commons was analyzed. Based on the reference, a research framework for the case study of learning commons was developed. With IT technology diffusion, libraries have become information commons. However, the main mission of libraries should basically remain as learning. Because of this, libraries which function as information commons should go back to being learning commons, which are primarily places of learning. This research shows that libraries should stress its original basic mission which is learning, beyond being information commons in the Japanese library.

An Experimental Study on the Quality Deviation of Concrete Using Premixed Cement and Non-Premixed Cement (프리믹스 혼합시멘트를 사용한 콘크리트의 품질편차에 관한 연구)

  • Bae, Jun-Young;Kim, Jong-Back;Cho, Sung-Hyun;Roh, Hyeon-Seung;Kim, Jung-Hwan;Park, Seung-Bum
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.569-572
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    • 2008
  • This study carried out to evaluate the quality deviation according to Premixed and Non-Premixed cement for normal and high strength concrete using blast furnace slag and fly ash. The results of experiment are founded that concrete using premixed cement have more performance than non-premixed cement at a point of view for the quality deviations both strength and Chloride ion diffusion. Therefore, it is desirable that premixed cement should be used to decrease strength deviation in high strength concrete and durability deviation in normal strength concrete.

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Neural Network Modeling of PECVD SiN Films and Its Optimization Using Genetic Algorithms

  • Han, Seung-Soo
    • International Journal of Fuzzy Logic and Intelligent Systems
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    • v.1 no.1
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    • pp.87-94
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    • 2001
  • Silicon nitride films grown by plasma-enhanced chemical vapor deposition (PECVD) are useful for a variety of applications, including anti-reflecting coatings in solar cells, passivation layers, dielectric layers in metal/insulator structures, and diffusion masks. PECVD systems are controlled by many operating variables, including RF power, pressure, gas flow rate, reactant composition, and substrate temperature. The wide variety of processing conditions, as well as the complex nature of particle dynamics within a plasma, makes tailoring SiN film properties very challenging, since it is difficult to determine the exact relationship between desired film properties and controllable deposition conditions. In this study, SiN PECVD modeling using optimized neural networks has been investigated. The deposition of SiN was characterized via a central composite experimental design, and data from this experiment was used to train and optimize feed-forward neural networks using the back-propagation algorithm. From these neural process models, the effect of deposition conditions on film properties has been studied. A recipe synthesis (optimization) procedure was then performed using the optimized neural network models to generate the necessary deposition conditions to obtain several novel film qualities including high charge density and long lifetime. This optimization procedure utilized genetic algorithms, hybrid combinations of genetic algorithm and Powells algorithm, and hybrid combinations of genetic algorithm and simplex algorithm. Recipes predicted by these techniques were verified by experiment, and the performance of each optimization method are compared. It was found that the hybrid combinations of genetic algorithm and simplex algorithm generated recipes produced films of superior quality.

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Preparation of Antiserum against Hemolysin from Vibrio vulnificus using Hemolysin-bound Liposomes (Liposome을 이용한 Vibrio vulnificus가 생산하는 용혈독소의 항혈청 제조법)

  • 김영만
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.22 no.1
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    • pp.91-95
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    • 1993
  • To investigate hemolysin from Vibrio vulnificus in terms of protein chemistry and immunochemistvy, the simple method to produce antiserum was developed as follows ; Crude hemolysin from Vibrio vulnificus was mixed with cholesterol-phosphatidylcholine-liposome. Only hemolysin with molecular weight of 50kD was selertively bound to the liposome. Thus, without purification of crude hemolysin, liposome bound hemolysin was used as antigen to produce antiserum by injecting into back muscle of a rabbit. Resultant antiserum reacted only with hemolysin. Hemouysin of Vibrio vulnificus from patients and environment was formed single band in gel diffusion precipitation reaction with antiserum.

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