• Title/Summary/Keyword: arrhenius model

Search Result 240, Processing Time 0.025 seconds

Study on the Generalization of the Equivalent Point Method for Thermal Evaluation (Equivalent Point Method의 일반적 이용을 위한 연구)

  • Rhim, Jong-Whan
    • Korean Journal of Food Science and Technology
    • /
    • v.22 no.5
    • /
    • pp.575-581
    • /
    • 1990
  • The existence of the equivalent point for a thermal processing system was demonstrated using arbitrarily chosen ideal direct heating curves. i.e. isothermal heating curves at $120^{\circ}C$ for 10min and at $135^{\circ}C$ for 10sec. Under these conditions, G-values and F-values were calculated at various values of Ea- and z-values by applying the Arrhenius and the Bigelow models respectively. The equivalent time and equivalent temperature were determined by both line intersection and linear regression methods. The equivalent points estimated by both the line intersection and the linear regression methods were consistent and their values were the same as the heating time and temperature of the ideal direct heating curves.

  • PDF

Determination of Reorganization Energy from the Temperature Dependence of Electron Transfer Rate Constant for Hydroquinone-tethered Self-assembled Monolayers (SAMs)

  • Park, Won-choul;Hong, Hun-Gi
    • Bulletin of the Korean Chemical Society
    • /
    • v.27 no.3
    • /
    • pp.381-385
    • /
    • 2006
  • The temperature dependence on the electron transfer rate constant $(k_{app})$ for hydroquinone redox center in $H_2Q(CH_2)_n$SH-SAMs (n = 1, 4, 6, 8, 10, and 12) on gold electrode was investigated to obtain reorganization energy $(\lambda)$ using Laviron’s formalism and Arrhenius plot of ln $[k_{app}/T^{1/2}]$ vs. T^{-1} based on the Marcus densityof-states model. All the symmetry factors measured for the SAMs were relatively close to unity and rarely varied to temperature change as expected. The electron tunneling constant $(\beta)$ determined from the dependence of the $k_{app}$ on the distance between the redox center and the electrode surface gives almost the same $\beta$ values which are quite insensitive to temperature change. Good linear relationship of Arrhenius plot for all $H_2Q(CH_2)_n$SH-SAMs on gold electrode was obtained in the temperature range from 273 to 328 K. The slopes n Arrhenius plot deduced that $\lambda$ of hydroquinone moiety is ca. 1.3-1.4 eV irrespectively of alkyl chain length of the electroactive SAM.

TRAFFIC FLOW MODELS WITH NONLOCAL LOOKING AHEAD-BEHIND DYNAMICS

  • Lee, Yongki
    • Journal of the Korean Mathematical Society
    • /
    • v.57 no.4
    • /
    • pp.987-1004
    • /
    • 2020
  • Motivated by the traffic flow model with Arrhenius looka-head relaxation dynamics introduced in [25], this paper proposes a traffic flow model with look ahead relaxation-behind intensification by inserting look behind intensification dynamics to the flux. Finite time shock formation conditions in the proposed model with various types of interaction potentials are identified. Several numerical experiments are performed in order to demonstrate the performance of the modified model. It is observed that, comparing to other well-known macroscopic traffic flow models, the model equipped with look ahead relaxation-behind intensification has both enhanced dispersive and smoothing effects.

Rheological Properties of Dandelion Root Concentrates by Extraction Solvents

  • Lee, Ok-Hwan;Kang, Suk-Nam;Lee, Boo-Yong
    • Food Science and Biotechnology
    • /
    • v.15 no.1
    • /
    • pp.33-38
    • /
    • 2006
  • This study was performed to provide basic rheological data of dandelion root concentrates in order to predict their processing aptitude and usefulness as functional foods material. The hot water and 70% ethanol extracts of dandelion root were concentrated at 5, 20, and 50 Brix, and their static viscosity, dynamic viscosity, and Arrhenius plots were investigated. Almost all hot water concentrates showed the typical flow properties of a pseudoplastic fluid, but evaluation using the power law model indicated that the 70% ethanol concentrates showed a flow behavior close to a Newtonian fluid. The apparent viscosity of hot water and 70% ethanol concentrates decreased with increasing temperature. Yield stresses of hot water and 70% ethanol concentrates by Herschel-Bulkley model application were in the range of 0.026 - 1.368 Pa and 0.022 - 0.238 Pa, respectively. The effect of temperature and concentration on the apparent viscosity was examined by Arrhenius equation. The activation energies of hot water and 70% ethanol concentrates were in the range of $8.762-23.778{\times}10^3\;J/mol{\cdot}kg$ and $3.217-20.384{\times}10^3\;J/mol{\cdot}kg$ with increasing concentration, respectively. Storage (G') and loss (G") moduli were generally increased with increasing frequency. For the 70% ethanol concentrates, G" predominated over G' at all applied frequencies and so they showed the typical flow behavior of a low molecular solution. However, for the hot water concentrates, G' predominated over G" at more than 1.9 rad/sec (cross-over point) and so they showed the typical flow behavior of a macromolecular solution.

Effect of curing conditions on mode-II debonding between FRP and concrete: A prediction model

  • Jiao, Pengcheng;Soleimani, Sepehr;Xu, Quan;Cai, Lulu;Wang, Yuanhong
    • Computers and Concrete
    • /
    • v.20 no.6
    • /
    • pp.635-643
    • /
    • 2017
  • The rehabilitation and strengthening of concrete structures using Fiber-Reinforced Polymer (FRP) materials have been widely investigated. As a priority issue, however, the effect of curing conditions on the bonding behavior between FRP and concrete structures is still elusive. This study aims at developing a prediction model to accurately capture the mode-II interfacial debonding between FRP strips and concrete under different curing conditions. Single shear debonding experiments were conducted on FRP-concrete samples with respect to different curing time t and temperatures T. The J-integral formulation and constrained least square minimization are carried out to calibrate the parameters, i.e., the maximum slip $\bar{s}$ and stretch factor n. The prediction model is developed based on the cohesive model and Arrhenius relationship. The experimental data are then analyzed using the proposed model to predict the debonding between FRP and concrete, i.e., the interfacial shear stress-slip relationship. A Finite Element (FE) model is developed to validate the theoretical predictions. Satisfactory agreements are obtained. The prediction model can be used to accurately capture the bonding performance of FRP-concrete structures.

Transverse and Diagonal Mode Structures of Three-dimensional Detonation Wave (3차원 데토네이션 파의 수평 및 대각선 모드 파면 구조)

  • Cho Deok-Rae;Choi Jeong-Yeol
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • v.y2005m4
    • /
    • pp.343-346
    • /
    • 2005
  • Three dimensional structures of detonation wave propagating through a square-shaped duct were investigated using computational method and parallel processing. Inviscid fluid dynamics equations coupled with $variable-{\gamma}$ formulation and simplified one-step Arrhenius chemical reaction model were analysed by MUSCL-type TVD scheme and four stage Runge-Kutta time integration. The unsteady computational results in three dimension show the detailed mechanism of transverse mode and diagonal mode of detonation wave instabilities resulting same cell length but different cell width in smoked-foil record.

  • PDF

A Basic Study on Fatigue Fracture Model at Elevated Temperatures by the Dimensional Analysis Method (차원해석법에 의한 고온피로 파괴 모델의 기초적 연구)

  • 서창민;김영호;권오헌
    • Journal of Ocean Engineering and Technology
    • /
    • v.6 no.1
    • /
    • pp.105-112
    • /
    • 1992
  • The main purpose of this study is to derive a law of fatigue crack growth rate in the region of elastic or elasto-plastic fracture mechanics at elevated temperatures through the application of dimensional analysis. An equation of elasto-plastic fatigue crack growth rate at elevated temperatures appeared a new Arrhenius type equation containing J-integral range and absolute temperature. The elastic or elasto-plastic crack growth rate equation shows a fairly good agreement with the experimental results for Cr-Mo-V rotor steel and Hastelloy-X alloy in the comparatively wide temperature ranges.

  • PDF

Determining the Safer Thickness of the Epoxy Coating on Wooden Utensils (식품 안전성 확보를 위한 목재 식기용 에폭시 코팅의 두께 결정)

  • 이광수;임동길;김상엽;장미란;김우성;이영자
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.33 no.2
    • /
    • pp.447-450
    • /
    • 2004
  • Overall migration through epoxy layer coated wood was investigated to estimate the coating thickness satisfying the regulatory limit. As an index of overall migration, KMnO$_4$ oxidizable extractives by the food simulant water solution was used. Migration pattern in interest range could described by a simple diffusion model and the temperature dependence of the permeability index could be explained by Arrhenius equation. The thickness of epoxy coating greater than 0.004 mm was analyzed to be required for satisfying the regulatory guideline.

Coupled Analysis of Structure and Surface Ablation in Solid Rocket Nozzle (삭마반응을 고려한 고체 추진기관 노즐 조립체의 열반응 및 구조해석)

  • Kim, Yun-Chul;Doh, Young-Dae;Hahm, Hee-Cheol;Moon, Soon-Il
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2011.11a
    • /
    • pp.565-569
    • /
    • 2011
  • A two-dimensional thermal response and ablation analysis code for predicting charring material ablation and shape change on solid rocket nozzle is presented. For closing the problem of thermo-structural analysis, Arrhenius' equation and Zvyagin's ablation model are used. The moving boundary problem are solved by remeshing-rezoning method. For simulation of complicated thermal protection systems, this method is integrated with a three-dimensional finite-element thermal and structure analysis code.

  • PDF

A Study on the Lifetime Prediction of Device by the Method of Bayesian Estimate (베이지안 추정법에 의한 소자의 수명 예측에 관한 연구)

  • 오종환;오영환
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.19 no.8
    • /
    • pp.1446-1452
    • /
    • 1994
  • In this paper, Weibull distribution is applied to the lifetme distribution of a device. The method of Bayesian estimate used to estimate requiring parameter in order to predict lifetime of device using accelerated lifetime test data, namely failure time of device. The method of Bayesian estimate needs prior information in order to estimate parameter. But this paper proposed the method of parameter estimate without prior information. As stress is temperature, Arrhenius model is applied and the method of linear estimate is applied to predict lifetime of device at the state of normal operation.

  • PDF