• 제목/요약/키워드: anodic oxidation

검색결과 324건 처리시간 0.037초

휘발성 할로겐 화합물(THM)의 양극 산화에 관한 연구 (Studies on the anodic oxidation of some volatile organic halogen compounds(THM))

  • 유광식;박상윤;양성봉;우상범
    • 분석과학
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    • 제10권4호
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    • pp.264-273
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    • 1997
  • 수용액 중의 trihalomethane을 제거하기 위하여 양극 산화반응을 시키고 solid phase microextraction(SPME) fiber로 추출한 다음 GC-ECD로 분석하였다. 반응 용기 내부로 염소이온 등이 오염되는 것을 방지하기 위해 음극과 양극은 $KNO_3$-agar bridge로서 연결시켰다. 6종의 trihalomethane들은 성분에 따라 감도의 차이가 있었지만, 검량선은 수 ppb에서 수백 ppb 범위에서 좋은 직선관계를 보였다. 백금(Pt), 티탄(Ti), 지르코늄(Zr), Ti 금속상에 이리듐(Ir)을 도포시킨 고체 전극, 및 유리질 탄소에 루테늄(Ru)을 도포한 양극들을 사용하여 THM 성분을 제거하려 하였다. 제거효율이 가장 우수한 것은 Ti-Ir 양극으로서, 9V의 전압을 걸었을 때 약 1.5시간 이후에는 모든 성분들이 제거되었음을 알 수 있었다. 다양한 산화상태(mv)의 루테늄으로 유리질 탄소전극을 도포시킨 전극은 초기에는 제거효율이 우수하였으나, 시간이 경과할수록 전극 표면의 훼손으로 인해 제거효율은 약 60% 정도로 감소하였다. 특히 클로로포름은 약간 증가되는 경향을 보임으로써, 이것은 전극반응에 의하여 오히려 재생되는 것으로 생각된다.

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알루미늄 순도 및 표면처리가 나노기공의 형성에 미치는 영향 (Effects of Aluminum purity and surface condition for fabricate Nano-sized Porous using Anodic Oxidation)

  • 이병욱;이재홍;장석원;김창교
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2004년도 하계학술대회 논문집 C
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    • pp.1573-1575
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    • 2004
  • An alumina membrane with nano-sized pores was fabricated by anodic oxidation. The shape and structure of the pore on alumina membrane were changed according to the roughness of aluminum surface. The shape and structure of the nano-sized pre were investigated according to purity of aluminum substrate for the anodization process. The aluminum substrates with 99.5% and 99.999% purities were used. The aluminum substrate(99.5%) was anodized after the processes of pressing, mechanical polishing, chemical polishing, and electrochemical polishing. The nano-sized pores with the pore size of 50 - 100nm, the cell size of 20-50nm and the thickness of $10{\mu}m{\sim}45{\mu}m$ were obtained. Even though the electrochemical polishing was used for the aluminum substrate (99.999%), the same characteristics as the aluminum substrate (99.5%) was obtained. The alumina membrane prepared by anodization for 5 min using fixed voltage method shows the pore with irregular shape. The pore shape was changed to regular shape after pore widening process.

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AFM을 이용한 나노 패턴 형성과 크기에 따른 광특성 시뮬레이션 (Simulations of Optical Characteristics according to the Silicon Oxide Pattern Distance Variation using an Atomic Force Microscopy (AFM))

  • 황민영;문경숙;구상모
    • 한국전기전자재료학회논문지
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    • 제23권6호
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    • pp.440-443
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    • 2010
  • We report a top-down approach based on atomic force microscopy (AFM) local anodic oxidation for the fabrication of the nano-pattern field effect transistors (FETs). AFM anodic oxidation is relatively a simple process in atmosphere at room temperature but it still can result in patterns with a high spatial resolution, and compatibility with conventional silicon CMOS process. In this work, we study nano-pattern FETs for various cross-bar distance value D, from ${\sim}0.5\;{\mu}m$ to $1\;{\mu}m$. We compare the optical characteristics of the patterned FETs and of the reference FETs based on both 2-dimensional simulation and experimental results for the wavelength from 100 nm to 900 nm. The simulated the drain current of the nano-patterned FETs shows significantly higher value incident the reference FETs from ${\sim}1.7\;{\times}\;10^{-6}A$ to ${\sim}2.3\;{\times}\;10^{-6}A$ in the infrared range. The fabricated surface texturing of photo-transistors may be applied for high-efficiency photovoltaic devices.

Performances of Metallic (sole, composite) and Non-Metallic Anodes to Harness Power in Sediment Microbial Fuel Cells

  • Haque, Niamul;Cho, Daechul;Kwon, Sunghyun
    • Environmental Engineering Research
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    • 제19권4호
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    • pp.363-367
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    • 2014
  • One chambered sediment microbial fuel cell (SMFC) was equipped with Fe, brass (Cu/Zn), Fe/Zn, Cu, Cu/carbon cloth and graphite felt anode. Graphite felt was used as common cathode. The SMFC was membrane-less and mediator-less as well. Order of anodic performance on the basis of power density was Fe/Zn ($6.90Wm^{-2}$) > Fe ($6.03Wm^{-2}$) > Cu/carbon cloth ($2.13Wm^{-2}$) > Cu ($1.13Wm^{-2}$) > brass ($Cu/Zn=0.24Wm^{-2}$) > graphite felt ($0.10Wm^{-2}$). Fe/Zn composite anode have twisted 6.73% more power than Fe alone, Cu/carbon cloth boosted power production by 65%, and brass (Cu/Zn) produced 65% less power than Cu alone. Graphite felt have shown the lowest electricity generation because of its poor galvanic potential. The estuarine sediment served as supplier of oxidants or electron producing microbial flora, which evoked electrons via a complicated direct microbial electron transfer mechanism or making biofilm, respectively. Oxidation reduction was kept to be stationary over time except at the very initial period (mostly for sediment positioning) at anodes. Based on these findings, cost effective and efficient anodic material can be suggested for better SMFC configurations and stimulate towards practical value and application.

FIPOS 기술을 이용한 SOI 구조의 실온제조 (SOI Structures Formed at Room Temperature Using FIPOS Technique)

  • 최광돈;이종현;손병기;신종욱
    • 대한전자공학회논문지
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    • 제25권11호
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    • pp.1304-1314
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    • 1988
  • Porous실리콘 形成反應에서 HF濃度, 電流應度, 反應時間 및 基叛의 表面狀態가 PSL (Porous Silicon Layers)의 porosity에 미치는 影響을 실험적으로 조사하였다. PSL을 陽배化 시켜서 室溫에서 FIPPOS-SOI를 제조하는 방법을 연구하였다. 이 방법으로 100um폭의 SOI strip line을 제조하였으며 SOI의 stress제거를 위해 2단계 PSL 형성법을 이용하였다. 또한 이 실온 SOI 제조기술을 이용하여 이미 소자공정을 끝낸 집적회로를 SOI화 시킬 수 있는 방법을 제안하였다.

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