• Title/Summary/Keyword: advanced oxidation process

Search Result 365, Processing Time 0.023 seconds

The improvement of electrical properties of InGaZnO (IGZO)4(IGZO) TFT by treating post-annealing process in different temperatures.

  • Kim, Soon-Jae;Lee, Hoo-Jeong;Yoo, Hee-Jun;Park, Gum-Hee;Kim, Tae-Wook;Roh, Yong-Han
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.169-169
    • /
    • 2010
  • As display industry requires various applications for future display technology, which can guarantees high level of flexibility and transparency on display panel, oxide semiconductor materials are regarded as one of the best candidates. $InGaZnO_4$(IGZO) has gathered much attention as a post-transition metal oxide used in active layer in thin-film transistor. Due to its high mobility fabricated at low temperature fabrication process, which is proper for application to display backplanes and use in flexible and/or transparent electronics. Electrical performance of amorphous oxide semiconductors depends on the resistance of the interface between source/drain metal contact and active layer. It is also affected by sheet resistance on IGZO thin film. Controlling contact/sheet resistance has been a hot issue for improving electrical properties of AOS(Amorphous oxide semiconductor). To overcome this problem, post-annealing has been introduced. In other words, through post-annealing process, saturation mobility, on/off ratio, drain current of the device all increase. In this research, we studied on the relation between device's resistance and post-annealing temperature. So far as many post-annealing effects have been reported, this research especially analyzed the change of electrical properties by increasing post-annealing temperature. We fabricated 6 main samples. After a-IGZO deposition, Samples were post-annealed in 5 different temperatures; as-deposited, $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$, $400^{\circ}C$ and $500^{\circ}C$. Metal deposition was done on these samples by using Mo through E-beam evaporation. For analysis, three analysis methods were used; IV-characteristics by probe station, surface roughness by AFM, metal oxidation by FE-SEM. Experimental results say that contact resistance increased because of the metal oxidation on metal contact and rough surface of a-IGZO layer. we can suggest some of the possible solutions to overcome resistance effect for the improvement of TFT electrical performances.

  • PDF

Development of a Rotating Biological Contactor(RBC) Process for the Advanced Wastewater Treatment (회전원판(回轉圓板) 생물막(生物膜) 공법(工法)을 이용한 하(下)·폐수(廢水)의 고도처리(高度處理) 공정(工程) 개발(開發))

  • Kim, Eung Ho;Park, Jae Lo;Yoon, Jung Ro
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.8 no.2
    • /
    • pp.1-11
    • /
    • 1994
  • This study was conducted to develop a new RBC process available for the effective removal of organic matters and nitrogen in sewage. The RBC process for the oxidation organic compounds and nitrification was designed to occur at the 1st-stage and next-stage RBC respectively. Then nitrified water was recycled to the denitrifying RBC located at the lower part of the 1st-stage RBC. Some results were summarized as follows. 1. The loading limitation was represented as $60g{\cdot}COD/gm^2/day$ in experiment of simultaneous removal of organic matter and nitrogen. The maxmum COD % removal was 85% at the load $35g{\cdot}COD/m^2/day$. 2. The $NO_3-N$ % removal was approximately 80% at the load $60g{\cdot}COD/m^2/day$ and the maximum $NO_3-N$ remaval rate was $3.9g{\cdot}COD/m^2/day$ and the overall C/N ratio of 11.0 as required to achive 80% of $NO_3-N$% removal. 3.$NO_3-N$ removal rate was rapidly decreased above the load $7g{\cdot}NH_4{^+}-N/m^2/day$ and the maximum $NO_3-N$ removal rate was $3.7g{\cdot}NO_3-N/m^2/day$. 4. Irrespective of the recycle ratio, the COD % removal at the system of 2-stage RBC unit was nearly constant as 89% while the maximum one in the 1st-stage unit was 77% in the case of 50% recycle. 5. The maximum COD % removal in the 3-stage RBC system was 93% while 1st-stage one being 80%, under the $NH_4{^+}-N$ load of $7.4g/m^2{\cdot}d$. Also maximum percentage of nitrification and denitrification was 69% and 41% respectively, under the same $NH_4{^+}-N$ load.

  • PDF

Analysis of Soot Particle Morphology Using Rayleigh Debye Gans Scattering Theory (RDG 산란 이론을 이용한 그을음 탄소 입자의 형상 분석)

  • Seo, Hyoungseock;Kim, Kibum
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.17 no.9
    • /
    • pp.641-646
    • /
    • 2016
  • Soot particles generated by fossil fuel combustion normally have fractal morphology with aggregates consisting of small spherical particles. Thus, Rayleigh or Mie elastic light scattering theory is not feasible for determining the fractal properties of soot aggregates. This paper describes a detailed process for applying Rayleigh-Debye Gans (RDG) scattering theory to effectively extract the morphological properties of any nano-scale particles. The fractal geometry of soot aggregates produced from an isooctane diffusion flame was observed using ex situ transmission electron microscopy (TEM) after thermophoretic sampling. RDG scattering theory was then used to analyze their fractal morphology, and various properties were calculated, such as the diameter of individual soot particles, number density, and volume fraction. The results show indiscernible changes during the soot growth process, but a distinct decreasing trend was observed in the soot oxidation process. The fractal dimension of the soot aggregates was determined to be around 1.82, which is in good agreement with that produced for other types of fuel. Thus, it can be concluded that the value of the fractal dimension is independent of the fuel type.

Engineering and Economic Evaluation of Production of MgO Nanoparticles using a Physicochemical Method

  • Priatna, Deri;Nandiyanto, Asep Bayu Dani
    • International journal of advanced smart convergence
    • /
    • v.8 no.4
    • /
    • pp.26-33
    • /
    • 2019
  • We conducted research to evaluate economically and engineering about the synthesis of Magnesium Oxide, MgO, nanoparticles using physicochemical methods. The method used was economic evaluation by calculating GPM, BEP, PBP, and CNPV. The other method used was engineering perspective. MgO nanoparticles were synthesized by reacting Mg(NO3)2 and NaOH with a mole ratio 1: 2. Mg(OH)2 formed was heated and calcined to remove water content and to oxidation to form MgO. An economic evaluation by calculating GPM and CNPV for the production of MgO nanoparticles on an industrial scale shows that the payback period (PBP) occur in the third year and profits increase each year. Tax variations show that the higher of tax, the lower profits received. When there was an increase of selling prices, the profit was greater. The variable cost used is the price of raw material. When there was an increased in the variable cost price, the payback period was longer and the profits was reduced. The benefit of this research is knowing the industrial production of MgO nanoparticles is beneficial. The function of MgO nanoparticles is a material for the manufacture of ceramics and can be used as an antimicrobial in the water filtration process.

HAAs Formation by Chlorine Dose and Reaction Time and The Removal Effect of Precursors by The Advanced Oxidation Processes (염소주입량과 반응시간에 따른 HAAs 생성과 고도산화처리에 의한 전구물질 제거 영향)

  • Kim, Kyoung-Suk;Oh, Byung-Soo;Ju, Seul;Kang, Joon-Wun
    • Journal of Korean Society on Water Environment
    • /
    • v.20 no.2
    • /
    • pp.145-150
    • /
    • 2004
  • This study investigated the effect of chlorine dose and chlorine reaction time for the formation of haloacetic acids (HAAs). According to the results, HAA formation was highly affected by chlorine dose and chlorine reaction time. HAA formation reached a plateau value at 30 mg/L of chlorine dose and 24 hr of chlorine reaction time. For the speciation of formed HAAs in the test water, the concentration of brominated-HAAs was significantly lower than that of chlorinated-HAAs because of low level of bromide ion concentration in the test water. It also investigated the removal efficiency of HAA precursors by several unit processes, such as ozone alone, UV alone, and combined ozone/UV system. Of them, ozone/UV system was proved as the best process to control the HAAs formation. The increase of the brominated-HAAs was observed during ozonation with and without UV irradiation showing the slight increase of total HAA concentrations.

Photocatalytic Degradation of Methyl tert-Butyl Ether (MTBE): A review

  • Seddigi, Zaki S.;Ahmed, Saleh A.;Ansari, Shahid P.;Yarkandi, Naeema H.;Danish, Ekram;Oteef, Mohammed D.Y.;Cohelan, M.;Ahmed, Shakeel;Abulkibash, Abdallah M.
    • Advances in environmental research
    • /
    • v.3 no.1
    • /
    • pp.11-28
    • /
    • 2014
  • Advanced oxidation processes using UV and catalysts like $TiO_2$ and ZnO have been recently applied for the photocatalytic degradation of MTBE in water. Attempts have been made to replace the UV radiation by the solar spectrum. This review intends to shed more light on the work that has been done so far in this area of research. The information provided will help in crystallizing the ideas required to shift the trend from UV photocatalysis to sunlight photocatalysis. The careful optimization of the reaction parameters and the type of the dopant employed are greatly responsible for any enhancement in the degradation process. The advantage of shifting from UV photocatalysts to visible light photocatalysts can be observed when catalysts like $TiO_2$ and ZnO are doped with suitable metals. Therefore, it is expected that in the near future, the visible light photocatalysis will be the main technique applied for the remediation of water contaminated with MTBE.

A Study on the Dye Wastewater Treatment Using TiO2 Photocatalyst/Ozonation (광촉매/오존을 이용한 염색폐수처리에 관한 연구)

  • Kim, Chang-Kyun;Chung, Ho-Jin;Kim, Jong-Suk
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.21 no.6
    • /
    • pp.663-670
    • /
    • 2007
  • This study was performed to provide basic information for evaluating the efficiency and applicable extent of photocatalysis and ozonation for the treatment of dye wastewater. The treatability of dye wastewater by $UV/TiO_2$ and $UV/TiO_2/O_3$ advanced oxidation process (AOP) was investigated under various conditions. The experiments were conducted in a batch reactor of 50 liters equipped with twelve UV Lamps of 16W. In $UV/TiO_2$ AOP, the removal efficiency of TCODMn and Color increased to 58% and 67% respectively with increasing UV intensity. Also, The removal efficiency of TCODMn and Color increased to 97% and 99% respectively with increasing $H_2O_2$. Acid area was more efficient than neutral and alkalic areas in wastewater treatment, and pH 5 was the most effective and the treatment efficiency continually increased as the amount of photocatalyst was increased. When the photocatalyst was increased, TCODMn was removed faster than Color.

Hydroxyapatite Coating on Al2O3 by Hydrothermal Process

  • Ha, Jung-Soo
    • Journal of the Korean Ceramic Society
    • /
    • v.40 no.12
    • /
    • pp.1154-1158
    • /
    • 2003
  • Hydrothermal deposition of hydroxyapatite coatings on $Al_2$O$_3$ substrates was studied using aqueous solutions of Ca(NO$_3$)$_2$ㆍ4$H_2O$ and (NH$_4$)$_2$HPO$_4$ containing EDTA disodium salt as a chelating agent for $Ca^{2+}$. For the precipitation of the coatings the EDTA-Ca$^{2+}$ chelates were dissociated thermally at 20$0^{\circ}C$ or decomposed by oxidation with $H_2O$$_2$ at 9$0^{\circ}C$. Scanning electron microscopy and X-ray diffraction were used to investigate the deposition behavior and the phase of the coatings. Hydroxyapatite coatings were not deposited with the thermal dissociation method, whereas uniform deposition of the coatings (about 0.7 $\mu\textrm{m}$ thickness) was obtained with the oxidative decomposition method. The coatings consisted of fine rod-like hydroxyapatite crystals (hexagonal structure) with 60-80 nm diameters, having some preferred orientation with their length (i.e., the c axis) perpendicular to the substrate.ate.

Microstructural Analysis of Epitaxial Layer Defects in Si Wafer

  • Lim, Sung-Hwan
    • Korean Journal of Materials Research
    • /
    • v.20 no.12
    • /
    • pp.645-648
    • /
    • 2010
  • The structure and morphology of epitaxial layer defects in epitaxial Si wafers produced by the Czochralski method were studied using focused ion beam (FIB) milling, scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Epitaxial growth was carried out in a horizontal reactor at atmospheric pressure. The p-type Si wafers were loaded into the reactor at about $800^{\circ}C$ and heated to about $1150^{\circ}C$ in $H_2$. An epitaxial layer with a thickness of $4{\mu}m$ was grown at a temperature of 1080-$1100^{\circ}C$. Octahedral void defects, the inner walls of which were covered with a 2-4 nm-thick oxide, were surrounded mainly by $\{111\}$ planes. The formation of octahedral void defects was closely related to the agglomeration of vacancies during the growth process. Cross-sectional TEM observation suggests that the carbon impurities might possibly be related to the formation of oxide defects, considering that some kinds of carbon impurities remain on the Si surface during oxidation. In addition, carbon and oxygen impurities might play a crucial role in the formation of void defects during growth of the epitaxial layer.

Synthesis of highly crystalline nanoporous titanium dioxide at room temperature (상온에서 고결정성 나노기공 이산화티탄 제조기술)

  • Chung, Pyung Jin;Kwon, Yong Seok
    • Journal of Energy Engineering
    • /
    • v.25 no.2
    • /
    • pp.65-78
    • /
    • 2016
  • Initial studies of the photocatalyst has been developed from the field relating to the conversion and storage of solar energy. Recently, the study of the various organic decomposition compound and the water purification and waste water treatment by ultraviolet irradiation in the presence of light or a photocatalyst are being actively investigated. In addition, the oxidized material-carbon nanotubes, graphene-nanocomposites have been studied. Such a complex is suitable as a material constituting the solar cells and photolysis nanoelectronics, including the flexible element due to thermal and chemical stability.