• Title/Summary/Keyword: absorbers

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A Comprehensive Study for Two Damage Sites of Human Hair upon UV-B Damage

  • Song, Sang-Hun;Son, Seongkil;Kang, Nae Gyu
    • Korea Journal of Cosmetic Science
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    • v.2 no.1
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    • pp.1-10
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    • 2020
  • Protection mechanisms for skin damage of ultraviolet (UV) absorbers in personal care products for protection against UV are well studied, but not for hair protection. The purpose of this study is to describe and compare the changes of physical property produced in human hair by doses of the UV-B exposure causing protein degradation. To observe the change of physical properties in hair, the experimental intensity of UV-B exposure has been established on the basis of statistical data from official meterological administration as daily one hour sunlight exposure for two weeks. Polysilicone-15, ethylhexyl methoxycinnamate (OMC), and octocrylene were employed for UV-B absorber, and those were treated to hair swatch by rubbing wash through shampoo and conditioner. Bending rigidity displayed kinetically successive reduction at high doses of UV exposure up to the 8,000 s, and exhibited different level at each sample of UV-B absorber. However, the values of Bossa Nova Technologies (BNT) for shinning factor were already saturable at the 2,000 s exposure except that treated with polysilicone-15. The differential scanning calorimetry (DSC) to measure a strength of inner protein produces a successive reduction of enthalpy as like a reduction of bending rigidity upon UV exposure. Surface roughness from lateral force microscope (LFM) acquired immediately after UV exposure show a saturable frictional voltage which has been also found in a saturable BNT data as the time of UV exposure increases. Through researching the DSC and the LFM, shinning of hair was much correlated to the protein damage at the surface, and bending rigidity could be regulated by the protein structural damage inside hair. Therefore, the optimization of efficient strategy for simultaneous prevention of hair protein on the surface and internal hair was required to maintain physical properties against UV.

Improvement in Performance of Cu2ZnSn(S,Se)4 Absorber Layer with Fine Temperature Control in Rapid Thermal Annealing System (Cu2ZnSn(S,Se)4(CZTSSe) 흡수층의 급속 열처리 공정 온도 미세 조절을 통한 특성 향상)

  • Kim, Dong Myeong;Jang, Jun Sung;Karade, Vijay Chandrakant;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.31 no.11
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    • pp.619-625
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    • 2021
  • Cu2ZnSn(S,Se)4 (CZTSSe) based thin-film solar cells have attracted growing attention because of their earth-abundant and non-toxic elements. However, because of their large open-circuit voltage (Voc)-deficit, CZTSSe solar cells exhibit poor device performance compared to well-established Cu(In,Ga)(S,Se)2 (CIGS) and CdTe based solar cells. One of the main causes of this large Voc-deficit is poor absorber properties for example, high band tailing properties, defects, secondary phases, carrier recombination, etc. In particular, the fabrication of absorbers using physical methods results in poor surface morphology, such as pin-holes and voids. To overcome this problem and form large and homogeneous CZTSSe grains, CZTSSe based absorber layers are prepared by a sputtering technique with different RTA conditions. The temperature is varied from 510 ℃ to 540 ℃ during the rapid thermal annealing (RTA) process. Further, CZTSSe thin films are examined with X-ray diffraction, X-ray fluorescence, Raman spectroscopy, IPCE, Energy dispersive spectroscopy and Scanning electron microscopy techniques. The present work shows that Cu-based secondary phase formation can be suppressed in the CZTSSe absorber layer at an optimum RTA condition.

Influence of Annealing Temperature on Crystal Orientation of Electrodeposited Sb2Se3 Thin-Film Photovoltaic Absorbers

  • Kim, Seonghyun;Lee, Seunghun;Park, Jaehan;Kim, Shinho;Kim, Yangdo
    • Korean Journal of Materials Research
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    • v.32 no.5
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    • pp.243-248
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    • 2022
  • This study demonstrates a different approach method to fabricate antimony selenide (Sb2Se3) thin-films for the solar cell applications. As-deposited Sb2Se3 thin-films are fabricated via electrodeposition route and, subsequently, annealed in the temperature range of 230 ~ 310℃. Cyclic voltammetry is performed to investigate the electrochemical behavior of the Sb and Se ions. The deposition potential of the Sb2Se3 thin films is determined to be -0.6 V vs. Ag/AgCl (in 1 M KCl), where the stoichiometric composition of Sb2Se3 appeared. It is found that the crystal orientations of Sb2Se3 thin-films are largely dependent on the annealing temperature. At an annealing temperature of 250 ℃, the Sb2Se3 thin-film grew most along the c-axis [(211) and/or (221)] direction, which resulted in the smooth movement of carriers, thereby increasing the carrier collection probability. Therefore, the solar cell using Sb2Se3 thin-film annealed at 250 ℃ exhibited significant enhancement in JSC of 10.03 mA/cm2 and a highest conversion efficiency of 0.821 % because of the preferred orientation of the Sb2Se3 thin film.

Vibration control in high-rise buildings with tuned liquid dampers - Numerical simulation and engineering applications

  • Zijie Zhou;Zhuangning Xie;Lele Zhang
    • Wind and Structures
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    • v.36 no.2
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    • pp.91-103
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    • 2023
  • Tuned liquid dampers (TLDs) are increasingly being used as efficient dynamic vibration absorbers to mitigate wind-induced vibration in super high-rise buildings. However, the damping characteristics of screens and the control effectiveness of actual structures must be investigated to improve the reliability of TLDs in engineering applications. In this study, a numerical TLD model is developed using computational fluid dynamics (CFD) and a simulation method for achieving the coupled vibration of the structure and TLD is proposed. The numerical results are verified using shaking table tests, and the effects of the solidity ratio and screen position on the TLD damping ratios are investigated. The TLD control effectiveness is obtained by simulating the wind-induced vibration response of a full-scale structure-TLD system to determine the optimal screen solidity ratio. The effects of the structural frequency, damping ratio, and wind load amplitude on the TLD performance are further analyzed. The TLD damping ratio increases nonlinearly with the solidity ratio, and it increases with the screens towards the tank center and then decreases slightly owing to the hydrodynamic interaction between screens. Full-scale coupled simulations demonstrated that the optimal TLD control effectiveness was achieved when the solidity ratio was 0.46. In addition, structural frequency shifts can significantly weaken the TLD performance. The control effectiveness decreases with an increase in the structural damping ratio, and is insensitive to the wind load amplitude within a certain range, implying that the TLD has a stable damping performance over a range of wind speed variations.

LEU+ loaded APR1400 using accident tolerant fuel cladding for 24-month two-batch fuel management scheme

  • Husam Khalefih;Taesuk Oh;Yunseok Jeong;Yonghee Kim
    • Nuclear Engineering and Technology
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    • v.55 no.7
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    • pp.2578-2590
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    • 2023
  • In this work, a 24-month two-batch fuel management strategy for the APR1400 using LEU + has been investigated, where enrichments of 5.9 and 5.2 w/o are utilized in lieu of the conventional 4-5 w/o UO2 fuel. In addition, an Accident Tolerant Fuel (ATF) clad based on the swaging technology is applied to APR1400 fuel assemblies. In this special ATF clad design, both outer and inner SS316 layers protect the conventional zircaloy clad. Erbia (Er2O3) is introduced as a burnable absorber with two-fold goals to lower the critical boron concentration in the long-cycle LEU + loaded core as well as to handle the LEU + fuel in the existing front-end fuel facilities without renewing the license. Two types of fuel assemblies with different loading of gadolinia (Gd2O3) are considered to control both the reactivity and the core radial power distribution. The erbia burnable absorber is uniformly admixed with UO2 in all fuel pins except for the gadolinia-bearing ones. In this study, two core designs were devised with different erbia loading, and core performance and safety parameters were evaluated for each case in comparison with a core design without any burnable absorbers. The core analysis was done using the two-step method. First, cross-sections are generated by the SERPENT 2 Monte Carlo code, and the 3-D neutronic analysis is performed with an in-house multi-physics nodal code KANT.

Femtosecond Mid-IR Cr:ZnS Laser with Transmitting Graphene-ZnSe Saturable Absorber

  • Won Bae Cho;Ji Eun Bae;Seong Cheol Lee;Nosoung Myoung;Fabian Rotermund
    • Current Optics and Photonics
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    • v.7 no.6
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    • pp.738-744
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    • 2023
  • Graphene-based saturable absorbers (SAs) are widely used as laser mode-lockers at various laser oscillators. In particular, transmission-type graphene-SAs with ultrabroad spectral coverage are typically manufactured on transparent substrates with low nonlinearity to minimize the effects on the oscillators. Here, we developed two types of transmitting graphene SAs based on CaF2 and ZnSe. Using the graphene-SA based on CaF2, a passively mode-locked mid-infrared Cr:ZnS laser delivers relatively long 540 fs pulses with a maximum output power of up to 760 mW. In the negative net cavity dispersion regime, the pulse width was not reduced further by inhomogeneous group delay dispersion (GDD) compensation. In the same laser cavity, we replaced only the graphene-SA based on CaF2 with the SA based on ZnSe. Due to the additional self-phase modulation effect induced by the ZnSe substrate with high nonlinearity, the stably mode-locked Cr:ZnS laser produced Fourier transform-limited ~130 fs near 2,340 nm. In the stable single-pulse operation regime, average output powers up to 635 mW at 234 MHz repetition rates were achieved. To our knowledge, this is the first attempt to achieve shorter pulse widths from a polycrystalline Cr:ZnS laser by utilizing the graphene deposited on the substrate with high nonlinearity.

Moisturizing Effect and Durability of Sun Protection Factor (UVA/B) Activity with Multiple Emulsion (W/O/W) System (멀티플 에멀전(W/O/W) 시스템을 이용한 자외선차단성능(UVA/B)의 내수성과 보습효과)

  • Lee, Myoung-Hee;Kim, In-Young
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.339-347
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    • 2015
  • This study is to evaluate moisturizing effect and durability of UV A/B blocking activity with multiple (W/O/W) emulsion system. Most of the sun protective products come to be hot issue having both high SPF and long-lasting activity as using special products when is going out, mountain climbing and sports. Also, many consumers prefer the products which have the excellent waterproofing activity of sun care cosmetics as well as the non-sticky feeling that carried out the study of the sensorial science and texture preference. Therefore, development of the specific formulation using this multiple (W/O/W) emulsion technology, it has O/W type hydro skin feel having soft and moist texture when it is treated on the skin. Finally, this formulation is instantly changed to W/O type feel after adsorbed into the skin. The purpose of this study is to get high SPF lasting effect having high water resistance tactivity with high functional multiple (W/O/W) emulsion cream. We used major ingredients, UV-B absorbers were selected with ethylhexyl methoxycinnamate, isoamyl-p-methoxycinnamate, ethylhexylsalicylate, and octocrylene, UV-A absorbers were selected with butylmethoxydibenzoylmethane, bis-ethylhexyloxyphenol methoxy phenyltriazine. SPF effect of O/W type cream was 34.1. SPF effect of W/O/W type cream was 40.6 (increased about 19%). Water resistance effect after 4 hours, SPF effect of O/W type cream was 3.6 (quickly drop down). SPF effect of W/O/W type cream having 81.0 % waterproofing effect was 32.7 (decreased about SPF 7.9). Moisturizing effect of O/W cream at first was superior comparing multiple emulsion. But after 3 hours quickly was drop-down. Moisturizing effect of multiple emulsion was high comparing O/W type and other sun block creams after 4 hours was constantly maintaining water-content.

A Study on Manufacturing Method of High Performance Smart EMW Absorber with Heat Radiating Function and Its Prospects (방열 기능형 고성능 스마트 전파흡수체 제조 방법 개발 및 전망)

  • Kim, Dong Il;Jeon, Yong Bok
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.26 no.10
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    • pp.841-850
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    • 2015
  • With the rapid progress of electronics and radio communication technology, human enjoys greater freedom in information communication. However, EMW(Electro-Magnetic Wave) environments have become more complicate and difficult to control. Thus, international organizations, such as the American National Standard Institution(ANSI), Federal Communications Commission(FCC), the Comite Internationale Special des Perturbations Radio Electrique(CISPR), etc, have provided standard for controlling the EM wave environments and for the countermeasure of the electromagnetic compatibility(EMC). In this paper, fabrication of the smart EMW absorber which has heat radiating function and high performance absorption abilities were suggested. Furthermore, we prospected future smart EMW absorbers. The designed smart EMW absorber is fabricated following process. Firstly, we applied high temperature heat treated to a mixture of Iron-oxide($Fe_2O_3$) and ceramics. Secondly, we applied low temperature heat treated to the mixture of heat treated material and a carbon material. Lastly, we made apertures on the absorber. The designed smart EM wave absorber has the absorption ability of more than 20 dB from 2 GHz to 2.45 GHz band, respectively. Thus, it is respected that these results can be applied as various EMC devices in electronic, communication, and controlling systems.

Experimental Study on Optimization of Absorber Configuration in Compression/Absorption Heat Pump with NH3/H2O Mixture (NH3/H2O 혼합냉매를 사용한 압축/흡수식 히트펌프 시스템의 흡수기 최적화에 관한 실험적 연구)

  • Kim, Ji-Young;Kim, Min-Sung;Baik, Young-Jin;Park, Seong-Ryong;Chang, Ki-Chang;Ra, Ho-Sang;Kim, Yong-Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.35 no.3
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    • pp.229-235
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    • 2011
  • This research aims todevelopa compression/absorption hybrid heat pump system using an $NH_3/H_2O$ as working fluid.The heatpump cycle is based on a combination of compression and absorption cycles. The cycle consists of two-stage compressors, absorbers, a desorber, a desuperheater, solution heat exchangers, a solution pump, a rectifier, and a liquid/vapor separator. The compression/absorption hybrid heat pump was designed to produce hot water above $90^{\circ}C$ using high-temperature glide during a two-phase heat transfer. Distinct characteristics of the nonlinear temperature profile should be considered to maximize the performance of the absorber. In this study, the performance of the absorber was investigated depending on the capacity, shape, and arrangementof the plate heat exchangers with regard tothe concentration and distribution at the inlet of the absorber.

The Properties of Vibration Absorption according to the Diameter of Fiberous $BaTiO_3$ Powder (섬유상 $BaTiO_3$의 분말 직경에 따른 흡진 특성)

  • Seo, Yong-Gyo
    • Korean Journal of Materials Research
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    • v.4 no.1
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    • pp.3-8
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    • 1994
  • Recently, sound and mechanical vibration are becoming important problems in our life. In the present study, the measurement of vibration absorption characteristics of barium titanate ceramics and the investigation of its relationship to microstructures were carried out. The barium titanate ceramics is expected to be better vibration absorption material owing to its chemical and physical stability than other conventional vibration absorbers like glasswool board. Barium titanate ceramics were prepared by sintering fiberous $BaTiO_{3}$ crystallites in order to enhance the vibration absorption characteristics. The fiberous $BaTiO_{3}$ ceramics were prepared through the ionic exchange after the preparation of fiberous $K_2Ti_4O_9$ with 0.2$\mu\textrm{m}$, 1.2$\mu\textrm{m}$, 2.0$\mu\textrm{m}$, diameter length by KDC method. The fiberous crystallites were oriented in a plane perpendicular to the press direction and sintered. The investigation of the grain diameters of the sintered ceramics, equivalent factor, electromechanical coupling factor($k_1$), and the generated voltage(V) shows that the grain's diameter decreases with the increase of the diameter of the used fiberous crystallites. The vibration absorption increases the crystallites' diameter. That means that the vibration absorption increases with the internal friction of grain boundary. Which was identified by the investigation of the equivallent circuit.

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